2,050 research outputs found
In Situ Detection of Active Edge Sites in Single-Layer MoS Catalysts
MoS2 nanoparticles are proven catalysts for processes such as
hydrodesulphurization and hydrogen evolution, but unravelling their
atomic-scale structure under catalytic working conditions has remained
significantly challenging. Ambient pressure X-ray Photoelectron Spectroscopy
(AP-XPS) allows us to follow in-situ the formation of the catalytically
relevant MoS2 edge sites in their active state. The XPS fingerprint is
described by independent contributions to the Mo3d core level spectrum whose
relative intensity is sensitive to the thermodynamic conditions. Density
Functional Theory (DFT) is used to model the triangular MoS2 particles on
Au(111) and identify the particular sulphidation state of the edge sites. A
consistent picture emerges in which the core level shifts for the edge Mo atoms
evolve counter-intuitively towards higher binding energies when the active
edges are reduced. The shift is explained by a surprising alteration in the
metallic character of the edge sites, which is a distinct spectroscopic
signature of the MoS2 edges under working conditions
Radiocarbon Chronologies and Extinction Dynamics of the Late Quaternary Mammalian Megafauna of the Taimyr Peninsula, Russian Federation
This paper presents 75 new radiocarbon dates based on late Quaternary mammal remains recovered from eastern Taimyr Peninsula and adjacent parts of the northern Siberian lowlands, Russian Federation, including specimens of woolly mammoth (Mammuthus primigenius), steppe bison (Bison priscus), muskox (Ovibos moschatus), moose (Alces alces), reindeer (Rangifer tarandus), horse (Equus caballus) and wolf (Canis lupus). New evidence permits reanalysis of megafaunal extinction dynamics in the Asian high Arctic periphery. Increasingly, radiometric records of individual species show evidence of a gap at or near the Pleistocene/Holocene boundary (PHB). In the past, the PHB gap was regarded as significant only when actually terminal, i.e., when it marked the apparent ââlastââ occurrence of a species (e.g., current ââlastââ occurrence date for woolly mammoth in mainland Eurasia is 9600 yr BP). However, for high Arctic populations of horses and muskoxen the gap marks an interruption rather than extinction, because their radiocarbon records resume, nearly simultaneously, much later in the Holocene. Taphonomic effects, ÎC14 flux, and biased sampling are unlikely explanations for these hiatuses. A possible explanation is that the gap is the signature of an event, of unknown nature, that prompted the nearly simultaneous crash of many megafaunal populations in the high Arctic and possibly elsewhere in Eurasia.
Peel and peel again
Aim: To determine if the internal limiting membrane (ILM) was present in the epiretinal membrane (ERM) when we deliberately tried to perform a "double peel" for macular pucker. Methods: Pars-plana vitrectomy and a "double peel" were carried out. The ERM and ILM were stained with Trypan Blue and peeled separately over the same area. The amount of ERM present in ILM specimens and the amount of ILM present in ERM specimens were evaluated by histological examination. Results: Seventeen eyes in 17 patients were included. It was possible to double peel in all cases. Five of 17 ERM specimens (29%) contained ILM fragments. When ILM was present on the ERM, it represented less than 50% of the sample. One ILM specimen was lost as result of an administrative error; of the remaining 16 specimens, residual ERM was found in six, and cellular remnants were observed on the vitreous surface in a further six of the ILMs. Clinically, no recurrence of ERM was found. Conclusion: ILM was present in some ERM specimens seemingly over the same area that an intact ILM was subsequently peel. We speculate that the ILM in the ERM represent a secondary basement membrane and that the surgical plane of dissection for most ERM peel is between the ERM and the native ILM, making it feasible to double peel routinely.published_or_final_versio
Effects of erythropoietin in murine-induced pluripotent cell-derived panneural progenitor cells
Induced cell fate changes by reprogramming of somatic cells offers an efficient strategy to generate autologous pluripotent stem (iPS) cells from any adult cell type. The potential of iPS cells to differentiate into various cell types is well established, however the efficiency to produce functional neurons from iPS cells remains modest. Here, we generated panneural progenitor cells (pNPCs) from mouse iPS cells and investigated the effect of the neurotrophic growth factor erythropoietin (EPO) on their survival, proliferation and neurodifferentiation. Under neural differentiation conditions, iPS-derived pNPCs gave rise to microtubule-associated protein-2 positive neuronlike cells (34% to 43%) and platelet-derived growth factor receptor positive oligodendrocytelike cells (21% to 25%) while less than 1% of the cells expressed the astrocytic marker glial fibrillary acidic protein. Neuronlike cells generated action potentials and developed active presynaptic terminals. The pNPCs expressed EPO receptor (EPOR) mRNA and displayed functional EPOR signaling. In proliferating cultures, EPO (0.1â3 U/mL) slightly improved pNPC survival but reduced cell proliferation and neurosphere formation in a concentration-dependent manner. In differentiating cultures EPO facilitated neurodifferentiation as assessed by the increased number of β-III-tubulin positive neurons. Our results show that EPO inhibits iPS pNPC self-renewal and promotes neurogenesis
Magneto-optical Trapping of Cadmium
We report the laser-cooling and confinement of Cd atoms in a magneto-optical
trap, and characterize the loading process from the background Cd vapor. The
trapping laser drives the 1S0-1P1 transition at 229 nm in this two-electron
atom and also photoionizes atoms directly from the 1P1 state. This
photoionization overwhelms the other loss mechanisms and allows a direct
measurement of the photoionization cross section, which we measure to be
2(1)x10^(-16)cm^(2) from the 1P1 state. When combined with nearby laser-cooled
and trapped Cd^(+) ions, this apparatus could facilitate studies in ultracold
interactions between atoms and ions.Comment: 8 pages, 11 figure
Necessary conditions for variational regularization schemes
We study variational regularization methods in a general framework, more
precisely those methods that use a discrepancy and a regularization functional.
While several sets of sufficient conditions are known to obtain a
regularization method, we start with an investigation of the converse question:
How could necessary conditions for a variational method to provide a
regularization method look like? To this end, we formalize the notion of a
variational scheme and start with comparison of three different instances of
variational methods. Then we focus on the data space model and investigate the
role and interplay of the topological structure, the convergence notion and the
discrepancy functional. Especially, we deduce necessary conditions for the
discrepancy functional to fulfill usual continuity assumptions. The results are
applied to discrepancy functionals given by Bregman distances and especially to
the Kullback-Leibler divergence.Comment: To appear in Inverse Problem
Vibrational Study of 13C-enriched C60 Crystals
The infrared (IR) spectrum of solid C60 exhibits many weak vibrational modes.
Symmetry breaking due to 13C isotopes provides a possible route for optically
activating IR-silent vibrational modes. Experimental spectra and a
semi-empirical theory on natural abundance and 13C-enriched single crystals of
C60 are presented. By comparing the experimental results with the theoretical
results, we exclude this isotopic activation mechanism from the explanation for
weakly active fundamentals in the spectra.Comment: Accepted for Phys. Rev. B, typeset in REVTEX v3.0 in LaTeX.
Postscript file including figures is available at
http://insti.physics.sunysb.edu/~mmartin/papers/c13twocol2.ps File with
figures will be e-mailed by reques
Reply to the comment on "Imaging of the Hydrogen Subsurface Site in Rutile TiO2''
A reply to the Comment by M. Calatayud et al. on "Imaging of the Hydrogen Subsurface Site in Rutile TiO2" (Physical Review Letters, Volume 102, Issue 13). DOI: 10.1103/physrevlett.102.136103.Peer reviewe
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