167 research outputs found
The electroclinic effect and modulated phases in smectic liquid crystals
We explore the possibility that the large electroclinic effect observed in
ferroelectric liquid crystals arises from the presence of an ordered array of
disclination lines and walls. If the spacing of these defects is in the
subvisible range, this modulated phase would be similar macroscopically to a
smectic A phase. The application of an electric field distorts the array,
producing a large polarization, and hence a large electroclinic effect. We show
that with suitable elastic parameters and sufficiently large chirality, the
modulated phase is favored over the smectic A and helically twisted smectic C*
phases. We propose various experimental tests of this scenario.Comment: 9 pages, 7 figures; new version includes dipolar interactions and
bend-twist couplin
A novel enzymatically-mediated drug delivery carrier for bone tissue engineering applications: combining biodegradable starch-based microparticles and differentiation agents
In many biomedical applications, the performance
of biomaterials depends largely on their degradation
behavior. For instance, in drug delivery applications, the
polymeric carrier should degrade under physiological
conditions slowly releasing the encapsulated drug. The aim
of this work was, therefore, to develop an enzymaticmediated
degradation carrier system for the delivery of
differentiation agents to be used in bone tissue engineering
applications. For that, a polymeric blend of starch with
polycaprolactone (SPCL) was used to produce a microparticle
carrier for the controlled release of dexamethasone
(DEX). In order to investigate the effect of enzymes on the
degradation behavior of the developed system and release
profile of the encapsulated osteogenic agent (DEX), the
microparticles were incubated in phosphate buffer solution
in the presence of a-amylase and/or lipase enzymes (at
physiological concentrations), at 37 C for different periods
of time. The degradation was followed by gravimetric
measurements, scanning electron microscopy (SEM) and
Fourier transformed infrared (FTIR) spectroscopy and the
release of DEX was monitored by high performance liquid
chromatography (HPLC). The developed microparticles
were shown to be susceptible to enzymatic degradation, as observed by an increase in weight loss and porosity with
degradation time when compared with control samples
(incubation in buffer only). For longer degradation times,
the diameter of the microparticles decreased significantly
and a highly porous matrix was obtained. The in vitro
release studies showed a sustained release pattern with
48% of the encapsulated drug being released for a period of
30 days. As the degradation proceeds, it is expected that
the remaining encapsulated drug will be completely
released as a consequence of an increasingly permeable
matrix and faster diffusion of the drug. Cytocompatibility
results indicated the possibility of the developed microparticles
to be used as biomaterial due to their reduced
cytotoxic effects
Magnetic Interactions and Transport in (Ga,Cr)As
The magnetic, transport, and structural properties of (Ga,Cr)As are reported.
Zincblende GaCrAs was grown by low-temperature molecular beam
epitaxy (MBE). At low concentrations, x0.1, the materials exhibit unusual
magnetic properties associated with the random magnetism of the alloy. At low
temperatures the magnetization M(B) increases rapidly with increasing field due
to the alignment of ferromagnetic units (polarons or clusters) having large
dipole moments of order 10-10. A standard model of
superparamagnetism is inadequate for describing both the field and temperature
dependence of the magnetization M(B,T). In order to explain M(B) at low
temperatures we employ a distributed magnetic moment (DMM) model in which
polarons or clusters of ions have a distribution of moments. It is also found
that the magnetic susceptibility increases for decreasing temperature but
saturates below T=4 K. The inverse susceptibility follows a linear-T
Curie-Weiss law and extrapolates to a magnetic transition temperature
=10 K. In magnetotransport measurements, a room temperature resistivity
of =0.1 cm and a hole concentration of cm
are found, indicating that Cr can also act as a acceptor similar to Mn. The
resistivity increases rapidly for decreasing temperature below room
temperature, and becomes strongly insulating at low temperatures. The
conductivity follows exp[-(T/T)] over a large range of
conductivity, possible evidence of tunneling between polarons or clusters.Comment: To appear in PRB 15 Mar 200
Recent Advances in Understanding Particle Acceleration Processes in Solar Flares
We review basic theoretical concepts in particle acceleration, with
particular emphasis on processes likely to occur in regions of magnetic
reconnection. Several new developments are discussed, including detailed
studies of reconnection in three-dimensional magnetic field configurations
(e.g., current sheets, collapsing traps, separatrix regions) and stochastic
acceleration in a turbulent environment. Fluid, test-particle, and
particle-in-cell approaches are used and results compared. While these studies
show considerable promise in accounting for the various observational
manifestations of solar flares, they are limited by a number of factors, mostly
relating to available computational power. Not the least of these issues is the
need to explicitly incorporate the electrodynamic feedback of the accelerated
particles themselves on the environment in which they are accelerated. A brief
prognosis for future advancement is offered.Comment: This is a chapter in a monograph on the physics of solar flares,
inspired by RHESSI observations. The individual articles are to appear in
Space Science Reviews (2011
Horizontal Branch Stars: The Interplay between Observations and Theory, and Insights into the Formation of the Galaxy
We review HB stars in a broad astrophysical context, including both variable
and non-variable stars. A reassessment of the Oosterhoff dichotomy is
presented, which provides unprecedented detail regarding its origin and
systematics. We show that the Oosterhoff dichotomy and the distribution of
globular clusters (GCs) in the HB morphology-metallicity plane both exclude,
with high statistical significance, the possibility that the Galactic halo may
have formed from the accretion of dwarf galaxies resembling present-day Milky
Way satellites such as Fornax, Sagittarius, and the LMC. A rediscussion of the
second-parameter problem is presented. A technique is proposed to estimate the
HB types of extragalactic GCs on the basis of integrated far-UV photometry. The
relationship between the absolute V magnitude of the HB at the RR Lyrae level
and metallicity, as obtained on the basis of trigonometric parallax
measurements for the star RR Lyrae, is also revisited, giving a distance
modulus to the LMC of (m-M)_0 = 18.44+/-0.11. RR Lyrae period change rates are
studied. Finally, the conductive opacities used in evolutionary calculations of
low-mass stars are investigated. [ABRIDGED]Comment: 56 pages, 22 figures. Invited review, to appear in Astrophysics and
Space Scienc
Herschel observations of EXtra-Ordinary Sources (HEXOS): Observations of H2O and its isotopologues towards Orion KL
We report the detection of more than 48 velocity-resolved ground rotational state transitions of H 16
2 O, H 18
2 O, and H 17
2 O â most for the first time
â in both emission and absorption toward Orion KL using Herschel/HIFI. We show that a simple fit, constrained to match the known emission
and absorption components along the line of sight, is in excellent agreement with the spectral profiles of all the water lines. Using the measured
H 18
2 O line fluxes, which are less affected by line opacity than their H 16
2 O counterparts, and an escape probability method, the column densities
of H 18
2 O associated with each emission component are derived. We infer total water abundances of 7.4 Ă 10â5, 1.0Ă 10â5, and 1.6 Ă 10â5 for the
plateau, hot core, and extended warm gas, respectively. In the case of the plateau, this value is consistent with previous measures of the Orion-KL
water abundance as well as those of other molecular outflows. In the case of the hot core and extended warm gas, these values are somewhat higher
than water abundances derived for other quiescent clouds, suggesting that these regions are likely experiencing enhanced water-ice sublimation
from (and reduced freeze-out onto) grain surfaces due to the warmer dust in these sources
Herschel observations of EXtra-Ordinary Sources (HEXOS): Detection of hydrogen fluoride in absorption towards Orion KL
We report a detection of the fundamental rotational transition of hydrogen fluoride in absorption towards Orion KL using Herschel/HIFI. After the
removal of contaminating features associated with common molecules (âweedsâ), the HF spectrum shows a P-Cygni profile, with weak redshifted
emission and strong blue-shifted absorption, associated with the low-velocity molecular outflow. We derive an estimate of 2.9 Ă 1013 cmâ2 for the
HF column density responsible for the broad absorption component. Using our best estimate of the H2 column density within the low-velocity
molecular outflow, we obtain a lower limit of âŒ1.6 Ă 10â10 for the HF abundance relative to hydrogen nuclei, corresponding to âŒ0.6% of the solar
abundance of fluorine. This value is close to that inferred from previous ISO observations of HF J = 2â1 absorption towards Sgr B2, but is in
sharp contrast to the lower limit of 6 Ă 10â9 derived by Neufeld et al. for cold, foreground clouds on the line of sight towards G10.6-0.4
Herschel observations of deuterated water towards Sgr B2(M)
Observations of HDO are an important complement for studies of water, because they give strong constraints on the formation processes â grain
surfaces versus energetic process in the gas phase, e.g. in shocks. The HIFI observations of multiple transitions of HDO in Sgr B2(M) presented
here allow the determination of the HDO abundance throughout the envelope, which has not been possible before with ground-based observations
only. The abundance structure has been modeled with the spherical Monte Carlo radiative transfer code RATRAN, which also takes radiative
pumping by continuum emission from dust into account. The modeling reveals that the abundance of HDO rises steeply with temperature from
a low abundance (2.5 Ă 10â11) in the outer envelope at temperatures below 100 K through a medium abundance (1.5 Ă 10â9) in the inner
envelope/outer core at temperatures between 100 and 200 K, and finally a high abundance ( 3.5 Ă 10â9) at temperatures above 200 K in the hot
core
- âŠ