16 research outputs found
First X-ray Structure Determination of a Bismuthio Ylide : 4,4-Dimethyl-2,6-dioxo-1-triphenylbismuthiocyclohexanide
Magnetic Phase Transition of FE II , CO II and NI II Complexes Bridged by Pyrimidine and Dicyanamide
Electron Density Distributions of Pyrimidine Bridged Cu, Fe, and Co Complexes Showing Magnetic Properties
Ferro- and Ferrimagnetic Chains of hin-Bridged Copper(II) and Manganese(II) and hnn-Bridged Manganese(II) Complexes (hin = 4,4,5,5-Tetramethylimidazolin-1-oxyl; hnn = 4,4,5,5-Tetramethylimidazolin-1-oxyl 3-Oxide)
First X-ray Structure Determination of a Bismuthio Ylide : 4,4-Dimethyl-2,6-dioxo-1-triphenylbismuthiocyclohexanide
Synthesis and Characterization of 10-Se-3 Type Selenatetraazapentalene Derivatives with A Hypervalent Selenium
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Synthesis and structure of a hexacoordinate carbon compound.
In an exploration of six coordination and hypervalence in carbon compounds, steric constraints have been employed to bring four ether O atoms in close proximity to an allenic carbon atom. The dimethylated dication 2 is confirmed to have hexacoordinate carbon by experimental charge density analysis and DFT calculations and is arguably hypervalent