Metal Toxicity During Short‐Term Sediment Resuspension and Redeposition in a Tropical Reservoir

Billings Complex is the largest water‐storage reservoir in São Paulo, Brazil, and has been contaminated since the 1960s. Periodically, Billings sediments are subjected to currents causing resuspension and subsequent release of metals. A short‐term (4‐h) resuspension was simulated using sediment flux exposure chambers (SeFECs) to better understand the fate, bioavailability, and transport of iron (Fe), manganese (Mn), and zinc (Zn) during these events, as well as possible organism toxicity. Daphnia magna and Hyalella azteca were exposed during the 4‐h resuspension, and were monitored after exposure for survival, growth, and reproduction. Resuspension rapidly deoxygenated the overlying water, decreased the pH, and resulted in elevated dissolved Zn above the US Environmental Protection Agency’s (2002) criteria for acute toxicity (120 µg L–1). However, Zn was scavenged (after 20 h) from solution as new sorption sites formed. Dissolved Mn increased during and after resuspension, with maximum values at 20 h post exposure. An initial release of Fe occurred, likely associated with oxidation of acid‐volatile sulfides, but decreased after 1 h of resuspension. The Fe decrease is likely due to precipitation as oxyhydroxides. No acute toxicity was observed during resuspension; however, mortality of D. magna and H. azteca occurred during the postexposure period. Daphnia magna also exhibited chronic toxicity, with decreased neonate production after exposure. This sublethal effect could lead to decreased zooplankton populations over a longer period in the reservoir. Environ Toxicol Chem 2019;38:1476–1485. © 2019 SETACConceptual model of metal (Me) speciation under different sediment redox states. During bedded conditions (A) metals are mainly bounded as insoluble sulfides or associated with organic carbon (OC). When resuspended (B), sulfide species are oxidized, mobilizing metals (such as Zn) into the overlying water (OW). However, the mobilized metal is scavenged by OC and freshly‐precipitated FexOx. As particles redeposit (C), and are returned to the benthic environment, further oxidation can occur in the aerobic sediment layer releasing Fe. High dissolved Fe concentrations in OW caused acute and chronic toxicity to D. magna. Ingestion of Zn caused growth inhibition and mortality to H. azteca.Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/149673/1/etc4434_am.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/149673/2/etc4434.pd

Localized electronic states and photoemission superconducting condensate in Bi2_{2}Sr2_{2}Ca1_{1}Cu2_{2}O8+x_{8+x}

We present the first detailed angle-resolved photoemission evidence that there are two types of carriers that contribute to the photoemission superconducting condensate in $Bi_{2}Sr_{2}Ca_{1}Cu_{2}O_{8+x}$. Our data indicate that both itinerant and somewhat localized normal state carriers can contribute to the formation of Cooper pairs.Comment: APS_Revtex, 11 pages, including 3 figures, available upon request. UW-Madison preprint#

A novel collaboratively designed robot to assist carers

© Springer International Publishing Switzerland 2014. This paper presents a co-design process and an assisted navigation strategy that enables a novel assistive robot, Smart Hoist, to aid carers transferring non-ambulatory residents. Smart Hoist was codesigned with residents and carers at IRT Woonona residential care facility to ensure that the device can coexist in the facility, while providing assistance to carers with the primary aim of reducing lower back injuries, and improving the safety of carers and patients during transfers.The Smart Hoist is equipped with simple interfaces to capture user intention in order to provide assisted manoeuvring. Using the RGB-D sensor attached to the device, we propose a method of generating a repulsive force that can be combined with the motion controller’s output to allow for intuitive manoeuvring of the Smart Hoist, while negotiating with the environment.Extensive user trials were conducted on the premises of IRTWoonona residential care facility and feedback from end users confirm its intended purpose of intuitive behaviour, improved performance and ease of use

Mirror-image relations in category learning

The discrimination of patterns that are mirror-symmetric counterparts of each other is difficult and requires substantial training. We explored whether mirror-image discrimination during expertise acquisition is based on associative learning strategies or involves a representational shift towards configural pattern descriptions that permit resolution of symmetry relations. Subjects were trained to discriminate between sets of unfamiliar grey-level patterns in two conditions, which either required the separation of mirror images or not. Both groups were subsequently tested in a 4-class category-learning task employing the same set of stimuli. The results show that subjects who had successfully learned to discriminate between mirror-symmetric counterparts were distinctly faster in the categorization task, indicating a transfer of conceptual knowledge between the two tasks. Additional computer simulations suggest that the development of such symmetry concepts involves the construction of configural, protoholistic descriptions, in which positions of pattern parts are encoded relative to a spatial frame of reference

‘Engage the World’: examining conflicts of engagement in public museums

Public engagement has become a central theme in the mission statements of many cultural institutions, and in scholarly research into museums and heritage. Engagement has emerged as the go-to-it-word for generating, improving or repairing relations between museums and society at large. But engagement is frequently an unexamined term that might embed assumptions and ignore power relationships. This article describes and examines the implications of conflicting and misleading uses of ‘engagement’ in relation to institutional dealings with contested questions about culture and heritage. It considers the development of an exhibition on the Dead Sea Scrolls by the Royal Ontario Museum, Toronto in 2009 within the new institutional goal to ‘Engage the World’. The chapter analyses the motivations, processes and decisions deployed by management and staff to ‘Engage the World’, and the degree to which the museum was able to re-think its strategies of public engagement, especially in relation to subjects,issues and publics that were more controversial in nature