29 research outputs found
Observation of superconductivity at 30 K~46 K in AxFe2Se2 (A = Li, Na, Ba, Sr, Ca, Yb, and Eu)
New iron selenide superconductors by intercalating smaller-sized alkali
metals (Li, Na) and alkaline earths using high-temperature routes have been
pursued ever since the discovery of superconductivity at about 30 K in KFe2Se2,
but all have failed so far. Here we demonstrate that a series of
superconductors with enhanced Tc=30~46 K can be obtained by intercalating
metals, Li, Na, Ba, Sr, Ca, Yb, and Eu in between FeSe layers by the
ammonothermal method at room temperature. Analysis on their powder X-ray
diffraction patterns reveals that all the main phases can be indexed based on
body-centered tetragonal lattices with a~3.755-3.831 {\AA} while c~15.99-20.54
{\AA}. Resistivities show the corresponding sharp transitions at 45 K and 39 K
for NaFe2Se2 and Ba0.8Fe2Se2, respectively, confirming their bulk
superconductivity. These findings provide a new starting point for studying the
properties of these superconductors and an effective synthetic route for the
exploration of new superconductors as well.Comment: 22 pages, 5 figure
Studies on BiCoO3 and BiCo1−xFexO3
BiCoO3 and BiCo1−xFexO3 (x ≤ 0.7) prepared at atmospheric pressure are found to possess a cubic structure probably involving the Bi12O36 network. BiCoO3 is paramagnetic above 100 K, with a negative paramagnetic Curie temperature. BiCo1−xFexO3 (x = 0.5 or 0.7) is ferromagnetic with Tc ≈ 600K
Charge transfer in Chevrel phases
Chemical shifts of Mo K-absorption edge and Mo core level binding energies in Ax Mo6 Ch8 (Ch = S, Se, Te) Chevrel phases show clear evidence for charge transfer from the A element to the Mo6 cluster. The chemical shifts vary linearly with the intercluster Mo-Mo distance as well as the rhombohedral parameter
Studies on magnetic properties of MnTi1-xNbxO3 system
Synthesis and characterization of electrical and magnetic properties of ilmenite phases of the type MnTi1-xNbxO3 have been carried out. Single phase materials could be obtained for 0.0 less than or equal to x less than or equal to 0.25. The electrical conductivity increases with increasing Nb content. Magnetic susceptibility studies show that the phases exhibit 2D antiferromagnetic behavior. The magnetic susceptibility data has been analyzed using Fisher's specific heat to determine the long range ordering temperature, (C) 1998 Academic Press