Notch effect on structural strength of components at elevated temperature under creep, fatigue and creep-fatigue loading conditions : phenomenon and mechanism

Structural discontinuities (e.g., nozzle, hole, and groove) widely occur in many high temperature components of nuclear and fossil power plants. In general, the notched component is used for simplified tests and analyses due to the complexity of the introduction of a practical component. In the previous work, the effects of the notch on failure life of the components have been reported experimentally, including the strengthening and weakening effects; however, the internal mechanisms have not been clearly demonstrated. This work reviews the notch effects on the structural strength of the notched components at elevated temperatures under creep, fatigue, and creep-fatigue loading conditions. Experimental phenomena (i.e., strengthening or weakening effects) for typical notched specimens subjected to the above three loading conditions are summarized, and the related factors for notch effects on creep rupture life or cycle to failure of the components are discussed. The mechanisms for the strengthening or weakening effects induced by a notch are described. Evaluation procedures for notch effect analysis under complex loading conditions are also included, and the primary challenges concerning the notch effect are provided for further investigations

Iron(II)-Catalyzed Intermolecular Amino-Oxygenation of Olefins through the N−O Bond Cleavage of Functionalized Hydroxylamines

An iron-catalyzed diastereoselective intermolecular olefin amino-oxygenation reaction is reported, which proceeds via an iron-nitrenoid generated by the N− O bond cleavage of a functionalized hydroxylamine. In this reaction, a bench-stable hydroxylamine derivative is used as the amination reagent and oxidant. This method tolerates a range of synthetically valuable substrates that have been all incompatible with existing amino-oxygenation methods. It can also provide amino alcohol derivatives with regio- and stereochemical arrays complementary to known amino-oxygenation methods

FeII and FeI emission in IRAS 07598+6508 and PHL 1092

One of the puzzles in understanding the spectra of active galactic nuclei (AGN) is the origin of the FeII emission. FeI emission, if present, will help reveal the physical conditions of the emitting gas. In an attempt to verify the presence of FeI lines, high S/N spectra of two FeII-strong quasars, IRAS 07598-6508 and PHL 1092, were obtained at the Multiple Mirror Telescope and the Steward 2.3 m Telescope. We have identified emission lines of FeI and TiII. The source of energy for FeII, FeI and TiII emission is probably not from ionization by the photon continuum, but heat. The high rate of energy generation and the presence of both high and low velocity gas indicate that the heat is generated not over a large area, but a narrow band in accretion disk, in which the rotational speed decreases rapidly.Comment: 17 pages, Latex, figures available upon request, to appear in Ap

Thrusting and exhumation of the southern Mongolian Plateau: Joint thermochronological constraints from the Langshan Mountains, western Inner Mongolia, China

The Mongolian Plateau has undergone multi-stage denudation since the Late Triassic, and the NE-trending Langshan Mountains in the southern margin of the Mongolian Plateau is crucial to unraveling the Meso-Cenozoic cooling and exhumation history of the Mongolian Plateau. The Langshan Mountains are dominated by Precambrian gneiss and Permian–Middle Triassic granitic plutons crosscut by a set of NE-striking thrust faults. A joint thermochronological study was conducted on 31 granitic and gneissic samples along the HQ and CU transects across the Langshan Mountains and other two samples from the BQ in the north of the Langshan Mountains. Four biotite/muscovite and three K-feldspar 40Ar/39Ar plateau ages range from 205 ± 1 to 161 ± 1 and 167 ± 1 to 131 ± 1 Ma, respectively. Thirty-three apatite fission track (AFT) ages are between 184 ± 11 and 79 ± 4 Ma, with mean track lengths from 11.1 ± 1.8 to 13.1 ± 1.4 μm of mostly unimodal distributions. Thirty-one single-grain raw AHe ages are in a range of 134 ± 8 to 21 ± 1 Ma. The AFT ages decrease monotonously from NW to SE until thrust faults along the two transects, with an age-jump across thrust F35. Joint thermal history modelling shows a three-stage cooling history as a result of denudation, especially with spatial differentiation in the first stage. Relative slow cooling at c. 0.6–1.0 °C/Ma occurred in the BQ and the northern part of the HQ transect during 220–100 Ma and the northern part of the CU transect during 160–100 Ma, respectively, with an amount of c. 2–3 km denudation between 160 and 100 Ma, implying little movement along the thrusts F13 and F33. In the middle and southern parts of the HQ transect and the southern part of the CU transect, rapid cooling at c. 4.0–7.0 °C/Ma, with c. 6–9 km denudation during 170–130 or 160–100 Ma, respectively, is probably influenced by thrusting of F35, F38 and F42 and the resultant tilting. A combination of thrusting, tilting, and denudation led to the youngering trends towards thrusts in different parts. However, there was no significant denudation across the Langshan Mountains in the second stage from c. 100 or 80 Ma until the last stage of rapid denudation (c. 2 km) since 20–10 Ma, which is simultaneous with the rapid uplift of the northern part of the Tibetan Plateau at c. 15 Ma. A youngering trend of AFT ages from the inner to the peripherals of the Mongolian Plateau implies the outward propagation of the Mongolian Plateau since the Mesozoic

catena-Poly[[triaqua­(pyridine-κN)nickel(II)]-μ-sulfato-κ2 O:O′]

The title compound, [Ni(SO4)(C5H5N)(H2O)3]n, was synthesized by the hydro­thermal reaction of NiSO4·6H2O, pyridine and water. The central NiII atom is coordinated in a distorted octa­hedral environment by a pyridine N atom, three aqua O atoms and two O atoms of bridging sulfate anions, yielding a zigzag chain. A three-dimensional network is generated via complex hydrogen bonds involving the sulfate and aqua ligands and a pyridine C—H group

Potassium zinc borate, KZnB3O6

The title compound, KZnB3O6 contains a remarkable [B6O12]6− group ( symmetry) formed by two rings linked by edge-sharing BO4 tetra­hedra, a feature that has only been observed previously under high pressure conditions. These borate groups are connected through distorted ZnO4 tetra­hedra in edge-shared pairs ( symmetry), forming a three-dimensional network whose cavities are filled by K+ cations

Empirical modeling of the stellar spectrum of galaxies

An empirical method of modeling the stellar spectrum of galaxies is proposed, based on two successive applications of Principal Component Analysis (PCA). PCA is first applied to the newly available stellar library STELIB, supplemented by the J, H and K$_{s}$ magnitudes taken mainly from the 2 Micron All Sky Survey (2MASS). Next the resultant eigen-spectra are used to fit the observed spectra of a sample of 1016 galaxies selected from the Sloan Digital Sky Survey Data Release One (SDSS DR1). PCA is again applied, to the fitted spectra to construct the eigen-spectra of galaxies with zero velocity dispersion. The first 9 galactic eigen-spectra so obtained are then used to model the stellar spectrum of the galaxies in SDSS DR1, and synchronously to estimate the stellar velocity dispersion, the spectral type, the near-infrared SED, and the average reddening. Extensive tests show that the spectra of different type galaxies can be modeled quite accurately using these eigen-spectra. The method can yield stellar velocity dispersion with accuracies better than 10%, for the spectra of typical S/N ratios in SDSS DR1.Comment: 34 pages with 18 figures, submitted to A

(E)-3-[2,5-Dioxo-3-(propan-2-yl­idene)pyrrolidin-1-yl]acrylic acid

The title compound, C10H11NO4, was extracted from a culture broth of Penicillium verruculosum YL-52. The mol­ecular structure is essentially planar, with an r.m.s. deviation of 0.01342 (2) Å for the non-H atoms. In the crystal structure, adjacent mol­ecules are connected into a centrosymmetric dimer through a pair of O—H⋯O hydrogen bonds. The dimers are further extended into a chain by weak C—H⋯O hydrogen bonds