Spin-controlled Mott-Hubbard bands in LaMnO_3 probed by optical ellipsometry

Spectral ellipsometry has been used to determine the dielectric function of an untwinned crystal of LaMnO_3 in the spectral range 0.5-5.6 eV at temperatures 50 K < T < 300 K. A pronounced redistribution of spectral weight is found at the Neel temperature T_N = 140 K. The anisotropy of the spectral weight transfer matches the magnetic ordering pattern. A superexchange model quantitatively describes spectral weight transfer induced by spin correlations. This analysis implies that the lowest-energy transitions around 2 eV are intersite d-d transitions, and that LaMnO_3 is a Mott-Hubbard insulator.Comment: 4 pages, 4 figure

Measurement of Linear Stark Interference in 199Hg

We present measurements of Stark interference in the 6$^1S_0$ $\rightarrow$ 6$^3P_1$ transition in $^{199}$Hg, a process whereby a static electric field $E$ mixes magnetic dipole and electric quadrupole couplings into an electric dipole transition, leading to $E$-linear energy shifts similar to those produced by a permanent atomic electric dipole moment (EDM). The measured interference amplitude, $a_{SI}$ = $(a_{M1} + a_{E2})$ = (5.8 $\pm$ 1.5)$\times 10^{-9}$ (kV/cm)$^{-1}$, agrees with relativistic, many-body predictions and confirms that earlier central-field estimates are a factor of 10 too large. More importantly, this study validates the capability of the $^{199}$Hg EDM search apparatus to resolve non-trivial, controlled, and sub-nHz Larmor frequency shifts with EDM-like characteristics.Comment: 4 pages, 4 figures, 1 table; revised in response to reviewer comment

Pickoff and spin-conversion quenchings of ortho-positronium in oxygen

The quenching processes of the thermalized ortho-positronium(o-Ps) on an oxygen molecule have been studied by the positron annihilation age-momentum correlation techinique(AMOC). The Doppler broadening spectrum of the 511 keV gamma-rays from the 2gamma annihilation of o-Ps in O_2 has been measured as a function of the o-Ps age. The rate of the quenching, consisting of the pickoff and the spin-conversion, is estimated from the positron lifetime spectrum. The ratio of the pickoff quenching rate to the spin-conversion rate is deduced from the Doppler broadening of the 511 keV gamma-rays from the annihilation of the o-Ps. The pickoff parameter ^1Z_eff, the effective number of the electrons per molecule which contribute to the pickoff quenching, for O_2 is determined to be 0.6 +- 0.4. The cross-section for the elastic spin-conversion quenching is determined to be (1.16 +- 0.01) * 10^{-19} cm^2.Comment: 4 pages with 5 eps figures, LaTeX2e(revtex4

Improved limit on the permanent electric dipole moment of 199Hg

We report the results of a new experimental search for a permanent electric dipole moment of 199Hg utilizing a stack of four vapor cells. We find d(199Hg) = (0.49 \pm 1.29_stat \pm 0.76_syst) x 10^{-29} e cm, and interpret this as a new upper bound, |d(199Hg)| < 3.1 x 10^{-29} e cm (95% C.L.). This result improves our previous 199Hg limit by a factor of 7, and can be used to set new constraints on CP violation in physics beyond the standard model.Comment: 4 pages, 4 figures. additional reference, minor edits in response to reviewer comment

Winds and tides of the Extended Unified Model in the mesosphere and lower thermosphere validated with meteor radar observations

The mesosphere and lower thermosphere (MLT) is a critical region that must be accurately reproduced in general circulation models (GCMs) that aim to include the coupling between the lower and middle atmosphere and the thermosphere. An accurate representation of the MLT is thus important for improved climate modelling and the development of a whole atmosphere model. This is because the atmospheric waves at these heights are particularly large, and so the energy and momentum they carry is an important driver of climatological phenomena through the whole atmosphere, affecting terrestrial and space weather. The Extended Unified Model (ExUM) is the recently developed version of the Met Office's Unified Model which has been extended to model the MLT. The capability of the ExUM to model atmospheric winds and tides in the MLT is currently unknown. Here, we present the first study of winds and tides from the ExUM. We make a comparison against meteor radar observations of winds and tides from 2006 between 80 and 100 km over two radar stations – Rothera (68∘ S, 68∘ W) and Ascension Island (8∘ S, 14∘ W). These locations are chosen to study tides in two very different tidal regimes – the equatorial regime, where the diurnal (24 h) tide dominates, and the polar regime, where the semi-diurnal (12 h) tide dominates. The results of this study illustrate that the ExUM is capable of reproducing atmospheric winds and tides that capture many of the key characteristics seen in meteor radar observations, such as zonal and meridional wind maxima and minima, the increase in tidal amplitude with increasing height, and the decrease in tidal phase with increasing height. In particular, in the equatorial regime some essential characteristics of the background winds, tidal amplitudes and tidal phases are well captured but with significant differences in detail. In the polar regime, the difference is more pronounced. The ExUM zonal background winds in austral winter are primarily westward rather than eastward, and in austral summer they are larger than observed above 90 km. The ExUM tidal amplitudes here are in general consistent with observed values, but they are also larger than observed values above 90 km in austral summer. The tidal phases are generally well replicated in this regime. We propose that the bias in background winds in the polar regime is a consequence of the lack of in situ gravity wave generation to generate eastward fluxes in the MLT. The results of this study indicate that the ExUM has a good natural capability for modelling atmospheric winds and tides in the MLT but that there is room for improvement in the model physics in this region. This highlights the need for modifications to the physical parameterization schemes used in the model in this region – such as the non-orographic spectral gravity wave scheme – to improve aspects such as polar circulation. To this end, we make specific recommendations of changes that can be implemented to improve the accuracy of the ExUM in the MLT.</p

A Fourier transform infrared trace gas and isotope analyser for atmospheric applications

Concern in recent decades about human impacts on Earth's climate has led to the need for improved and expanded measurement capabilities of greenhouse gases in the atmosphere. In this paper we describe in detail an in situ trace gas analyser based on Fourier Transform Infrared (FTIR) spectroscopy that is capable of simultaneous and continuous measurements of carbon dioxide (CO&lt;sub&gt;2&lt;/sub&gt;), methane (CH&lt;sub&gt;4&lt;/sub&gt;), carbon monoxide (CO), nitrous oxide (N&lt;sub&gt;2&lt;/sub&gt;O) and &lt;sup&gt;13&lt;/sup&gt;C in CO&lt;sub&gt;2&lt;/sub&gt; in air with high precision. High accuracy is established by reference to measurements of standard reference gases. Stable water isotopes can also be measured in undried airstreams. The analyser is automated and allows unattended operation with minimal operator intervention. Precision and accuracy meet and exceed the compatibility targets set by the World Meteorological Organisation – Global Atmosphere Watch for baseline measurements in the unpolluted troposphere for all species except &lt;sup&gt;13&lt;/sup&gt;C in CO&lt;sub&gt;2&lt;/sub&gt;. &lt;br&gt;&lt;br&gt; The analyser is mobile and well suited to fixed sites, tower measurements, mobile platforms and campaign-based measurements. The isotopic specificity of the optically-based technique and analysis allows its application in isotopic tracer experiments, for example in tracing variations of &lt;sup&gt;13&lt;/sup&gt;C in CO&lt;sub&gt;2&lt;/sub&gt; and &lt;sup&gt;15&lt;/sup&gt;N in N&lt;sub&gt;2&lt;/sub&gt;O. We review a number of applications illustrating use of the analyser in clean air monitoring, micrometeorological flux and tower measurements, mobile measurements on a train, and soil flux chamber measurements

Total column CO_2 measurements at Darwin, Australia – site description and calibration against in situ aircraft profiles

An automated Fourier Transform Spectroscopic (FTS) solar observatory was established in Darwin, Australia in August 2005. The laboratory is part of the Total Carbon Column Observing Network, and measures atmospheric column abundances of CO_2 and O_2 and other gases. Measured CO_2 columns were calibrated against integrated aircraft profiles obtained during the TWP-ICE campaign in January–February 2006, and show good agreement with calibrations for a similar instrument in Park Falls, Wisconsin. A clear-sky low airmass relative precision of 0.1% is demonstrated in the CO2 and O2 retrieved column-averaged volume mixing ratios. The 1% negative bias in the FTS X_(CO_2) relative to the World Meteorological Organization (WMO) calibrated in situ scale is within the uncertainties of the NIR spectroscopy and analysis

Project Fire Flight 1 vibration data

Spectral density analysis on Fire Project flight vibration dat

Derivation of tropospheric methane from TCCON CH₄ and HF total column observations

The Total Carbon Column Observing Network (TCCON) is a global ground-based network of Fourier transform spectrometers that produce precise measurements of column-averaged dry-air mole fractions of atmospheric methane (CH₄). Temporal variability in the total column of CH₄ due to stratospheric dynamics obscures fluctuations and trends driven by tropospheric transport and local surface fluxes that are critical for understanding CH₄ sources and sinks. We reduce the contribution of stratospheric variability from the total column average by subtracting an estimate of the stratospheric CH₄ derived from simultaneous measurements of hydrogen fluoride (HF). HF provides a proxy for stratospheric CH₄ because it is strongly correlated to CH₄ in the stratosphere, has an accurately known tropospheric abundance (of zero), and is measured at most TCCON stations. The stratospheric partial column of CH₄ is calculated as a function of the zonal and annual trends in the relationship between CH₄ and HF in the stratosphere, which we determine from ACE-FTS satellite data. We also explicitly take into account the CH₄ column averaging kernel to estimate the contribution of stratospheric CH₄ to the total column. The resulting tropospheric CH₄ columns are consistent with in situ aircraft measurements and augment existing observations in the troposphere