Superhard Phases of Simple Substances and Binary Compounds of the B-C-N-O System: from Diamond to the Latest Results (a Review)

The basic known and hypothetic one- and two-element phases of the B-C-N-O system (both superhard phases having diamond and boron structures and precursors to synthesize them) are described. The attention has been given to the structure, basic mechanical properties, and methods to identify and characterize the materials. For some phases that have been recently described in the literature the synthesis conditions at high pressures and temperatures are indicated.Comment: Review on superhard B-C-N-O phase

Modeling the morphodynamic response of tidal embayments to sea-level rise

Sea-level rise has a strong influence on tidal systems, and a major focus of climate change effect studies is to predict the future state of these environmental systems. Here, we used a model to simulate the morphological evolution of tidal embayments and to explore their response to a rising sea level. The model was first used to reproduce the formation of channels and intertidal flats under a stable mean water level in an idealised and initially unchannelled tidal basin. A gradual rise in sea level was imposed once a well-developed channel network had formed. Simulations were conducted with different sea-level rise rates and tidal ranges. Sea-level rise forced headward erosion of the tidal channels, driving a landward expansion of the channel network and channel development in the previously non-inundated part of the basin. Simultaneously, an increase in channel drainage width in the lower part of the basin occurred and a decrease in the overall fraction of the basin occupied by channels could be observed. Sea-level rise thus altered important characteristics of the tidal channel network. Some intertidal areas were maintained despite a rising sea level. However, the size, shape, and location of the intertidal areas changed. In addition, sea-level rise affected the exchange of sediment between the different morphological elements. A shift from exporting to importing sediment as well as a reinforcement of the existing sediment export was observed for the simulations performed here. Sediment erosion in the inlet and the offshore transport of sediment was enhanced, resulting in the expansion of the ebb-tidal delta. Our model results further emphasise that tidal embayments can exhibit contrasting responses to sea-level rise.<br/

Simulating the role of tides and sediment characteristics on tidal flat sorting and bedding dynamics

Understanding sediment sorting and bedding dynamics has high value to unravelling the mechanisms underlying geomorphological, geological, ecological and environmental imprints of tidal wetlands and hence to predicting their future changes. Using the Nanhui tidal flat on the Changjiang (Yangtze) Delta, China, as a reference site, this study establishes a schematized morphodynamic model coupling flow, sediment dynamics and bed level change to explore the processes that govern sediment sorting and bedding phenomena. Model results indicate an overall agreement with field data in terms of tidal current velocities, suspended sediment concentrations (SSCs), deposition thicknesses and sedimentary structures. Depending on the variation of tidal current strength, sand-dominated layers (SDLs) and mud-dominated layers (MDLs) tend to form during spring and neap tides, respectively. Thinner tidal couplets are developed during daily scale flood–ebb variations. A larger tidal level variation during a spring–neap tidal cycle, associated with a stronger tidal current variation, favours the formation of SDLs and tidal couplets. A larger boundary sediment supply generally promotes the formation of tidal bedding, though the bedding detail is partially dependent on the SSC composition of different sediment types. Sediment properties, including for example grain size and settling velocity, are also found to influence sediment sorting and bedding characteristics. In particular, finer and coarser sediment respond differently to spring and neap tides. During neap tides, relatively small flow velocities favour the deposition of finer sediment, with limited coarser sediment being transported to the upper tidal flat because of the larger settling velocity. During spring tides, larger flow velocities transport more coarser sediment to the upper tidal flat, accounting for distinct lamination formation. Model results are qualitatively consistent with field observations, but the role of waves, biological processes and alongshore currents needs to be included in further studies to establish a more complete understanding.</p