Iron oxide nanoparticles fabricated by electric explosion of wire: Focus on magnetic nanofluids

Nanoparticles of iron oxides (MNPs) were prepared using the electric explosion of wire technique (EEW). The main focus was on the fabrication of de-aggregated spherical nanoparticles with a narrow size distribution. According to XRD the major crystalline phase was magnetite with an average diameter of MNPs, depending on the fraction. Further separation of air-dry EEW nanoparticles was performed in aqueous suspensions. In order to provide the stability of magnetite suspension in water, we found the optimum concentration of the electrostatic stabilizer (sodium citrate and optimum pH level) based on zeta-potential measurements. The stable suspensions still contained a substantial fraction of aggregates which were disintegrated by the excessive ultrasound treatment. The separation of the large particles out of the suspension was performed by centrifuging. The structural features, magnetic properties and microwave absorption of MNPs and their aqueous solutions confirm that we were able to obtain an ensemble in which the magnetic contributions come from the spherical MNPs. The particle size distribution in fractionated samples was narrow and they showed a similar behaviour to that expected of the superparamagnetic ensemble. Maximum obtained concentration was as high as 5 % of magnetic material (by weight). Designed assembly of de-aggregated nanoparticles is an example of on-purpose developed magnetic nanofluid. Copyright © 2012 Author(s)

Magnetic properties and giant magnetoimpedance effect for CoFeMoSiB surface modified amorphous ribbons covered by water based ferrofluid

Giant magnetoimpedance (GMI) effect is a powerful technique for magnetic label detection. Co-based amorphous ribbons are cheap materials showing high GMI effect at low operation frequencies for close to zero magnitostriction compositions. In this work magnetic properties and GMI were studied for CoFeMoSiB amorphous ribbons in as-quenched and surface modified states without and in the presence of water-based ferrofluid with electrostatic stabilization of γ-Fe2O3 nanoparticles. Surface modification by ultrasound treatment resulted in appearance of round defects with average diameter of about 150 micrometers. The GMI difference for as-quenched ribbons in absence and in the presence of ferrofluid was measured for the frequency range of 0.5 to 10 MHz. Although proposed surface modification by the ultrasound treatment did not improve the sensitivity limit for ferrofluid detection, it did not decrease it either. Observed changes of GMI are useful for understanding of functionality of GMI biosensors. © 2018 The Authors, published by EDP Sciences.The work was supported in part by the Government of the B is acknowledged for financial support under th e Elkartek Program, the Project Micro4Fab (KK -206/01 30)00 and the Ministry of dE ucation and Science of the RF Project N 055 , within the state job 3.21.61 20/17.9 . We thank I.V. Beketov , A.I . Medvedev and A. Larr anga for special support. Selected measurements were made at SGIKER services of .UPV/EH

An evolution equation as the WKB correction in long-time asymptotics of Schrodinger dynamics

We consider 3d Schrodinger operator with long-range potential that has short-range radial derivative. The long-time asymptotics of non-stationary problem is studied and existence of modified wave operators is proved. It turns out, the standard WKB correction should be replaced by the solution to certain evolution equation.Comment: This is a preprint of an article whose final and definitive form has been published in Comm. Partial Differential Equations, available online at http://www.informaworld.co

Planetary migration in evolving planetesimals discs

In the current paper, we further improved the model for the migration of planets introduced in Del Popolo et al. (2001) and extended to time-dependent planetesimal accretion disks in Del Popolo and Eksi (2002). In the current study, the assumption of Del Popolo and Eksi (2002), that the surface density in planetesimals is proportional to that of gas, is released. In order to obtain the evolution of planetesimal density, we use a method developed in Stepinski and Valageas (1997) which is able to simultaneously follow the evolution of gas and solid particles for up to 10^7 yrs. Then, the disk model is coupled to migration model introduced in Del Popolo et al. (2001) in order to obtain the migration rate of the planet in the planetesimal. We find that the properties of solids known to exist in protoplanetary systems, together with reasonable density profiles for the disk, lead to a characteristic radius in the range 0.03-0.2 AU for the final semi-major axis of the giant planet.Comment: IJMP A in prin

Preparation of alumina nanoparticle suspensions with narrow particle size distribution

Dynamic light scattering (DLS) was applied to the study of the process of the preparing deaggregated water suspensions of alumina nanopowders with specific surface areas of 20-140 m2/g. Nanopowders were prepared by the electric explosion of wire and laser evaporation and, according to electron microscopy (TEM), consisted of nonagglomerated spherical nanoparticles with lognormal size distribution. According to DLS, nonsedimenting water suspensions of alumina nanoparticles, stabilized by sodium citrate at a 5 mM concentration, contain substantial fraction of aggregates. The dynamics of the change in the mean average size of aggregates under exhaustive ultrasound treatment of suspensions with 10 g/l concentration for 1.5-4 h by two types of ultrasonic processors was studied. It was shown that the mean average size of aggregates exponentially diminishes by 1.5-2 times and the fraction of individual particles in suspension enlarges from 45 to 85%. Sequentially centrifuging the suspension at 18000 g separates the remaining aggregates and results in suspensions of individual alumina nanoparticles. Particle size distributions in these suspensions obtained by TEM and DLS are the same within experimental error. © 2013 Pleiades Publishing, Ltd