44,663 research outputs found
A molecular dynamics computer simulation study of room-temperature ionic liquids. I. Equilibrium solvation structure and free energetics
Solvation in 1-ethyl-3-methylmidazolium chloride and in
1-ethyl-3-methylimidazolium hexafluorophosphate near equilibrium is
investigated via molecular dynamics computer simulations with diatomic and
benzenelike molecules employed as probe solutes. It is found that
electrostriction plays an important role in both solvation structure and free
energetics. The angular and radial distributions of cations and anions become
more structured and their densities near the solute become enhanced as the
solute charge separation grows. Due to the enhancement in structural rigidity
induced by electrostriction, the force constant associated with solvent
configuration fluctuations relevant to charge shift and transfer processes is
also found to increase. The effective polarity and reorganization free energies
of these ionic liquids are analyzed and compared with those of highly polar
acetonitrile. Their screening behavior of electric charges is also
investigated.Comment: 12 page
Dynamic model for failures in biological systems
A dynamic model for failures in biological organisms is proposed and studied
both analytically and numerically. Each cell in the organism becomes dead under
sufficiently strong stress, and is then allowed to be healed with some
probability. It is found that unlike the case of no healing, the organism in
general does not completely break down even in the presence of noise. Revealed
is the characteristic time evolution that the system tends to resist the stress
longer than the system without healing, followed by sudden breakdown with some
fraction of cells surviving. When the noise is weak, the critical stress beyond
which the system breaks down increases rapidly as the healing parameter is
raised from zero, indicative of the importance of healing in biological
systems.Comment: To appear in Europhys. Let
Dynamic model of fiber bundles
A realistic continuous-time dynamics for fiber bundles is introduced and
studied both analytically and numerically. The equation of motion reproduces
known stationary-state results in the deterministic limit while the system
under non-vanishing stress always breaks down in the presence of noise.
Revealed in particular is the characteristic time evolution that the system
tends to resist the stress for considerable time, followed by sudden complete
rupture. The critical stress beyond which the complete rupture emerges is also
obtained
The effect of supersymmetric CP phases on Chargino-Pair Production via Drell-Yan Process at the LHC
We compute the rates for pp annihilation into chargino-pairs via Drell-Yan
process taking into account the effects of supersymmetric soft phases, at
proton-proton collider. In particular, the phase of the mu parameter gains
direct accessibility via the production of dissimilar charginos. The phases of
the trilinear soft masses do not have a significant effect on the cross
sections.Comment: 24 pages, 7 figure
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