Raman-assisted Rabi resonances in two-mode cavity QED

The dynamics of a vibronic system in a lossy two-mode cavity is studied, with the first mode being resonant to the electronic transition and the second one being nearly resonant due to Raman transitions. We derive analytical solutions for the dynamics of this system. For a properly chosen detuning of the second mode from the exact Raman resonance, we obtain conditions that are closely related to the phenomenon of Rabi resonance as it is well known in laser physics. Such resonances can be observed in the spontaneous emission spectra, where the spectrum of the second mode in the case of weak Raman coupling is enhanced substantially.Comment: 6 pages, 5 figure

Effect of the Distribution System on Drinking Water Quality

The overall objective of this paper is to characterise the main aspects of water quality deterioration in a distribution system. The effect of residence time on chlorine uptake and the formation and evolution of disinfection by-products in distributed drinking water are discussed

Formation of Haloforms during Chlorination of Natural Waters

Recent drinking water regulations have lowered the standards for disinfection by-products and have added new disinfection by-products for regulation. Natural organic matter (NOM), mainly humic compounds, plays a major role in the formation of undesirable organic by-products following disinfection of drinking water. Many disinfection by-products have adverse carcinogenic or mutagenic effects on human health. This paper deals with the formation potencial of disinfection by-products in water samples taken from different places in the Flaje catchment

Transferable Pair Potentials for CdS and ZnS Crystals

A set of interatomic pair potentials is developed for CdS and ZnS crystals. We show that a simple energy function, which has been used to describe the properties of CdSe [J. Chem. Phys. 116, 258 (2002)], can be parametrized to accurately describe the lattice and elastic constants, and phonon dispersion relations of bulk CdS and ZnS in the wurtzite and rocksalt crystal structures. The predicted coexistence pressure of the wurtzite and rocksalt structures, as well as the equation of state are in good agreement with experimental observations. These new pair potentials enable the study of a wide range of processes in bulk and nanocrystalline II-VI semiconductor materials

Metastability in pressure-induced structural transformations of CdSe/ZnS core/shell nanocrystals

The kinetics and thermodynamics of structural transformations under pressure depend strongly on particle size due to the influence of surface free energy. By suitable design of surface structure, composition, and passivation it is possible, in principle, to prepare nanocrystals in structures inaccessible to bulk materials. However, few realizations of such extreme size-dependent behavior exist. Here we show with molecular dynamics computer simulation that in a model of CdSe/ZnS core/shell nanocrystals the core high pressure structure can be made metastable under ambient conditions by tuning the thickness of the shell. In nanocrystals with thick shells, we furthermore observe a wurtzite to NiAs transformation, which does not occur in the pure bulk materials. These phenomena are linked to a fundamental change in the atomistic transformation mechanism from heterogenous nucleation at the surface to homogenous nucleation in the crystal core. Our results suggest a new route towards expanding the range of available nanoscale materials

Lewatit S100 in Drinking Water Treatment for Ammonia Removal

Ammonium nitrogen is the most important form of nitrogen that can cause excessive algal growth and stimulate eutrophication in surface water. The purpose of this study is to investigate the possibility of removing ammonium from drinking water by means of an ion Exchange process. Polymeric Lewatit S100 material (particle-size 0.3–1.2 mm) was used. The breakthrough capacity was determined by dynamic laboratory investigations and the concentration of regenerant solution (5 and 10 % NaCl) was investigated. The concentration of ammonium ion inputs in the tap water that we used were 10, 5 and 2 mg NH4+ l_1 and down to levels below 0.5 mg NH4 + l_1. The experimental results show that the breakthrough capacity was very small at ammonium concentration 2 mg NH4 + l_1 compared to its breakthrough capacity at ammonium concentration 10 mg NH4 + l_1. There was no difference between regeneration by 10 and 5 % NaCl. We conclude that the use of Lewatit S100 is an attractive and promising method for ammonium concentration greater than 5 mg NH4 + l_1 and till 10 mg NH4 + l_1

Clinoptilolite in Drinking Water Treatment for Ammonia Removal

In most countries today the removal of ammonium ions from drinking water has become almost a necessity. The natural zeolite clinoptiloliteis mined commercially in many parts of the world. It is a selective exchanger for the ammonium cation, and this has prompted its use in water treatment, wastewater treatment, swimming pools and fish farming. The work described in this paper provides dynamic data on cation exchange processes in clinoptilolite involving the NH4 +, Ca+2 and Mg+2 cations. We used material of natural origin – clinoptilolite from Nižný Hrabovec in Slovakia (particle-size 3–5 mm). The breakthrough capacity was determined by dynamic laboratory investigations, and we investigated the influence of thermal pretreatment of clinoptilolite and the concentration of regenerant solution (2, 5, and 10% NaCl). The concentrations of ammonium ion inputs in the tap water that we used were 10, 5, and 2 mg NH4 + l_1 and down to levels below 0.5 mg NH4 + l_1. The experimental results show that repeated pretreatment sufficiently improves the zeolite’s properties, and the structure of clinoptilolite remains unchanged during the loading and regeneration cycles. Ammonium removal capacities were increased by approximately 40 % and 20 % for heat-treated zeolite samples. There was no difference between the regenerates for 10% and 5% NaCl. We conclude that the use of zeolite is an attractive and promising method for ammonium removal