18 research outputs found
Synthesis and Crystal Structure of a Copper(II) Benzoate Complex Bearing a Bis-2,2′-Tetrahydrofuryl Peroxide Moiety
Get PDFComplex [Cu2(ben)4·2THF−(η1–O2)]∞ (2) (ben=C6H5CO2− benzoate; THF=tetrahydrofuran) was isolated when a solution of Cu2(ben)4·2THF (1) in THF upon natural sunlight irradiation yields crystals suitable for single-crystal X-ray diffraction analysis. 2, crystallized in the C2/c monoclinic space group, Z=8, V=3394.2 (4) Å3, and the unit cell parameters a=9.7935(7) Å, b=19.0055 (13) Å, c=18.2997 (13) Å, α=90°, β=94.7996 (11)º and γ=90°. This is the first example of a polymeric copper(II) carboxylate compound stabilizing a peroxo group via its apical ligand (THF molecule). Additionally, 2 was also characterized by elemental analysis, Fourier-transformed infrared spectroscopy (FTIR) and Raman spectroscopyUniversidad de Costa Rica/[804-B7-279]/UCR/Costa RicaUniversidad de Costa Rica/[804-B0-650]/UCR/Costa RicaUCR::Vicerrectoría de Docencia::Ciencias Básicas::Facultad de Ciencias::Escuela de QuímicaUCR::Vicerrectoría de Investigación::Unidades de Investigación::Ciencias Básicas::Centro de Investigación en Electroquímica y Energía Química (CELEQ
Cyclohexane oxidation: relationships of the process efficiency with electrical conductance, electronic and cyclic voltammetry spectra of the reaction mixture
No full textSelective functionalization of n-hexane with molecular O2 catalyzed by immobilized Cu/Co, Cu/Fe and Co/V complexes on modified Al2O3
No full textPreparation of MCM-41 Supported Salen Vanadium Complex and its Catalysis for the Oxidation of Cyclohexane with H2O2 as an Oxidant
No full textSynthesis of 13-Aryl Derivatives of the Sesquiterpene Lactone Argolide and their Analgesic Activity
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Catalytic activity of iron-substituted polyoxotungstates in the oxidation of aromatic compounds with hydrogen peroxide
No full textElectronic Effect of Substituent of Quinones on their Catalytic Performance in Hydrocarbons Oxidation
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