Tuning the microwave electromagnetic properties of biochar-based composites by annealing

Abstract We report on the effects of thermal treatment of biochar embedded in epoxy-based composites on their microwave electrical properties, linking such properties to the material structure investigated by Raman, X-ray photoelectron spectroscopy, and X-ray diffraction. Annealing temperatures in the range 900–1500 °C and biochar concentrations in the epoxy matrix in the range from 5 to 25 wt.% were investigated. The microwave analysis, in the range from 250 MHz to 6 GHz, allowed us to determine the complex permittivity of composites and, through a proper deconvolution technique, to determine the contribution of biochar inclusions alone. High values of real permittivity (up to 220) and conductivity (up to 17 S/m) were evaluated for the biochar particles at 5 GHz, after the 1500 °C thermal treatment. A clear correlation between electrical properties and the biochar microstructure emerged from the dataset, with real permittivity and conductivity increasing as carbon inclusions transform from amorphous to nanocrystalline graphite. Conversely, the percentage of aromatic carbon has a weaker influence on the microwave properties. This study opens to the possibility of tailoring the high-frequency properties of biochar and biochar composites through proper thermal treatments

Thin glass shells for active optics for future space telescopes

We present a method for the manufacturing of thin shells of glass, which appears promising for the development of active optics for future space telescopes. The method exploits the synergy of different mature technologies, while leveraging the commercial availability of large, high-quality sheets of glass, with thickness up to few millimeters. The first step of the method foresees the pre-shaping of flat substrates of glass by replicating the accurate shape of a mold via hot slumping technology. The replication concept is advantageous for making large optics composed of many identical or similar segments. After the hot slumping, the shape error residual on the optical surface is addressed by applying a deterministic sub-aperture technology as computer-controlled bonnet polishing and/or ion beam figuring. Here we focus on the bonnet polishing case, during which the thin, deformable substrate of glass is temporary stiffened by a removable holder. In this paper, we report on the results so far achieved on a 130 mm glass shell case study.Comment: This is a pre-print of an article published in CEAS Space Journal. The final authenticated version is available online at: http://link.springer.com/article/10.1007/s12567-019-00259-

Adipose Tissue Dysfunction in Obesity: Role of Mineralocorticoid Receptor

The mineralocorticoid receptor (MR) acts as an essential regulator of blood pressure, volume status, and electrolyte balance. However, in recent decades, a growing body of evidence has suggested that MR may also have a role in mediating pro-inflammatory, pro-oxidative, and pro-fibrotic changes in several target organs, including the adipose tissue. The finding that MR is overexpressed in the adipose tissue of patients with obesity has led to the hypothesis that this receptor can contribute to adipokine dysregulation and low-grade chronic inflammation, alterations that are linked to the development of obesity-related metabolic and cardiovascular complications. Moreover, several studies in animal models have investigated the role of MR antagonists (MRAs) in preventing the metabolic alterations observed in obesity. In the present review we will focus on the potential mechanisms by which MR activation can contribute to adipose tissue dysfunction in obesity and on the possible beneficial effects of MRAs in this setting

Atrial Fibrillation and Aortic Ectasia as Complications of Primary Aldosteronism: Focus on Pathophysiological Aspects

Primary aldosteronism (PA) is the most common cause of secondary hypertension. A growing body of evidence has suggested that, beyond its well-known effects on blood pressure and electrolyte balance, aldosterone excess can exert pro-inflammatory, pro-oxidant and pro-fibrotic effects on the kidney, blood vessels and heart, leading to potentially harmful pathophysiological consequences. In clinical studies, PA has been associated with an increased risk of cardiovascular, cerebrovascular, renal and metabolic complication compared to essential hypertension, including atrial fibrillation (AF) and aortic ectasia. An increased prevalence of AF in patients with PA has been demonstrated in several clinical studies. Aldosterone excess seems to be involved in the pathogenesis of AF by inducing cardiac structural and electrical remodeling that in turn predisposes to arrhythmogenicity. The association between PA and aortic ectasia is less established, but several studies have demonstrated an effect of aldosterone on aortic stiffness, vascular smooth muscle cells and media composition that, in turn, might lead to an increased risk of aortic dilation and dissection. In this review, we focus on the current evidence regarding the potential role of aldosterone excess in the pathogenesis of AF and aortic ectasia

High Frequency Electromagnetic Shielding by Biochar-Based Composites

We report on the microwave shielding efficiency of non-structural composites, where inclusions of biochar—a cost effective and eco-friendly material—are dispersed in matrices of interest for building construction. We directly measured the complex permittivity of raw materials and composites, in the frequency range 100 MHz–8 GHz. A proper permittivity mixing formula allows obtaining other combinations, to enlarge the case studies. From complex permittivity, finally, we calculated the shielding efficiency, showing that tailoring the content of biochar allows obtaining a desired value of electromagnetic shielding, potentially useful for different applications. This approach represents a quick preliminary evaluation tool to design composites with desired shielding properties starting from physical parameters

Neuroendocrine Alterations in Obese Patients with Sleep Apnea Syndrome

Obstructive sleep apnea syndrome (OSAS) is a serious, prevalent condition that has significant morbidity and mortality when untreated. It is strongly associated with obesity and is characterized by changes in the serum levels or secretory patterns of several hormones. Obese patients with OSAS show a reduction of both spontaneous and stimulated growth hormone (GH) secretion coupled to reduced insulin-like growth factor-I (IGF-I) concentrations and impaired peripheral sensitivity to GH. Hypoxemia and chronic sleep fragmentation could affect the sleep-entrained prolactin (PRL) rhythm. A disrupted Hypothalamus-Pituitary-Adrenal (HPA) axis activity has been described in OSAS. Some derangement in Thyroid-Stimulating Hormone (TSH) secretion has been demonstrated by some authors, whereas a normal thyroid activity has been described by others. Changes of gonadal axis are common in patients with OSAS, who frequently show a hypogonadotropic hypogonadism. Altogether, hormonal abnormalities may be considered as adaptive changes which indicate how a local upper airway dysfunction induces systemic consequences. The understanding of the complex interactions between hormones and OSAS may allow a multi-disciplinary approach to obese patients with this disturbance and lead to an effective management that improves quality of life and prevents associated morbidity or death