Polyhedral Oligomeric Silsesquioxane Based Catalyst for the Efficient Synthesis of Cyclic Carbonates

In this work, the synthesis of a novel imidazolium-based polyhedral oligomeric silsesquioxane (POSS-mim-Cl) material is presented. The new nanometer-size organosilica based compound was employed for chemical fixation of CO2 into epoxide under homogeneous conditions. The target reaction was represented by the obtention of cyclic carbonates starting from epoxides and CO2. Particularly, styrene oxide was chosen as reference substrate. In addition, different parameters (solvent, temperature, pressure of CO2, and mass of the catalyst) were modified to find the best condition for CO2 conversion. The catalyst POSS-mim-Cl displayed good catalytic performances, the best results being obtained at 40 bar of CO2, 150\ub0C, with 110 mg of catalyst and using isopropanol as co-solvent. It is worth to mention that POSS-mim-Cl displayed better catalytic performance than the corresponding 1-butyl-3-methyl imidazolium chloride. As far as we know this study represents the first use of imidazolium-based POSS as catalysts for the chemical fixation of CO2

Tribological properties of room temperature fluorinated graphite heat-treated under fluorine atmosphere

This work is concerned with the study of the tribologic properties of room temperature fluorinated graphite heat-treated under fluorine atmosphere. The fluorinated compounds all present good intrinsic friction properties (friction coefficient in the range 0.05–0.09). The tribologic performances are optimized if the materials present remaining graphitic domains (influenced by the presence of intercalated fluorinated species) whereas the perfluorinated compounds, where the fluorocarbon layers are corrugated (armchair configuration of the saturated carbon rings) present higher friction coefficients. Raman analyses reveal that the friction process induces severe changes in the materials structure especially the partial re-building of graphitic domains in the case of perfluorinated compounds which explains the improvement of μ during the friction tests for these last materials

Modelling the species jump: towards assessing the risk of human infection from novel avian influenzas

The scientific understanding of the driving factors behind zoonotic and pandemic influenzas is hampered by complex interactions between viruses, animal hosts and humans. This complexity makes identifying influenza viruses of high zoonotic or pandemic risk, before they emerge from animal populations, extremely difficult and uncertain. As a first step towards assessing zoonotic risk of Influenza, we demonstrate a risk assessment framework to assess the relative likelihood of influenza A viruses, circulating in animal populations, making the species jump into humans. The intention is that such a risk assessment framework could assist decisionmakers to compare multiple influenza viruses for zoonotic potential and hence to develop appropriate strain-specific control measures. It also provides a first step towards showing proof of principle for an eventual pandemic risk model. We show that the spatial and temporal epidemiology is as important in assessing the risk of an influenza A species jump as understanding the innate molecular capability of the virus.We also demonstrate data deficiencies that need to be addressed in order to consistently combine both epidemiological and molecular virology data into a risk assessment framework

Italian politics in an era of recession : the end of bipolarism?

Italian politics have undergone momentous change in the 2007–2017 decade under the impact of the eurozone crisis, whose peak in 2011–2013 could be equated to the earlier watershed years of 1992–1994. The lasting impact of the upheaval in Italian politics in the early 1990s could still be felt in the decade of economic recession, but there were also new challenges prompted by a crisis that had its roots in international financial contagion and which unravelled under the shadow of both recession and austerity. The changes were of an economic, social, cultural, institutional, policy-oriented and political nature. If one central quintessentially political theme stands out by the end of this decade it is the apparent exhaustion of the quest for bipolarisation that was initiated in the early 1990s

Hall Normalization Constants for the Bures Volumes of the n-State Quantum Systems

We report the results of certain integrations of quantum-theoretic interest, relying, in this regard, upon recently developed parameterizations of Boya et al of the n x n density matrices, in terms of squared components of the unit (n-1)-sphere and the n x n unitary matrices. Firstly, we express the normalized volume elements of the Bures (minimal monotone) metric for n = 2 and 3, obtaining thereby "Bures prior probability distributions" over the two- and three-state systems. Then, as an essential first step in extending these results to n > 3, we determine that the "Hall normalization constant" (C_{n}) for the marginal Bures prior probability distribution over the (n-1)-dimensional simplex of the n eigenvalues of the n x n density matrices is, for n = 4, equal to 71680/pi^2. Since we also find that C_{3} = 35/pi, it follows that C_{4} is simply equal to 2^{11} C_{3}/pi. (C_{2} itself is known to equal 2/pi.) The constant C_{5} is also found. It too is associated with a remarkably simple decompositon, involving the product of the eight consecutive prime numbers from 2 to 23. We also preliminarily investigate several cases, n > 5, with the use of quasi-Monte Carlo integration. We hope that the various analyses reported will prove useful in deriving a general formula (which evidence suggests will involve the Bernoulli numbers) for the Hall normalization constant for arbitrary n. This would have diverse applications, including quantum inference and universal quantum coding.Comment: 14 pages, LaTeX, 6 postscript figures. Revised version to appear in J. Phys. A. We make a few slight changes from the previous version, but also add a subsection (III G) in which several variations of the basic problem are newly studied. Rather strong evidence is adduced that the Hall constants are related to partial sums of denominators of the even-indexed Bernoulli numbers, although a general formula is still lackin

The Burden of Risk: Early Modern Maritime Enterprise and Varieties of Capitalism

This is the author accepted manuscript. The final version is available from Cambridge University Press via the DOI in this record.This essay will discuss the complex issues behind the relation between national and global economic histories, and the challenges of a comparative approach. Discussing different national approaches – Italian and English – to the management of the early modern maritime sector, it will argue that this comparison allows a privileged window into different varieties of capitalism, highlighting fundamental differences in the attitudes towards wage labour and risk management, which still today influence different approaches to economic activities.European Research Council (ERC

Afterword

This is the author accepted manuscript. The final version is available from Palgrave Macmillan via the DOI in this recordThis volume is one of the outcomes of the European Research Council-funded project ‘Sailing into Modernity: Comparative Perspectives on the Sixteenth- and Seventeenth-Century European Economic Transition’. The primary goal of this collaborative and comparative project has been to investigate the legal and economic status of seafarers in the Mediterranean during the ‘long’ seventeenth century (1570–1730). Through a study of the contractual conditions and economic treatment of sailors active in the Mediterranean, the project has been testing the hypothesis that differences in this regard were one of the factors in the ultimate success of northern European economies in their commercial penetration of the Mediterranean. This volume encompasses a much wider scope, as its goal is to present the current state of the art on these issues on a global stage. Essays by established academics and early-career scholars from three continents present research on three maritime regions — the Mediterranean, the Atlantic, and the Indian Ocean — over three centuries, with some of the contributions extending this chronological range even further

Agents of empire: knights, corsairs, Jesuits, and spies in the sixteenth-century Mediterranean world

This is the author accepted manuscrip

Design of urban furniture to enhance the soundscape: A case study

In modern urban scenarios all the aspects of the historical heritage, including public open spaces and ancient buildings, have to meet the high increase of density of infrastructures and constructions, with the consequent change of visual and sound environments. This in turn affects people’s quality of life. Because of the growing interest on this problem, this study investigates the relationship between soundscape and design solutions for urban furniture, considering technical and environmental feasibility of the designing process, from the materials characteristics, to the acoustic and psychoacoustic impact of the tool on the user. The process includes the acoustic suitability of 3D printing materials, the suitability of acoustic design using software simulation, the experimental assessment of the performance of the 3D printed prototype, and the statistical evaluation of the chosen studying parameters and conditions. This paper describes all the stages of the designing process, with a focus on the study of shapes and volumes of the prototype and on its impact on the user’s perception. FEM simulations and experimental tests performed in a semi-anechoic chamber allowed to validate the design process. These analyses proved that the designed prototype of urban furniture can not only positively influence the physical environment but also the psychoacoustic perception of it