The vertical distribution of iron stable isotopes in the North Atlantic near Bermuda

Seawater dissolved iron isotope ratios (δ^(56)Fe) have been measured in the North Atlantic near Bermuda. In a full-depth profile, seawater dissolved δ^(56)Fe is isotopically heavy compared to crustal values throughout the water column (δ^(56)Fe_(IRMM-014) = +0.30‰ to +0.71‰). Iron isotope ratios are relatively homogenous in the upper water column (between +0.30‰ to +0.45‰ above 1500 m), and δ^(56)Fe increases below this to a maximum of +0.71‰ at 2500 m, decreasing again to +0.35‰ at 4200 m. The δ^(56)Fe profile is very different from the iron concentration profile; in the upper water column [Fe] is variable while δ^(56)Fe is relatively constant, and in the deeper water column δ^(56)Fe varies while [Fe] remains relatively constant. The δ^(56)Fe profile is also not well correlated with other hydrographic tracers in the North Atlantic such as temperature, salinity, or the concentrations of oxygen, phosphate, silica, and CFC-11. The dissimilarity between δ^(56)Fe profiles and profiles of [Fe] and other hydrographic tracers shows that Fe isotope ratios provide a unique sort of information about ocean chemistry, and they suggest that Fe isotopes may therefore be a valuable new tool for tracing the global sources, sinks, and biogeochemical cycling of Fe

The First Molecular Electronic Hyperpolarizabilities of Highly Polarizable Organic Molecules: 2,6-Di-tert-butylindoanilines

The first molecular hyperpolarizabilities (β) of a series of 2,6-di-tert-butylindoanilines, measured by electric-field-induced second harmonic generation are somewhat more sensitive to donor strength than was found for analogously substituted nitrostilbenes, and dimethylindoaniline has a β roughly twice that of its 2,6 di-tert-butylated analogue, measured in chloroform; solvatochromic measurements on the former compound suggest that this decrease in hyperpolarizability is consistent with a bound-solvent effect

The Effect of varying Ground-state Aromaticity on the First Molecular Electronic Hyperpolarizabilites of Organic Donor-Acceptor Molecules

A series of compounds of the form 4-dimethylaminophenyl–polyene–acceptor, where the polyene ranges from nothing to all-trans-1,3,5-hexatriene and the acceptor is 2-nitrovinyl, formyl, or 2,2-dicyanovinyl has been prepared and their β values measured by solution electric-field-induced second-harmonic generation; these molecules, which lose only one aromatic resonance upon charge-transfer excitation, show enhanced β compared to bi-aromatic molecules with the same substitution and total conjugation length, such as 4-dimethylamino-4′-nitrostilbene (DANS), a well-known benchmark for high β organic molecules

Causal connectivity of evolved neural networks during behavior

To show how causal interactions in neural dynamics are modulated by behavior, it is valuable to analyze these interactions without perturbing or lesioning the neural mechanism. This paper proposes a method, based on a graph-theoretic extension of vector autoregressive modeling and 'Granger causality,' for characterizing causal interactions generated within intact neural mechanisms. This method, called 'causal connectivity analysis' is illustrated via model neural networks optimized for controlling target fixation in a simulated head-eye system, in which the structure of the environment can be experimentally varied. Causal connectivity analysis of this model yields novel insights into neural mechanisms underlying sensorimotor coordination. In contrast to networks supporting comparatively simple behavior, networks supporting rich adaptive behavior show a higher density of causal interactions, as well as a stronger causal flow from sensory inputs to motor outputs. They also show different arrangements of 'causal sources' and 'causal sinks': nodes that differentially affect, or are affected by, the remainder of the network. Finally, analysis of causal connectivity can predict the functional consequences of network lesions. These results suggest that causal connectivity analysis may have useful applications in the analysis of neural dynamics

Are We Understating the Impact of Economic Conditions on Welfare Rolls?

In this brief we argue that welfare participation is more sensitive to economic conditions than previously believed. Why? Prior research focused on short-term economic fluctuations and ignored differences between high- and low-skilled workers. As welfare is long-term (i.e., permanent) it makes more sense to make comparisons with long-term economic trends. Also, since low-skilled workers are more likely to end up on welfare, it is proper to focus on their economic opportunities. Thus, we focus on the long-term impact of economic conditions on welfare participation, and we concentrate our analysis on low-skilled workers. Specifically, we analyze long-term changes in the supply of high-paying jobs for coal and steel workers as they affect certain heavy coal- and steel-producing regions of the United States during the 1970s and 1980s. Our findings indicate that welfare participation in these regions closely mirrors the long-term local availability of high-paying jobs for low-skilled workers. This has serious policy implications for the long-term success of welfare reform.

Al-Qaeda’s Persistent Sanctuary

With growing instability across the Arab world, it has become de rigueur to argue that the primary al-Qaeda threat now comes from the Persian Gulf or North Africa. While these regions certainly present a threat to Western security, al-Qaeda’s primary command and control structure remains situated in the Pakistan-Afghanistan border regions. Since the mid-1990s, al-Qaeda’s senior leadership has enjoyed a sanctuary in Afghanistan and Pakistan. Today, al-Qaeda continues to present a grave threat from this region by providing strategic guidance, overseeing or encouraging terrorist operations, managing a robust propaganda campaign, conducting training and collecting and distributing financial assistance. As demonstrated over the past year, key al-Qaeda operatives such as Ilyas Kashmiri have been involved in plots to conduct Mumbai-style attacks in Europe, target a newspaper in Copenhagen that published cartoons of the Prophet Muhammad and bomb New York. The US, for example, has narrowly escaped several imminent attacks. Faisal Shahzad, who was trained in Pakistan, constructed several bombs, placed them in the back of his Nissan Pathfinder sports utility vehicle and drove into Times Square in New York City on a congested Saturday night in 2010. Only fortune intervened, since all three bombs malfunctioned. It may be tempting to focus predominantly on terrorist threats to the West from Libya, Yemen, Somalia, Egypt and other countries in the Arab world because of the widespread unrest and on-going violence, but this would be a dangerous mistake

First Measurement of the Electromagnetic Form Factor of the Neutral Kaon at a Large Momentum Transfer and the Effect of SU(3)SU(3) Breaking

At large momentum transfers the photon interacts with the charges and spins of the constituent partons in a hadron. It is expected that the neutral kaon can acquire finite electromagnetic form factors because its wave function is affected by the order of magnitude difference between the mass of the strange quark and that of the down quark, or flavor $SU(3)$ breaking. We report on the first measurement of the form factor of neutral kaons at the large timelike momentum transfer of $|Q^2|=17.4$ GeV$^2$ by measuring the cross section for $e^+e^-\to K_SK_L$ at $\sqrt{s}=4.17$ GeV using CLEO-c data with an integrated luminosity of 586 pb$^{-1}$. We obtain $F_{K_SK_L}(17.4~\textrm{GeV}^2)=5.3\times10^{-3}$, with a 90% C.L. interval of $(2.9-8.2)\times10^{-3}$. This is nearly an order of magnitude smaller than $F_{K^+K^-}(17.4~\textrm{GeV}^2)=(44\pm1)\times10^{-3}$, and indicates that the effect of $SU(3)$ breaking is small. In turn, this makes it unlikely that the recently observed strong violation of the pQCD prediction, $F_{\pi^+\pi^-}(|Q^2|)/F_{K^+K^-}(|Q^2|)=f_\pi^2/f_K^2$, which is based on the assumption of similar wave functions for the pions and kaons, can be attributed to $SU(3)$ breaking alone.Comment: 4 pages, 2 figures, accepted to PL