491 research outputs found
Extended x-ray absorption fine structure study of porous GaSb formed by ion implantation
Porous GaSb has been formed by Ga ion implantation into crystalline GaSb substrates at either room temperature or −180 °C. The morphology has been characterized using scanning electron microscopy and the atomic structure was determined using extended x-ray absorption fine structure spectroscopy. Room-temperature implantation at low fluences leads to the formation of ∼20-nm voids though the material remains crystalline. Higher fluences cause the microstructure to evolve into a network of amorphous GaSb rods ∼15 nm in diameter. In contrast, implantation at −180 °C generates large, elongated voids but no rods. Upon exposure to air, the surface of the porous material is readily oxidized yielding Ga₂O₃ and metallic Sb precipitates, the latter resulting from the reduction of unstable Sb₂O₃. We consider and discuss the atomic-scale mechanisms potentially operative during the concurrent crystalline-to-amorphous and continuous-to-porous transformations
Co–Au core-shell nanocrystals formed by sequential ion implantation into SiO₂
Co–Au core-shell nanocrystals (NCs) were formed by sequential ion implantation of Au and Co into thin SiO₂. The NCs were investigated by means of transmission electron microscopy and extended x-ray absorption fine structure spectroscopy. The latter reveals a bond length expansion in the Co core compared to monatomic Co NCs. Concomitantly, a significant contraction of the bond length and a significant reduction of the effective Au–Au coordination number were observed in the Au shells. Increased Debye-Waller factors indicate significant strain in the NCs. These experimental results verify recent theoretical predictions.P.K. and M.C.R. thank the Australian Research Council
for support. P.K., B.H., B.J., and M.C.R. were supported by
the Australian Synchrotron Research Program, funded by the
Commonwealth of Australia via the Major National Research
Facilities Program
Bond length contraction in Au nanocrystals formed by ion implantation into thin SiO[sub 2]
Au nanocrystals (NCs) fabricated by ion implantation into thin SiOâ‚‚ and annealing were investigated by means of extended x-rayabsorption fine structure (EXAFS)spectroscopy and transmission electron microscopy. A bond length contraction was observed and can be explained by surface tension effects in a simple liquid-drop model. Such results are consistent with previous reports on nonembedded NCs implying a negligible influence of the SiOâ‚‚ matrix. Cumulant analysis of the EXAFS data suggests surface reconstruction or relaxation involving a further shortened bond length. A deviation from the octahedral closed shell structure is apparent for NCs of size 25Ã….P. K. is grateful to the Humboldt Foundation in Germany
for support. P.K., B.J., A.C., C.J.G., G.d.M.A., G.J.F., and
M.C.R. were supported by the Australian Synchrotron Research
Program
A New Look at the Local White Dwarf Population
We have conducted a detailed new survey of the local population of white dwarfs lying within 20 pc of the Sun. A new revised catalog of local white dwarfs containing 122 entries (126 individual degenerate stars) is presented. This list contains 27 white dwarfs not included in a previous list from 2002, as well as new and recently published trigonometric parallaxes. In several cases new members of the local white dwarf population have come to light through accurate photometric distance estimates. In addition, a suspected new double degenerate system (WD 0423+120) has been identified. The 20 pc sample is currently estimated to be 80% complete. Using a variety of recent spectroscopic, photometric, and trigonometric distance determinations, we re-compute a space density of 4.8 ± 0.5 × 10−3 pc−3 corresponding to a mass density of 3.2 ± 0.3 × 10−3 M pc−3 from the complete portion of the sample within 13 pc. We find an overall mean mass for the local white dwarfs of 0.665 M, a value larger than most other non-volume-limited estimates. Although the sample is small, we find no evidence of a correlation between mass and temperature in which white dwarfs below 13,000 K are systematically more massive than those above this temperature. Within 20 pc 25% of the white dwarfs are in binary systems (including double degenerate systems). Approximately 6% are double degenerates and 6.5% are Sirius-like systems. The fraction of magnetic white dwarfs in the local population is found to be 13%
The influence of annealing conditions on the growth and structure of embedded Pt nanocrystals
The growth and structure of Pt nanocrystals (NCs) formed by ion implantation in a-SiO₂ has been investigated as a function of the annealing conditions. Transmission electron microscopy and small-angle x-ray scatteringmeasurements demonstrate that the annealing ambient has a significant influence on NC size. Samples annealed in either Ar, O₂, or forming gas (95% N₂: 5% H₂) at temperatures ranging from 500 °C–1300 °C form spherical NCs with mean diameters ranging from 1–14 nm. For a given temperature, annealing in Ar yields the smallest NCs. O₂ and forming gas ambients produce NCs of comparable size though the latter induces H chemisorption at 1100 °C and above, as verified with x-ray absorption spectroscopy. This H intake is accompanied by a bond-length expansion and increased structural disorder in NCs of diameter >3 nm.We thank the Australian Synchrotron Research Program
and the Australian Research Council for financial support
The structure of ultrathin Langmuir-Blodgett films of cadmium behenate
Grazing incidence x-ray-diffraction investigations of the structures of Langmuir-Blodgett films of cadmium behenate with 1, 2, 3, 5, and 21 monolayers are reported. The single monolayer film, deposited on a hydrophilic substrate, showed a hexagonal structure, whereas the bilayer film, deposited on a hydrophobic substrate, had a rectangular structure with herringbone orientation of the acyl chains. With multilayer films formed on a hydrophilic substrate, it was possible to detect that the hexagonal structure of the first layer was retained when additional layers were deposited and that the additional layers had the same rectangular structure as the bilayer. (c) 2005 American Institute of Physics
The galactic population of white dwarfs
Original paper can be found at: http://www.iop.org/EJ/conf DOI: 10.1088/1742-6596/172/1/012004 [16th European White Dwarfs Workshop]The contribution of white dwarfs of the different Galactic populations to the stellar content of our Galaxy is only poorly known. Some authors claim a vast population of halo white dwarfs, which would be in accordance with some investigations of the early phases of Galaxy formation claiming a top-heavy initial– mass– function. Here, I present a model of the population of white dwarfs in the Milky Way based on observations of the local white dwarf sample and a standard model of Galactic structure. This model will be used to estimate the space densities of thin disc, thick disc and halo white dwarfs and their contribution to the baryonic mass budget of the Milky Way. One result of this investigation is that white dwarfs of the halo population contribute a large fraction of the Galactic white dwarf number count, but they are not responsible for the lion's share of stellar mass in the Milky Way. Another important result is the substantial contribution of the – often neglected – population of thick disc white dwarfs. Misclassification of thick disc white dwarfs is responsible for overestimates of the halo population in previous investigations.Peer reviewe
Proteome Profiling of Breast Tumors by Gel Electrophoresis and Nanoscale Electrospray Ionization Mass Spectrometry
We have conducted proteome-wide analysis of fresh surgery specimens derived from breast cancer patients, using an approach that integrates size-based intact protein fractionation, nanoscale liquid separation of peptides, electrospray ion trap mass spectrometry, and bioinformatics. Through this approach, we have acquired a large amount of peptide fragmentation spectra from size-resolved fractions of the proteomes of several breast tumors, tissue peripheral to the tumor, and samples from patients undergoing noncancer surgery. Label-free quantitation was used to generate protein abundance maps for each proteome and perform comparative analyses. The mass spectrometry data revealed distinct qualitative and quantitative patterns distinguishing the tumors from healthy tissue as well as differences between metastatic and non-metastatic human breast cancers including many established and potential novel candidate protein biomarkers. Selected proteins were evaluated by Western blotting using tumors grouped according to histological grade, size, and receptor expression but differing in nodal status. Immunohistochemical analysis of a wide panel of breast tumors was conducted to assess expression in different types of breast cancers and the cellular distribution of the candidate proteins. These experiments provided further insights and an independent validation of the data obtained by mass spectrometry and revealed the potential of this approach for establishing multimodal markers for early metastasis, therapy outcomes, prognosis, and diagnosis in the future. © 2008 American Chemical Society
- …