Chemical probes of turbulence in the diffuse medium: the TDR model

Context. Tens of light hydrides and small molecules have now been detected over several hundreds sight lines sampling the diffuse interstellar medium (ISM) in both the Solar neighbourhood and the inner Galactic disk. They provide unprecedented statistics on the first steps of chemistry in the diffuse gas. Aims. These new data confirm the limitations of the traditional chemical pathways driven by the UV photons and the cosmic rays (CR) and the need for additional energy sources, such as turbulent dissipation, to open highly endoenergetic formation routes. The goal of the present paper is to further investigate the link between specific species and the properties of the turbulent cascade in particular its space-time intermittency. Methods. We have analysed ten different atomic and molecular species in the framework of the updated model of turbulent dissipation regions (TDR). We study the influence on the abundances of these species of parameters specific to chemistry (density, UV field, and CR ionisation rate) and those linked to turbulence (the average turbulent dissipation rate, the dissipation timescale, and the ion neutral velocity drift in the regions of dissipation). Results. The most sensitive tracers of turbulent dissipation are the abundances of CH+ and SH+, and the column densities of the J = 3, 4, 5 rotational levels of H2 . The abundances of CO, HCO+, and the intensity of the 158 $\mu$m [CII] emission line are significantly enhanced by turbulent dissipation. The vast diversity of chemical pathways allows the independent determinations of free parameters never estimated before: an upper limit to the average turbulent dissipation rate, $\overline{\varepsilon}$ < 10$^{-23}$ erg cm$^{-3}$ s$^{-1}$ for $n_H$=20 cm$^{-3}$, from the CH+ abundance; an upper limit to the ion-neutral velocity drift, $u_{in}$ < 3.5 km s$^{-1}$, from the SH+ to CH+ abundance ratio; and a range of dissipation timescales, 100 < $\tau_V$ < 1000 yr, from the CO to HCO+ abundance ratio. For the first time, we reproduce the large abundances of CO observed on diffuse lines of sight, and we show that CO may be abundant even in regions with UV-shieldings as low as $5 \times 10^{-3}$ mag. The best range of parameters also reproduces the abundance ratios of OH, C2H, and H2O to HCO+ and are consistent with the known properties of the turbulent cascade in the Galactic diffuse ISM. Conclusions. Our results disclose an unexpected link between the dissipation of turbulence and the emergence of molecular richness in the diffuse ISM. Some species, such as CH+ or SH+, turn out to be unique tracers of the energy trail in the ISM. In spite of some degeneracy, the properties of the turbulent cascade, down to dissipation, can be captured through specific molecular abundances

Interstellar chemistry of nitrogen hydrides in dark clouds

The aim of the present work is to perform a comprehensive analysis of the interstellar chemistry of nitrogen, focussing on the gas-phase formation of the smallest polyatomic species and in particular nitrogen hydrides. We present a new chemical network in which the kinetic rates of critical reactions have been updated based on recent experimental and theoretical studies, including nuclear spin branching ratios. Our network thus treats the different spin symmetries of the nitrogen hydrides self-consistently together with the ortho and para forms of molecular hydrogen. This new network is used to model the time evolution of the chemical abundances in dark cloud conditions. The steady-state results are analysed, with special emphasis on the influence of the overall amounts of carbon, oxygen, and sulphur. Our calculations are also compared with Herschel/HIFI observations of NH, NH$_2$, and NH$_3$ detected towards the external envelope of the protostar IRAS 16293-2422. The observed abundances and abundance ratios are reproduced for a C/O gas-phase elemental abundance ratio of $\sim0.8$, provided that the sulphur abundance is depleted by a factor larger than 2. The ortho-to-para ratio of H$_2$ in these models is $\sim10^{-3}$. Our models also provide predictions for the ortho-to-para ratios of NH$_2$ and NH$_3$ of $\sim2.3$ and $\sim0.7$ respectively. We conclude that the abundances of nitrogen hydrides in dark cloud conditions are consistent with the gas-phase synthesis predicted with our new chemical network.Comment: Accepted for publication in Astronomy & Astrophysics; 22 pages (9 in Appendix), 7 figures (2 in Appendix), 6 tables (3 in Appendix

Nitrogen hydrides and the H2 ortho-to-para ratio in dark clouds.

Accepted for publication in A&A (Astronomy and Astrophysics)Nitrogen bearing species are common tracers of the physical conditions in a wide variety of objects, and most remarkably in dark clouds. The reservoir of gaseous nitrogen is expected to be atomic or molecular, but none of the two species are observable in the dark gas. Their abundances therefore derive indirectly from those of N-bearing species through chemical modelling. The recent years have accumulated data which stress our incomplete understanding of the nitrogen chemistry in dark cloud conditions. To tackle this problem of the nitrogen chemistry in cold gas, we have revised the formation of nitrogen hydrides, which is initiated by the key reaction \ce{N+ + H2 -> NH+ + H}. We propose a new rate for this reaction which depends on the ortho-to-para ratio of H2. This new rate allows to reproduce the abundance ratios of the three nitrogen hydrides, NH, \ce{NH2}, and \ce{NH3}, observed towards IRAS16293-2422, provided that the channel leading to NH from the dissociative recombination of \ce{N2H+} is not closed at low temperature. The ortho-to-para ratio of H2 is constrained to O/P=$10^{-3}$ by the abundance ratio NH:NH2, which provides a new method to measure O/P. This work stresses the need for reaction rates at the low temperatures of dark clouds, and for branching ratios of critical dissociative recombination reactions

Warm H2_2 as a probe of massive accretion and feedback through shocks and turbulence across cosmic time

Galaxy formation depends on a complex interplay between gravitational collapse, gas accretion, merging, and feedback processes. Yet, after many decades of investigation, these concepts are poorly understood. This paper presents the argument that warm H$_2$ can be used as a tool to unlock some of these mysteries. Turbulence, shocks and outflows, driven by star formation, AGN activity or inflows, may prevent the rapid buildup of star formation in galaxies. Central to our understanding of how gas is converted into stars is the process by which gas can dissipate its mechanical energy through turbulence and shocks in order to cool. H$_2$ lines provide direct quantitative measurements of kinetic energy dissipation in molecular gas in galaxies throughout the Universe. Based on the detection of very powerful H$_2$ lines from z = 2 galaxies and proto-clusters at the detection limits of {\it Spitzer}, we are confident that future far-IR and UV H$_2$ observations will provide a wealth of new information and insight into galaxy evolution to high-z. Finally, at the very earliest epoch of star and galaxy formation, warm H$_2$ may also provide a unique glimpse of molecular gas collapse at 7 $<$ z $<$ 12 in massive dark matter (DM) halos on their way to forming the very first galaxies. Such measurements are beyond the reach of existing and planned observatories.Comment: Submitted as a science White Paper to the Astronomy and Astrophysics Astro 2020 Decadal Survey call issued by the National Academies of Sciences, Engineering and Medicine (March 11 2019

Warm H₂ as a probe of massive accretion and feedback through shocks and turbulence across cosmic time

Galaxy formation depends on a complex interplay between gravitational collapse, gas accretion, merging, and feedback processes. Yet, after many decades of investigation, these concepts are poorly understood. This paper presents the argument that warm H₂ can be used as a tool to unlock some of these mysteries. Turbulence, shocks and outflows, driven by star formation, AGN activity or inflows, may prevent the rapid buildup of star formation in galaxies. Central to our understanding of how gas is converted into stars is the process by which gas can dissipate its mechanical energy through turbulence and shocks in order to cool. H₂ lines provide direct quantitative measurements of kinetic energy dissipation in molecular gas in galaxies throughout the Universe. Based on the detection of very powerful H₂ lines from z = 2 galaxies and proto-clusters at the detection limits of Spitzer, we are confident that future far-IR and UV H₂ observations will provide a wealth of new information and insight into galaxy evolution to high-z. Finally, at the very earliest epoch of star and galaxy formation, warm H₂ may also provide a unique glimpse of molecular gas collapse at 7 < z < 12 in massive dark matter (DM) halos on their way to forming the very first galaxies. Such measurements are beyond the reach of existing and planned observatories

Warm H_2 as a probe of massive accretion and feedback through shocks and turbulence across cosmic time

Galaxy formation depends on a complex interplay between gravitational collapse, gas accretion, merging, and feedback processes. Yet, after many decades of investigation, these concepts are poorly understood. This paper presents the argument that warm H_2 can be used as a tool to unlock some of these mysteries. Turbulence, shocks and outflows, driven by star formation, AGN activity or inflows, may prevent the rapid buildup of star formation in galaxies. Central to our understanding of how gas is converted into stars is the process by which gas can dissipate its mechanical energy through turbulence and shocks in order to cool. H_2 lines provide direct quantitative measurements of kinetic energy dissipation in molecular gas in galaxies throughout the Universe. Based on the detection of very powerful H_2 lines from z = 2 galaxies and proto-clusters at the detection limits of Spitzer, we are confident that future far-IR and UV H_2 observations will provide a wealth of new information and insight into galaxy evolution to high-z. Finally, at the very earliest epoch of star and galaxy formation, warm H_2 may also provide a unique glimpse of molecular gas collapse at 7 < z < 12 in massive dark matter (DM) halos on their way to forming the very first galaxies. Such measurements are beyond the reach of existing and planned observatories

Excitation and emission of H2, CO and H2O molecules in interstellar shock waves

International audienceThe dissipation of kinetic energy that occurs in interstellar shock waves is accompanied by the emission of radiation. In the case of shocks that are propagating into mainly molecular gas, the emission occurs principally in lines of the species H2, H, O, CO and H2O. The relative intensities of these emission lines are indicative of the type and speed of the shock wave and of the physical conditions in the ambient gas. We present the results of computations of the intensities of these lines, for small grids of models of C- and J-type shock waves, and compare with the results of previous calculations. Our results should serve to aid the interpretation of observations made with the Herschel and other satellites

Interpreting observations of molecular outflow sources: the MHD shock code mhd_vode

International audienceThe planar MHD shock code mhd_vode has been developed in order to simulate both continuous (C) type shock waves and jump (J) type shock waves in the interstellar medium. The physical and chemical state of the gas in steady-state may also be computed and used as input to a shock wave model. The code is written principally in FORTRAN 90, although some routines remain in FORTRAN 77. The documented program and its input data are described and provided as supplementary material, and the results of exemplary test runs are presented. Our intention is to enable the interested user to run the code for any sensible parameter set and to comprehend the results. With applications to molecular outflow sources in mind, we have computed, and are making available as supplementary material, integrated atomic and molecular line intensities for grids of C- and J-type models; these computations are summarized in the Appendices