Evaluation of true interlamellar spacing from microstructural observations

A method for evaluating true interlamellar spacing from micrographs is proposed for a multidomained lamellar structure. The microstructure of these materials is assumed to be composed of many domains with the lamellae aligned roughly parallel to each other within each domain and with the domains themselves randomly oriented relative to one another. An explicit expression for the distribution of apparent interlamellar spacing is derived assuming that the distribution of the true interlamellar spacing is Gaussian. The average interlamellar spacing is close to the peak interlamellar spacing observed in the distribution. The theoretical distributions are compared with experimental ones obtained by analyzing micrographs of PbTe–Sb2Te3 lamellar composites

Zone Leveling Crystal Growth of Thermoelectric PbTe Alloys with Sb_(2)Te_3 Widmanstätten Precipitates

Unidirectional solidification of PbTe-rich alloys in the pseudobinary PbTe-Sb_(2)Te_3 system using the zone leveling technique enables the production of large regions of homogeneous solid solutions for the formation of precipitate nanocomposites as compared with Bridgman solidification. (PbTe)_(0.940)(Sb_(2)Te_3)_(0.060) and (PbTe)_(0.952)(Sb_(2)Te_3)_(0.048) alloys were successfully grown using (PbTe)_(0.4)(Sb_(2)Te_3)_(0.6) and (PbTe)_(0.461)(Sb_(2)Te_3)_(0.539) as seed alloys, respectively, with 1 mm h^(–1) withdrawal velocity. In the unidirectionally solidified regions of both alloys, Widmanstatten precipitates are formed due to the decrease in solubility of Sb_(2)Te_3 in PbTe. To determine the compositions of the seed alloys for the zone leveling experiments, the solute distribution in solidification in the PbTe-richer part of the pseudobinary PbTe-Sb_(2)Te_3 system has been examined from the concentration profiles in the samples unidirectionally solidified by the Bridgman method

Vortex-lattice melting in two-dimensional superconductors in intermediate fields

To examine the field dependence of the vortex lattice melting transition in two-dimensional (2D) superconductors, Monte Carlo simulations of the 2D Ginzburg-Landau (GL) model are performed by extending the conventional lowest Landau level (LL) approximation to include several {\it higher} LL modes of the superconducting order parameter with LL indices up to six. It is found that a nearly vertical melting line in lower fields, which is familiar within the elastic theory, is reached just by including higher LL modes with LL indices less than five, and that the first order character of the melting transition in higher fields is significantly weakened with decreasing the field. Nevertheless, a genuine crossover to the consecutive continuous melting picture intervened by a hexatic liquid is not found within the use of the GL model.Comment: 6 pages, 7 figures. To appear in Phys. Rev.

Rapid consolidation of powdered materials by induction hot pressing

A rapid hot press system in which the heat is supplied by RF induction to rapidly consolidate thermoelectric materials is described. Use of RF induction heating enables rapid heating and consolidation of powdered materials over a wide temperature range. Such rapid consolidation in nanomaterials is typically performed by spark plasma sintering (SPS) which can be much more expensive. Details of the system design, instrumentation, and performance using a thermoelectric material as an example are reported. The Seebeck coefficient, electrical resistivity, and thermal diffusivity of thermoelectric PbTe material pressed at an optimized temperature and time in this system are shown to agree with material consolidated under typical consolidation parameters

Effective thermal conductivity of polycrystalline materials with randomly oriented superlattice grains

A model has been established for the effective thermal conductivity of a bulk polycrystal made of randomly oriented superlattice grains with anisotropic thermal conductivity. The in-plane and cross-plane thermal conductivities of each superlattice grain are combined using an analytical averaging rule that is verified using finite element methods. The superlattice conductivities are calculated using frequency dependent solutions of the Boltzmann transport equation, which capture greater thermal conductivity reductions as compared to the simpler gray medium approximation. The model is applied to a PbTe/Sb_2Te_3 nanobulk material to investigate the effects of period, specularity, and temperature. The calculations show that the effective thermal conductivity of the polycrystal is most sensitive to the in-plane conductivity of each superlattice grain, which is generally four to five times larger than the cross-plane conductivity of a grain. The model is compared to experimental measurements of the same system for periods ranging from 287 to 1590 nm and temperatures from 300 to 500 K. The comparison suggests that the effective specularity increases with increasing annealing temperature and shows that these samples are in a mixed regime where both Umklapp and boundary scattering are important

Self-interactions in a topological BF-type model in D=5

All consistent interactions in five spacetime dimensions that can be added to a free BF-type model involving one scalar field, two types of one-forms, two sorts of two-forms, and one three-form are investigated by means of deforming the solution to the master equation with the help of specific cohomological techniques. The couplings are obtained on the grounds of smoothness, locality, (background) Lorentz invariance, Poincar\'{e} invariance, and the preservation of the number of derivatives on each field.Comment: LaTeX, 57 pages, final version, matching the published pape

Geometric Langevin equations on submanifolds and applications to the stochastic melt-spinning process of nonwovens and biology

In this article we develop geometric versions of the classical Langevin equation on regular submanifolds in euclidean space in an easy, natural way and combine them with a bunch of applications. The equations are formulated as Stratonovich stochastic differential equations on manifolds. The first version of the geometric Langevin equation has already been detected before by Leli\`evre, Rousset and Stoltz with a different derivation. We propose an additional extension of the models, the geometric Langevin equations with velocity of constant absolute value. The latters are seemingly new and provide a galaxy of new, beautiful and powerful mathematical models. Up to the authors best knowledge there are not many mathematical papers available dealing with geometric Langevin processes. We connect the first version of the geometric Langevin equation via proving that its generator coincides with the generalized Langevin operator proposed by Soloveitchik, Jorgensen and Kolokoltsov. All our studies are strongly motivated by industrial applications in modeling the fiber lay-down dynamics in the production process of nonwovens. We light up the geometry occuring in these models and show up the connection with the spherical velocity version of the geometric Langevin process. Moreover, as a main point, we construct new smooth industrial relevant three-dimensional fiber lay-down models involving the spherical Langevin process. Finally, relations to a class of self-propelled interacting particle systems with roosting force are presented and further applications of the geometric Langevin equations are given

QP-Structures of Degree 3 and 4D Topological Field Theory

A A BV algebra and a QP-structure of degree 3 is formulated. A QP-structure of degree 3 gives rise to Lie algebroids up to homotopy and its algebraic and geometric structure is analyzed. A new algebroid is constructed, which derives a new topological field theory in 4 dimensions by the AKSZ construction.Comment: 17 pages, Some errors and typos have been correcte

Topological Field Theories and Geometry of Batalin-Vilkovisky Algebras

The algebraic and geometric structures of deformations are analyzed concerning topological field theories of Schwarz type by means of the Batalin-Vilkovisky formalism. Deformations of the Chern-Simons-BF theory in three dimensions induces the Courant algebroid structure on the target space as a sigma model. Deformations of BF theories in $n$ dimensions are also analyzed. Two dimensional deformed BF theory induces the Poisson structure and three dimensional deformed BF theory induces the Courant algebroid structure on the target space as a sigma model. The deformations of BF theories in $n$ dimensions induce the structures of Batalin-Vilkovisky algebras on the target space.Comment: 25 page

Thermal fluctuations and disorder effects in vortex lattices

We calculate using loop expansion the effect of fluctuations on the structure function and magnetization of the vortex lattice and compare it with existing MC results. In addition to renormalization of the height of the Bragg peaks of the structure function, there appears a characteristic saddle shape ''halos'' around the peaks. The effect of disorder on magnetization is also calculated. All the infrared divergencies related to soft shear cancel.Comment: 10 pages, revtex file, one figur