Feasibility of Carbon Nanoparticle Coatings as Protective Barriers for CopperWetting Assessment

Copper is extensively used in a wide range of industrial and daily-life applications, varying from heat exchangers to electrical wiring. Although it is protected from oxidation by its native oxide layer, when subjected to harsh environmental conditionssuch as in coastal regionsthis metal can rapidly degrade. Therefore, in this study, we analyze the potential use of carbon nanoparticle coatings as protective barriers due to their intrinsic hydrophobic wetting behavior. The nanocarbon coatings were produced via electrophoretic deposition on Cu platelets and characterized via scanning electron microscopy, confocal laser scanning microscopy, and sessile drop test; the latter being the primary focus since it provides insights into the wetting behavior of the produced coatings. Among the measured coatings, graphite flakes, graphene oxide, and carbon nanotube (CNT) coatings showed superhydrophobic behavior. Based on their wetting behavior, and specifically for electrical applications, CNT coatings showed the most promising results since these coatings do not significantly impact the substrate’s electrical conductivity. Although CNT agglomerates do not affect the wetting behavior of the attained coatings, the coating’s thickness plays an important role. Therefore, to completely coat the substrate, the CNT coating should be sufficiently thickabove approximately 1 μm

Feasibility of Carbon Nanoparticle Coatings as Protective Barriers for CopperWetting Assessment

Copper is extensively used in a wide range of industrial and daily-life applications, varying from heat exchangers to electrical wiring. Although it is protected from oxidation by its native oxide layer, when subjected to harsh environmental conditionssuch as in coastal regionsthis metal can rapidly degrade. Therefore, in this study, we analyze the potential use of carbon nanoparticle coatings as protective barriers due to their intrinsic hydrophobic wetting behavior. The nanocarbon coatings were produced via electrophoretic deposition on Cu platelets and characterized via scanning electron microscopy, confocal laser scanning microscopy, and sessile drop test; the latter being the primary focus since it provides insights into the wetting behavior of the produced coatings. Among the measured coatings, graphite flakes, graphene oxide, and carbon nanotube (CNT) coatings showed superhydrophobic behavior. Based on their wetting behavior, and specifically for electrical applications, CNT coatings showed the most promising results since these coatings do not significantly impact the substrate’s electrical conductivity. Although CNT agglomerates do not affect the wetting behavior of the attained coatings, the coating’s thickness plays an important role. Therefore, to completely coat the substrate, the CNT coating should be sufficiently thickabove approximately 1 μm

Feasibility of Carbon Nanoparticle Coatings as Protective Barriers for CopperWetting Assessment

Copper is extensively used in a wide range of industrial and daily-life applications, varying from heat exchangers to electrical wiring. Although it is protected from oxidation by its native oxide layer, when subjected to harsh environmental conditionssuch as in coastal regionsthis metal can rapidly degrade. Therefore, in this study, we analyze the potential use of carbon nanoparticle coatings as protective barriers due to their intrinsic hydrophobic wetting behavior. The nanocarbon coatings were produced via electrophoretic deposition on Cu platelets and characterized via scanning electron microscopy, confocal laser scanning microscopy, and sessile drop test; the latter being the primary focus since it provides insights into the wetting behavior of the produced coatings. Among the measured coatings, graphite flakes, graphene oxide, and carbon nanotube (CNT) coatings showed superhydrophobic behavior. Based on their wetting behavior, and specifically for electrical applications, CNT coatings showed the most promising results since these coatings do not significantly impact the substrate’s electrical conductivity. Although CNT agglomerates do not affect the wetting behavior of the attained coatings, the coating’s thickness plays an important role. Therefore, to completely coat the substrate, the CNT coating should be sufficiently thickabove approximately 1 μm

Feasibility of Carbon Nanoparticle Coatings as Protective Barriers for CopperWetting Assessment

Copper is extensively used in a wide range of industrial and daily-life applications, varying from heat exchangers to electrical wiring. Although it is protected from oxidation by its native oxide layer, when subjected to harsh environmental conditionssuch as in coastal regionsthis metal can rapidly degrade. Therefore, in this study, we analyze the potential use of carbon nanoparticle coatings as protective barriers due to their intrinsic hydrophobic wetting behavior. The nanocarbon coatings were produced via electrophoretic deposition on Cu platelets and characterized via scanning electron microscopy, confocal laser scanning microscopy, and sessile drop test; the latter being the primary focus since it provides insights into the wetting behavior of the produced coatings. Among the measured coatings, graphite flakes, graphene oxide, and carbon nanotube (CNT) coatings showed superhydrophobic behavior. Based on their wetting behavior, and specifically for electrical applications, CNT coatings showed the most promising results since these coatings do not significantly impact the substrate’s electrical conductivity. Although CNT agglomerates do not affect the wetting behavior of the attained coatings, the coating’s thickness plays an important role. Therefore, to completely coat the substrate, the CNT coating should be sufficiently thickabove approximately 1 μm

Feasibility of Carbon Nanoparticle Coatings as Protective Barriers for CopperWetting Assessment

Copper is extensively used in a wide range of industrial and daily-life applications, varying from heat exchangers to electrical wiring. Although it is protected from oxidation by its native oxide layer, when subjected to harsh environmental conditionssuch as in coastal regionsthis metal can rapidly degrade. Therefore, in this study, we analyze the potential use of carbon nanoparticle coatings as protective barriers due to their intrinsic hydrophobic wetting behavior. The nanocarbon coatings were produced via electrophoretic deposition on Cu platelets and characterized via scanning electron microscopy, confocal laser scanning microscopy, and sessile drop test; the latter being the primary focus since it provides insights into the wetting behavior of the produced coatings. Among the measured coatings, graphite flakes, graphene oxide, and carbon nanotube (CNT) coatings showed superhydrophobic behavior. Based on their wetting behavior, and specifically for electrical applications, CNT coatings showed the most promising results since these coatings do not significantly impact the substrate’s electrical conductivity. Although CNT agglomerates do not affect the wetting behavior of the attained coatings, the coating’s thickness plays an important role. Therefore, to completely coat the substrate, the CNT coating should be sufficiently thickabove approximately 1 μm

Local Structure-Driven Localized Surface Plasmon Absorption and Enhanced Photoluminescence in ZnO-Au Thin Films

Nanocomposite films consisting of gold nanoparticles embedded in zinc oxide (ZnO-Au) have been synthesized with different gold loadings by reactive magnetron sputtering at near-room temperature followed by ex situ annealing in air up to 300 °C. Using X-ray diffraction and high resolution transmission microscopy it is shown that during deposition gold substitutes zinc in ZnO as isolated atoms and in nanoparticles still exhibiting the structure of ZnO. Both situations degrade the crystalline quality of the ZnO matrix, but thermal annealing cures it from isolated gold atoms and triggers the formation of gold nanoparticles of size higher than 3 nm, sufficient to observe a strong activation of localized surface plasmon resonance (LSPR). The amplitude of LSPR absorption observed after annealing increases with the gold loading and annealing temperature. Moreover, UV and visible photoluminescence from the ZnO matrix is strongly enhanced upon activation of LSPR showing strong coupling with the gold nanoparticles. Finally, modeling of spectroscopic ellipsometry measurements unambiguously reveals how curing the defects increases the optical bandgap of the ZnO matrix and modifies the optical dielectric functions of the nanocomposite and ZnO matrix

Deterministic Coupling of a Single Silicon-Vacancy Color Center to a Photonic Crystal Cavity in Diamond

Deterministic coupling of single solid-state emitters to nanocavities is the key for integrated quantum information devices. We here fabricate a photonic crystal cavity around a preselected single silicon-vacancy color center in diamond and demonstrate modification of the emitters internal population dynamics and radiative quantum efficiency. The controlled, room-temperature cavity coupling gives rise to a resonant Purcell enhancement of the zero-phonon transition by a factor of 19, coming along with a 2.5-fold reduction of the emitter’s lifetime

Surface Modification of Brass via Ultrashort Pulsed Direct Laser Interference Patterning and Its Effect on Bacteria-Substrate Interaction

In recent decades, antibiotic resistance has become a crucial challenge for human health. One potential solution to this problem is the use of antibacterial surfaces, i.e., copper and copper alloys. This study investigates the antibacterial properties of brass that underwent topographic surface functionalization via ultrashort pulsed direct laser interference patterning. Periodic line-like patterns in the scale range of single bacterial cells were created on brass with a 37% zinc content to enhance the contact area for rod-shaped Escherichia coli (E. coli). Although the topography facilitates attachment of bacteria to the surface, reduced killing rates for E. coli are observed. In parallel, a high-resolution methodical approach was employed to explore the impact of laser-induced topographical and chemical modifications on the antibacterial properties. The findings reveal the underlying role of the chemical modification concerning the antimicrobial efficiency of the Cu-based alloy within the superficial layers of a few hundred nanometers. Overall, this study provides valuable insight into the effect of alloy composition on targeted laser processing for antimicrobial Cu-surfaces, which facilitates the thorough development and optimization of the process concerning antimicrobial applications

Local Modification of the Microstructure and Electrical Properties of Multifunctional Au–YSZ Nanocomposite Thin Films by Laser Interference Patterning

Nanocomposite films consisting of gold nanoparticles embedded in an yttria-stabilized zirconia matrix (Au–YSZ) have been synthesized with different gold loadings by reactive magnetron sputtering followed by ex situ annealing in air or laser interference patterning (LIP) treatment. It is shown that the electrical conductivity of the nanocomposite films can be modified to a large extent by changing the gold loading, by thermal annealing, or by LIP. The structural and microstructural analyses evidenced the segregation of metallic gold in crystalline form for all synthesis conditions and treatments applied. Thermal annealing above 400 °C is observed to trigger the growth of pre-existing nanoparticles in the volume of the films. Moreover, pronounced segregation of gold to the film surface is observed for Au/(Au + Zr + Y) ratios above 0.40, which may prevent the use of thermal annealing to functionalize gold-rich Au–YSZ coatings. In contrast, significant modifications of the microstructure were detected within the interference spot (spot size close to 2 × 2 mm) of LIP treatments only for the regions corresponding to constructive interference. As a consequence, besides its already demonstrated ability to modify the friction behavior of Au–YSZ films, the LIP treatment enables local tailoring of their electrical resistivity. The combination of these characteristics can be of great interest for sliding electrical contacts