Industrial wastewater treatment using hydrodynamic cavitation and heterogeneous advanced Fenton processing

A combination of hydrodynamic cavitation and heterogeneous advanced Fenton process (AFP) based on the use of zero valent iron as the catalyst has been investigated for the treatment of real industrial wastewater. The effect of various operating parameters such as inlet pressure, temperature, and the presence of copper windings on the extent of mineralization as measured by total organic carbon (TOC) content have been studied with the aim of maximizing the extent of degradation. It has been observed that increased pressures, higher operating temperature and the absence of copper windings are more favourable for a rapid TOC mineralization. A new approach of latent remediation has also been investigated where hydrodynamic cavitation is only used as a pre-treatment with an aim of reducing the overall cost of pollutant degradation. It has been observed that approach of latent remediation works quite well with about 50–60% removal of TOC using only minimal initial treatment by hydrodynamic cavitation

Intensification of hydroxyl radical production in sonochemical reactors

The efficacy of sonochemical reactors in chemical processing applications has been well established in the laboratory scale of operation though at a given set of operating parameters and no efforts have been directed in terms of maximizing the free radical production. In the present work, the effect of different operating parameters viz. pH, power dissipation into the system, effect of additives such as air, haloalkanes, titanium dioxide, iron and oxygen on the extent of hydroxyl radical formation in a sonochemical reactor have been investigated using salicylic acid dosimetry. Possible mechanisms for oxidation of salicylic acid in the presence of different additives have also been established. It has been observed that acidic conditions under optimized power dissipation in the presence of iron powder and oxygen result in maximum liberation of hydroxyl radicals as quantified by the kinetic rate constant for production of 2,5- and 2,3-dihydroxybenzoic acid. The study has enabled the optimization of the conditions for maximum efficacy of sonochemical reactors where free radical attack is the controlling mechanism for the chemical processing applications

Thermal Equilibration of 176-Lu via K-Mixing

In astrophysical environments, the long-lived (\T_1/2 = 37.6 Gy) ground state of 176-Lu can communicate with a short-lived (T_1/2 = 3.664 h) isomeric level through thermal excitations. Thus, the lifetime of 176-Lu in an astrophysical environment can be quite different than in the laboratory. We examine the possibility that the rate of equilibration can be enhanced via K-mixing of two levels near E_x = 725 keV and estimate the relevant gamma-decay rates. We use this result to illustrate the effect of K-mixing on the effective stellar half-life. We also present a network calculation that includes the equilibrating transitions allowed by K-mixing. Even a small amount of K-mixing will ensure that 176-Lu reaches at least a quasi-equilibrium during an s-process triggered by the 22-Ne neutron source.Comment: 9 pages, 6 figure

COMET: A Recipe for Learning and Using Large Ensembles on Massive Data

COMET is a single-pass MapReduce algorithm for learning on large-scale data. It builds multiple random forest ensembles on distributed blocks of data and merges them into a mega-ensemble. This approach is appropriate when learning from massive-scale data that is too large to fit on a single machine. To get the best accuracy, IVoting should be used instead of bagging to generate the training subset for each decision tree in the random forest. Experiments with two large datasets (5GB and 50GB compressed) show that COMET compares favorably (in both accuracy and training time) to learning on a subsample of data using a serial algorithm. Finally, we propose a new Gaussian approach for lazy ensemble evaluation which dynamically decides how many ensemble members to evaluate per data point; this can reduce evaluation cost by 100X or more

The hypersonic laminar boundary layer approaching the base of a slender body.

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/76455/1/AIAA-1968-67-699.pd

Estimation of Heart-Surface Potentials using Regularized Multipole Sources

Direct inference of heart-surface potentials from body-surface potentials has been the goal of most recent work on electrocardiographic inverse solutions. We developed and tested indirect methods for inferring heart-surface potentials based on estimation of regularized multipole sources. Regularization was done using Tikhonov, constrained-least-squares, and multipole-truncation techniques. These multipole-equivalent methods (MEMs) were compared to the conventional mixed boundary-value method (BVM) in a realistic torso model with up to 20% noise added to body-surface potentials and ±1 cm error in heart position and size. Optimal regularization was used for all inverse solutions. The relative error of inferred heart-surface potentials of the MEM was significantly less (p \u3c 0.05) than that of the BVM using zeroth-order Tikhonov regularization in 10 of the 12 cases tested. These improvements occurred with a fourth-degree (24 coefficients) or smaller multipole moment. From these multipole coefficients, heart-surface potentials can be found at an unlimited number of heart-surface locations. Our indirect methods for estimating heart-surface potentials based on multipole inference appear to offer significant improvement over the conventional direct approach

Intensification of oxidation capacity using chloroalkanes as additives in hydrodynamic and acoustic cavitation reactors

The effect of the presence and absence of the chloroalkanes, dichloromethane (CH2Cl2), chloroform (CHCl3) and carbon tetrachloride (CCl4) on the extent of oxidation of aqueous I- to I3- has been investigated in (a) a liquid whistle reactor (LWR) generating hydrodynamic cavitation and (b) an ultrasonic probe, which produces acoustic cavitation. The aim has been to examine the intensification achieved in the extent of oxidation due to the generation of additional free radicals/oxidants in the reactor as a result of the presence of chloroalkanes. It has been observed that the extent of increase in the oxidation reaction is strongly dependent on the applied pressure in the case of the LWR. Also, higher volumes of the chloroalkanes favour the intensification and the order of effectiveness is CCl4> CHCl3 > CH2Cl2. However, the results with the ultrasonic probe suggest that an optimum concentration of CH2Cl2 or CHCl3 exists beyond which there is little increase in the extent of observed intensification. For CCl4, however, no such optimum concentration was observed and the extent of increase in the rates of oxidation reaction rose with the amount of CCl4 added. Stage wise addition of the chloroalkanes was found to give marginally better results in the case of the ultrasonic probe as compared to bulk addition at the start of the run. Although CCl4 is the most effective, its toxicity and carcinogenicity may mean that CH2Cl2 and CHCl3 offer a safer viable alternative and the present work should be useful in establishing the amount of chloroalkanes required for obtaining a suitable degree of intensification

Generation of Synthetic-Focus Images from Pulse-Echo Ultrasound using Difference Equations

To produce a complete-dataset, pulse-echo image requires a knowledge of the time of flight (TOF) from each source to each sensor in the transducer array for each site to be imaged. Increasing the speed of TOF calculation is important in adaptive-focus schemes. The authors determined TOF more rapidly than via direct calculation by representing TOF surfaces by two-dimensional (2-D), positive-integer-degree polynomials implemented in their forward-difference form. Errors which accumulate due to the use of a difference equation depend on the degree of the polynomial and on the size of the image. The number of bits needed to address echo samples in backscatter memory and the allowable error define the minimum precision needed for accurate values of TOF, Accurate calculation of TOF, expressed as 10-b addresses in backscatter memory, for each pixel in a 512 x 512 image with a second-degree difference equation requires 44 b of precision, Using the complete dataset from a 32-element array and a second-degree approximation to TOF on a typical graphics workstation reduced generation time of a 512 x 512 image from 702 to 239 s. Parallel formulation of both the TOF calculation and the retrieval and summation of echo samples resulted in significant further reduction in image-generation time. Parallel implementation on a SIMD array with 4096 processors, each of which had an indirect-addressing mode, allowed the generation of a 512 x 512 image in 16.3 s