Seismic analysis of 70 Ophiuchi A: A new quantity proposed

The basic intent of this paper is to model 70 Ophiuchi A using the latest asteroseismic observations as complementary constraints and to determine the fundamental parameters of the star. Additionally, we propose a new quantity to lift the degeneracy between the initial chemical composition and stellar age. Using the Yale stellar evolution code (YREC7), we construct a series of stellar evolutionary tracks for the mass range $M$ = 0.85 -- 0.93 $M_{\odot}$ with different composition $Y_{i}$ (0.26 -- 0.30) and $Z_{i}$ (0.017 -- 0.023). Along these tracks, we select a grid of stellar model candidates that fall within the error box in the HR diagram to calculate the theoretical frequencies, the large- and small- frequency separations using the Guenther's stellar pulsation code. Following the asymptotic formula of stellar $p$-modes, we define a quantity $r_{01}$ which is correlated with stellar age. Also, we test it by theoretical adiabatic frequencies of many models. Many detailed models of 70 Ophiuchi A have been listed in Table 3. By combining all non-asteroseismic observations available for 70 Ophiuchi A with these seismological data, we think that Model 60, Model 125 and Model 126, listed in Table 3, are the optimum models presently. Meanwhile, we predict that the radius of this star is about 0.860 -- 0.865 $R_{\odot}$ and the age is about 6.8 -- 7.0 Gyr with mass 0.89 -- 0.90 $M_{\odot}$. Additionally, we prove that the new quantity $r_{01}$ can be a useful indicator of stellar age.Comment: 23 pages, 5 figures, accepted by New Astronom

Asteroseismic study of solar-like stars: A method of estimating stellar age

Asteroseismology, as a tool to use the indirect information contained in stellar oscillations to probe the stellar interiors, is an active field of research presently. Stellar age, as a fundamental property of star apart from its mass, is most difficult to estimate. In addition, the estimating of stellar age can provide the chance to study the time evolution of astronomical phenomena. In our poster, we summarize our previous work and further present a method to determine age of low-mass main-sequence star.Comment: 2 pages, 1 figures, submitted to IAUS25

Strain driven anisotropic magnetoresistance in antiferromagnetic La0.4_{0.4}Sr0.6_{0.6}MnO3_{3}

We investigate the effects of strain on antiferromagntic (AFM) single crystal thin films of La$_{1-x}$Sr$_{x}$MnO$_{3}$ (x = 0.6). Nominally unstrained samples have strong magnetoresistance with anisotropic magnetoresistances (AMR) of up to 8%. Compressive strain suppresses magnetoresistance but generates AMR values of up to 63%. Tensile strain presents the only case of a metal-insulator transition and demonstrates a previously unreported AMR behavior. In all three cases, we find evidence of magnetic ordering and no indication of a global ferromagnetic phase transition. These behaviors are attributed to epitaxy induced changes in orbital occupation driving different magnetic ordering types. Our findings suggest that different AFM ordering types have a profound impact on the AMR magnitude and character.Comment: http://dx.doi.org/10.1063/1.489242

Single-Exponential Fluorescence Decay of the Nonnatural Amino Acid 7-Azatryptophan and the Nonexponential Fluorescence Decay of Tryptophan in Water

The fluorescence decay of an optical probe, the nonnatural amino acid 7-azatryptophan, is measured as a function of pH, in varying mixtures of H20 and D2O and in various nonaqueous solvents. The spectroscopic distinguishability of 7-azatryptophan is demonstrated by the comparison of its fluorescence lifetime in mixtures of N-acetyltryptophanamide (NATA) with that of mixtures of 5-hydroxytryptophan in NATA. The observation of single-exponential fluorescence decay for 7-azatryptophan in water is discussed in terms of nonradiative processes that compete effectively with charge transfer from the excited-state 7-azaindole to the side chain groups and in terms of the dependence of the charge-transfer reaction on the excited-state energy of 7-azaindole. We propose that the absence of nonexponential fluorescence decay (owing to the relative insignificance of charge transfer to the side chain as a nonradiative process in 7-azatryptophan in water) arises from an unfavorable free energy of reaction. This free energy is determined largely by the energy of the fluorescent state, which lies 46 nm (9.8 kcal/mol) below that of tryptophan when the solvent is water

Solvation of 7-azaindole in alcohols and water: evidence for concerted, excited-state, double-proton transfer in alcohols

The proton inventory technique is used for the first time to investigate excited-state proton-transfer processes. The nonradiative pathways of the biological probe, 7-azaindole, in methanol, ethanol, and water are examined. Results in methanol and ethanol demonstrate the involvement of two protons in the transition state for the excited-state doubleproton transfer process. These data provide the first experimental evidence suggesting a concerted tautomerization reaction of 7-azaindole in alcohols. The data for 7-azaindole in water are interpreted in terms of a nonradiative pathway that is qualitatively different from that in alcohols. We propose abstraction of the N1 hydrogen by water as a possible nonradiative decay process

Nonradiative pathways of 7-azaindole in water

The 7-azaindole chromophore in water is studied by means of picosecond absorption and fluorescence spectroscopy in order to determine its nonradiative decay pathways. It is concluded that a small population of 7-azaindole molecules (-20%) undergo excited-state tautomerization in about 70 ps. Intersystem crossing and photoionization are also identified as nonradiative decay channels. Photoionization occurs largely from an electronic state lying slightly in energy above the fluorescent state. This new understanding of the photophysics of the 7-azaindole chromophore in water will be essential in interpreting its behavior when it is used as an optical probe of protein structure and dynamics

Probing Solvation by Alcohols and Water with 7-Azaindole

The nonradiative pathways of 7-azaindole are extremely sensitive to solvent. In alcohols, 7-azaindole executes an excited-state double-proton transfer. In water, this tautomerization is frustrated. Proton inventory experiments suggest a concerted double-proton transfer in the alcohols and point to another nonradiative process in water. We propose the following idealized picture. Whereas at room temperature 7-azaindole can form a cyclic hydrogen-bonded intermediate with a single alcohol molecule facilitating tautomerization, in water more than one solvent molecule coordinates to the solute and thus prohibits the concerted process. More detailed measurements, however, indicate that water and alcohols do not solvate 7-azaindole in fundamentally different ways, but rather that they represent two extremes of the same phenomenon

Fluorescent species of 7-azaindole and 7-azatryptophan in water

A study of the fluorescence lifetimes and quantum yields of 7-azaindole and its methylated derivatives NImethyl- Famindole (1 M7AI) and 7-methyl-7H-pyrrolo[ 2,341 pyridine (7M7AI) in water is performed in order to explain the observation that the fluorescence spectrum of 7-azaindole apparently consists of one band (A, = 386 nm) whereas in alcohols the spectrum is bimodal (e.g., for methanol, A,, = 374, 505 nm). Careful measurements of the fluorescence decay as a function of emission wavelength indicate a small amplitude of an -70-ps decaying component at the bluer wavelengths and a rising component of the same duration at the redder wavelengths. The small amplitude component, which comprises no more than 20% of the fluorescence decay, is attributed to excited-state tautomerization that is mediated by the solvent. Particular attention is paid to the pH dependence of the fluorescence lifetimes and yields. We propose that upon tautomerization the basic l-nitrogen (NIo)f 7-azaindole is rapidly protonated givingrise to a species whose emission maximum is at -440 nm. The fluorescence emission maximum and lifetime of 7-azaindole is dominated by the 80% of the solute molecules that are blocked by unfavorable solvation from executing excited-state tautomerization. It is proposed that 210 ns is required for the surrounding water molecules to attain a configuration about 7-azaindole that is propitious for tautomerization