Seed particle formation for silicate dust condensation by SiO nucleation

Clustering of the abundant SiO molecules has been discussed as a possible mechanism of seed particle formation for silicate dust in stellar outflows with an oxygen rich element mixture. Previous results indicated that condensation temperatures based on this mechanism are significant lower than what is really observed. This negative result strongly rests on experimental data on vapour pressure of SiO. New determinations show the older data to be seriously in error. Here we aim to check with improved data the possibility that SiO nucleation triggers the cosmic silicate dust formation. First we present results of our measurements of vapour pressure of solid SiO. Second, we use the improved vapour pressure data to re-calibrate existing experimental data on SiO nucleation from the literature. Third, we use the re-calibrated data on SiO nucleation in a simple model for dust-driven winds to determine the condensation temperature of silicate in stellar outflows from AGB stars. We show that onset of nucleation under circumstellar conditions commences at higher temperature than was previously found. Calculated condensation temperatures are still by about 100 K lower than observed ones, but this may be due to the greenhouse effect of silicate dust temperatures. The assumption that the onset of silicate dust formation in late-type M stars is triggered by cluster formation of SiO is compatible with dust condensation temperatures derived from IR observations.Comment: 11 pages, 11 figure

Early Thermal Evolution of Planetesimals and its Impact on Processing and Dating of Meteoritic Material

Radioisotopic ages for meteorites and their components provide constraints on the evolution of small bodies: timescales of accretion, thermal and aqueous metamorphism, differentiation, cooling and impact metamorphism. Realising that the decay heat of short-lived nuclides (e.g. 26Al, 60Fe), was the main heat source driving differentiation and metamorphism, thermal modeling of small bodies is of utmost importance to set individual meteorite age data into the general context of the thermal evolution of their parent bodies, and to derive general conclusions about the nature of planetary building blocks in the early solar system. As a general result, modelling easily explains that iron meteorites are older than chondrites, as early formed planetesimals experienced a higher concentration of short-lived nuclides and more severe heating. However, core formation processes may also extend to 10 Ma after formation of Calcium-Aluminum-rich inclusions (CAIs). A general effect of the porous nature of the starting material is that relatively small bodies (< few km) will also differentiate if they form within 2 Ma after CAIs. A particular interesting feature to be explored is the possibility that some chondrites may derive from the outer undifferentiated layers of asteroids that are differentiated in their interiors. This could explain the presence of remnant magnetization in some chondrites due to a planetary magnetic field.Comment: 24 pages, 9 figures, Accepted for publication as a chapter in Protostars and Planets VI, University of Arizona Press (2014), eds. H. Beuther, R. Klessen, C. Dullemond, Th. Hennin

Monte Carlo Neutrino Oscillations

We demonstrate that the effects of matter upon neutrino propagation may be recast as the scattering of the initial neutrino wavefunction. Exchanging the differential, Schrodinger equation for an integral equation for the scattering matrix S permits a Monte Carlo method for the computation of S that removes many of the numerical difficulties associated with direct integration techniques

Infrared Spectroscopic Study of a Selection of AGB and Post-AGB Stars

We present here near-infrared spectroscopy in the H and K bands of a selection of nearly 80 stars that belong to various AGB types, namely S type, M type and SR type. This sample also includes 16 Post-AGB (PAGB) stars. From these spectra, we seek correlations between the equivalent widths of some important spectral signatures and the infrared colors that are indicative of mass loss. Repeated spectroscopic observations were made on some PAGB stars to look for spectral variations. We also analyse archival SPITZER mid-infrared spectra on a few PAGB stars to identify spectral features due to PAH molecules providing confirmation of the advanced stage of their evolution. Further, we model the SEDs of the stars (compiled from archival data) and compare circumstellar dust parameters and mass loss rates in different types. Our near-infrared spectra show that in the case of M and S type stars, the equivalent widths of the CO(3-0) band are moderately correlated with infrared colors, suggesting a possible relationship with mass loss processes. A few PAGB stars revealed short term variability in their spectra, indicating episodic mass loss: the cooler stars showed in CO first overtone bands and the hotter ones showed in HI Brackett lines. Our spectra on IRAS 19399+2312 suggest that it is a transition object. From the SPITZER spectra, there seems to be a dependence between the spectral type of the PAGB stars and the strength of the PAH features. Modelling of SEDs showed among the M and PAGB stars that the higher the mass loss rates, the higher the [K-12] colour in our sample.Comment: 14 pages; accepted in MNRAS, 200

Not-For-Profit Organizations And For-Profit Businesses: Perceptions And Reality

Not-for-profit organizations represent an important portion of the gross domestic product of the United States; yet there are many misconceptions in the business world regarding not-for-profits.&nbsp; This paper analyzes two surveys -- one of business persons and the other of seniors in an undergraduate business program &ndash; to determine the extent of the suspected misconceptions. Then the paper presents factual support to correct typical misconceptions regarding how not-for-profit organizations operate.&nbsp

The Photophysics of the Carrier of Extended Red Emission

Interstellar dust contains a component which reveals its presence by emitting a broad, unstructured band of light in the 540 to 950 nm wavelength range, referred to as Extended Red Emission (ERE). The presence of interstellar dust and ultraviolet photons are two necessary conditions for ERE to occur. This is the basis for suggestions which attribute ERE to an interstellar dust component capable of photoluminescence. In this study, we have collected all published ERE observations with absolute-calibrated spectra for interstellar environments, where the density of ultraviolet photons can be estimated reliably. In each case, we determined the band-integrated ERE intensity, the wavelength of peak emission in the ERE band, and the efficiency with which absorbed ultraviolet photons are contributing to the ERE. The data show that radiation is not only driving the ERE, as expected for a photoluminescence process, but is modifying the ERE carrier as manifested by a systematic increase in the ERE band's peak wavelength and a general decrease in the photon conversion efficiency with increasing densities of the prevailing exciting radiation. The overall spectral characteristics of the ERE and the observed high quantum efficiency of the ERE process are currently best matched by the recently proposed silicon nanoparticle (SNP) model. Using the experimentally established fact that ionization of semiconductor nanoparticles quenches their photoluminescence, we proceeded to test the SNP model by developing a quantitative model for the excitation and ionization equilibrium of SNPs under interstellar conditions for a wide range of radiation field densities.Comment: 42 p., incl. 8 fig. Accepted for publication by Ap

Hydrogenation of CO on a silica surface: an embedded cluster approach

The sequential addition of H atoms to CO adsorbed on a siliceous edingtonite surface is studied with an embedded cluster approach, using density functional theory for the quantum mechanical (QM) cluster and a molecular force field for the molecular mechanical (MM) cluster. With this setup, calculated QM/MM adsorption energies are in agreement with previous calculations employing periodic boundary conditions. The catalytic effect of the siliceous edingtonite (100) surface on CO hydrogenation is assessed because of its relevance to astrochemistry. While adsorption of CO on a silanol group on the hydroxylated surface did not reduce the activation energy for the reaction with a H atom, a negatively charged defect on the surface is found to reduce the gas phase barriers for the hydrogenation of both CO and H2C = O. The embedded cluster approach is shown to be a useful and flexible tool for studying reactions on (semi-)ionic surfaces and specific defects thereon. The methodology presented here could easily be applied to study reactions on silica surfaces that are of relevance to other scientific areas, such as biotoxicity of silica dust and geochemistry

MODTRAN3: An update and recent validations against airborne high resolution interferometer measurements

MODTRAN, the Moderate Resolution Atmospheric Radiance and Transmittance Model, encompasses all the capabilities of LOWTRAN 7, the widely used 20 cm(exp -1) resolution radiance code, but incorporates a much more sensitive molecular band model with 2 cm(exp -1) resolution. MODTRAN contains many important elements that other band model based radiative transfer codes do not incorporate. It shares with FASCODE: spherical geometry, single and multiple scattering default atmospheric profile descriptors (gases, aerosols, clouds, fogs, and rain), and molecular continua (H2O, CO2, O3, O2, N2). In addition, it can calculate the solar/lunar direct and scattered radiation. MODTRAN3 was released to the general public in November 1994. It has several important features that the previous version, MODTRAN2, does not have. Chloro-fluorocarbon (CFC) and related heavy molecules (whose spectroscopic properties first appear on the HITRAN92 data base as temperature-dependent cross sections) have been incorporated into pseudo-band models, with provision for using both default and user supplied profiles. The addition of SO2 and O2 in the UV, along with upgraded ozone Chappuis bands in the visible is also part of MODTRAN3. An improved multiple scattering algorithm, the DIScrete Ordinate Radiative Transfer (DISORT) has also been incorporated into MODTRAN3. MODTRAN is very fast: simple timing runs of MODTRAN3 vs. FASCOD3 show an improvement of more than a factor of 100 for a typical 500 cm(exp -1) spectral interval and comparable vertical layering. Speed is an important consideration in heating/cooling rates calculations, where a large number of radiative transfer calculations are needed. The MODTRAN3 used in this study is based on HITRAN92, but as mentioned, above, it will be upgraded to HITRAN94 upon its release at the end of 1994. MODTRAN has been adopted by: some researchers in the AVIRIS program as one radiative transfer code to derive surface reflectance from AVIRIS measurements. The accuracy of the code is very important because any errors in the radiative transfer calculation will directly translate into errors in the derived surface reflectance. In this paper, the new solar irradiance calculated by Kurucz, which is adopted in MODTRAN3, will be presented. Recent validations of MODTRAN3 with airborne high resolution interferometer measurements over ocean will be discussed. Good agreeement between model calculations and measurements was achieved