Transition from a simple yield stress fluid to a thixotropic material

From MRI rheometry we show that a pure emulsion can be turned from a simple yield stress fluid to a thixotropic material by adding a small fraction of colloidal particles. The two fluids have the same behavior in the liquid regime but the loaded emulsion exhibits a critical shear rate below which no steady flows can be observed. For a stress below the yield stress, the pure emulsion abruptly stops flowing, whereas the viscosity of the loaded emulsion continuously increases in time, which leads to an apparent flow stoppage. This phenomenon can be very well represented by a model assuming a progressive increase of the number of droplet links via colloidal particles.Comment: Published in Physical Review E. http://pre.aps.org/abstract/PRE/v76/i5/e05140

Flow induced by a sphere settling in an aging yield-stress fluid

We have studied the flow induced by a macroscopic spherical particle settling in a Laponite suspension that exhibits a yield-stress, thixotropy and shear-thinning. We show that the fluid thixotropy (or aging) induces an increase with time of both the apparent yield stress and shear-thinning properties but also a breaking of the flow fore-aft symmetry predicted in Hershel-Bulkley fluids (yield-stress, shear-thinning fluids with no thixotropy). We have also varied the stress exerted by the particles on the fluid by using particles of different densities. Although the stresses exerted by the particles are of the same order of magnitude, the velocity field presents utterly different features: whereas the flow around the lighter particle shows a confinement similar to the one observed in shear-thinning fluids, the wake of the heavier particle is characterized by an upward motion of the fluid ("negative wake"), whatever the fluid's age. We compare the features of this negative wake to the one observed in viscoelastic shear-thinning fluids (polymeric or micelle solutions). Although the flows around the two particles strongly differ, their settling behaviors display no apparent difference which constitutes an intriguing result and evidences the complexity of the dependence of the drag factor on flow field