A farmer's experience with deep plowing of Solonetzic soils

Non-Peer Reviewe

Assessing the agronomic value of hog manure-derived struvite as a phosphorus source for spring wheat

Non-Peer ReviewedRecovery of phosphorus (P) from liquid hog manure is one option for minimizing P loss from hog operations to surface water bodies, where it can cause eutrophication. The P, recovered as magnesium ammonium phosphate hexahydrate (MgNH4PO4∙6H2O), commonly known as struvite, has slow-release properties, which could improve P use efficiency in cropping systems. This greenhouse bioassay evaluated the effectiveness of struvite as a P source for spring wheat. Struvite, monoammonium phosphate (MAP), and polymer-coated monoammonium phosphate (CMAP) were applied at rates of 25 and 50 kg P2O5 ha-1 either in the seed-row or in a side-band in the first of three crop cycles. Results for Cycle 1 indicated no significant P source, rate, application method, and soil main effects on aboveground wheat dry matter yield (DMY). Phosphorus uptake (PU) in Cycle 1, averaged across soils, rates, and applications methods, was significantly greater with MAP (5.1 mg kg-1) and CMAP (4.9 mg kg-1) than with struvite (4.1 mg kg-1) application. Similarly, P uptake efficiency (PUE) was greater for MAP (21%) and CMAP (18%) than for struvite (12%). For the second and third crop cycles in which wheat followed canola, DMY, PU, and PUE were similar for the P sources, regardless of rate, placement, or soil. These results suggest that while struvite was as good as the commercial P fertilizers with respect to DMY and, in Cycles 2 and 3, PU and PUE, it did not exhibit the beneficial residual effects that typically characterize slow release fertilizers. Nonetheless, it is encouraging to note that the unrefined struvite, which is a by-product of manure management for environmental goals, can perform as well as commercial fertilizers that are optimized for agronomic performance

University of Minnesota – Twin Cities Modifications to the Montana State University Telemetry System for Stratospheric Eclipse Ballooning

On August 21, 2017, the path of totality of a solar eclipse swept across the continental United States from Oregon to South Carolina. Our team, flying weather balloons near Grand Island, Nebraska, was able to live stream the shadow of the moon from the stratosphere to the ground. The team was able to track our balloons with high accuracy due to new payload software and hardware implemented on the still image telemetry platform developed by the Montana Space Grant. In addition, the modified system allowed the team to relay commands and receive information from individual payloads attached to our balloons, giving live telemetry and control from a new GUI-based ground station control application. Although the eclipse is now over, the system will still be a powerful and useful tool for the University of Minnesota stratospheric ballooning team. The platform could be used for any other application needing real-time, ground-based communication to various payloads on a balloon gondola

Understanding the dynamics of segregation bands of simulated granular material in a rotating drum

Axial segregation of a binary mixture of grains in a rotating drum is studied using Molecular Dynamics (MD) simulations. A force scheme leading to a constant restitution coefficient is used and shows that axial segregation is possible between two species of grains made of identical material differing by size. Oscillatory motion of bands is investigated and the influence of the frictional properties elucidated. The mechanism of bands merging is explained using direct imaging of individual grains

The vaginal-PVPA: A vaginal mucosa-mimicking in vitro permeation tool for evaluation of mucoadhesive formulations

Drug administration to the vaginal site has gained increasing attention in past decades, highlighting the need for reliable in vitro methods to assess the performance of novel formulations. To optimize formulations destined for the vaginal site, it is important to evaluate the drug retention within the vagina as well as its permeation across the mucosa, particularly in the presence of vaginal fluids. Herewith, the vaginal-PVPA (Phospholipid Vesicle-based Permeation Assay) in vitro permeability model was validated as a tool to evaluate the permeation of the anti-inflammatory drug ibuprofen from liposomal formulations (i.e., plain and chitosan-coated liposomes). Drug permeation was assessed in the presence and absence of mucus and simulated vaginal fluid (SVF) at pH conditions mimicking both the healthy vaginal premenopausal conditions and vaginal infection/pre-puberty/post-menopause state. The permeation of ibuprofen proved to depend on the type of formulation (i.e., chitosan-coated liposomes exhibited lower drug permeation), the mucoadhesive formulation properties and pH condition. This study highlights both the importance of mucus and SVF in the vaginal model to better understand and predict the in vivo performance of formulations destined for vaginal administration, and the suitability of the vaginal-PVPA model for such investigations

Phosphorus mirabilis: illuminating the past and future of phosphorus stewardship

After its discovery in 1669, phosphorus (P) was named Phosphorus mirabilis (“the miraculous bearer of light”), arising from the chemoluminescence when white P is exposed to the atmosphere. The metaphoric association between P and light resonates through history: from the discovery of P at the start of the Enlightenment period to the vital role of P in photosynthetic capture of light in crop and food production through to new technologies, which seek to capitalize on the interactions between novel ultrathin P allotropes and light, including photocatalysis, solar energy production, and storage. In this introduction to the Journal of Environmental Quality special section “Celebrating the 350th Anniversary of Discovering Phosphorus—For Better or Worse,” which brings together 22 paper contributions, we shine a spotlight on the historical and emerging challenges and opportunities in research and understanding of the agricultural, environmental, and societal significance of this vital element. We highlight the role of P in water quality impairment and the variable successes of P mitigation measures. We reflect on the need to improve P use efficiency and on the kaleidoscope of challenges facing efficient use of P. We discuss the requirement to focus on place-based solutions for developing effective and lasting P management. Finally, we consider how cross-disciplinary collaborations in P stewardship offer a guiding light for the future, and we explore the glimmers of hope for reconnecting our broken P cycle and the bright new horizons needed to ensure future food, water, and bioresource security for growing global populations

Future phosphorus: advancing new 2D phosphorus allotropes and growing a sustainable bioeconomy

With more than 40 countries currently proposing to boost their national bioeconomies, there is no better time for a clarion call for a “new” bioeconomy, which, at its core, tackles the current disparities and inequalities in phosphorus (P) availability. Existing biofuel production systems have widened P inequalities and contributed to a linear P economy, impairing water quality and accelerating dependence on P fertilizers manufactured from finite nonrenewable phosphate rock reserves. Here, we explore how the emerging bioeconomy in novel, value-added, bio-based products offers opportunities to rethink our stewardship of P. Development of integrated value chains of new bio-based products offers opportunities for codevelopment of “P refineries” to recover P fertilizer products from organic wastes. Advances in material sciences are exploiting unique semiconductor and opto-electrical properties of new “two-dimensional” (2D) P allotropes (2D black phosphorus and blue phosphorus). These novel P materials offer the tantalizing prospect of step-change innovations in renewable energy production and storage, in biomedical applications, and in biomimetic processes, including artificial photosynthesis. They also offer a possible antidote to the P paradox that our agricultural production systems have engineered us into, as well as the potential to expand the future role of P in securing sustainability across both agroecological and technological domains of the bioeconomy. However, a myriad of social, technological, and commercialization hurdles remains to be crossed before such an advanced circular P bioeconomy can be realized. The emerging bioeconomy is just one piece of a much larger puzzle of how to achieve more sustainable and circular horizons in our future use of P

Degree of Phosphorus Saturation as a Predictor of Redox-Induced Phosphorus Release from Flooded Soils to Floodwater

Phosphorus (P) loss from soils is often enhanced under flooded, anaerobic conditions, increasing the risk of freshwater eutrophication. We aimed to develop a predictive tool to identify soils with greater P release potential under summer‐flooded conditions, which would help in developing strategies to mitigate P losses. One in situ mesocosm study was conducted in field plots with three treatments: cattle manure amended, monoammonium phosphate amended, and unamended. Two ex situ field mesocosm studies were conducted, each having 12 surface soils from agricultural fields. Prior to flooding, soils were analyzed for various soil test P (STP, intensity) and P sorption measures (capacity), and degree of P saturation (DPS) indices were calculated using different intensity and capacity combinations. Mesocosms were flooded and redox potential, pore water, and floodwater dissolved reactive P (DRP) concentrations were determined periodically up to 42 (in situ) and 56 d (ex situ) after the onset of flooding. Floodwater DRP increased significantly in most soils with flooding time, and the maximum DRP (DRPmax) was considered as the flooding‐induced P release risk. Relationships between floodwater DRPmax and STP or DPS indices were established separately for low‐P (Olsen P ≤ 30 mg kg−1) and high‐P (>30 mg kg−1) soils. Several STP indices effectively predicted the P release risk from high‐P soils, but not from low‐P soils. However, DPS calculated using Olsen P (intensity) and P sorption capacity or P saturation index (capacity) performed better in predicting summer flooding‐induced P release across all soil categories, with a higher predictive power."This work was supported by the Manitoba Conservation and Water Stewardship Fund, Environment Canada through the Lake Winnipeg Basin Stewardship Fund (EC no. 1300328), and a University of Winnipeg major grant. We also acknowledge the Manitoba Graduate Scholarship program and the University of Winnipeg Graduate Assistantship Program."https://acsess.onlinelibrary.wiley.com/doi/10.2134/jeq2019.04.015

Light emission from a scanning tunneling microscope: Fully retarded calculation

The light emission rate from a scanning tunneling microscope (STM) scanning a noble metal surface is calculated taking retardation effects into account. As in our previous, non-retarded theory [Johansson, Monreal, and Apell, Phys. Rev. B 42, 9210 (1990)], the STM tip is modeled by a sphere, and the dielectric properties of tip and sample are described by experimentally measured dielectric functions. The calculations are based on exact diffraction theory through the vector equivalent of the Kirchoff integral. The present results are qualitatively similar to those of the non-retarded calculations. The light emission spectra have pronounced resonance peaks due to the formation of a tip-induced plasmon mode localized to the cavity between the tip and the sample. At a quantitative level, the effects of retardation are rather small as long as the sample material is Au or Cu, and the tip consists of W or Ir. However, for Ag samples, in which the resistive losses are smaller, the inclusion of retardation effects in the calculation leads to larger changes: the resonance energy decreases by 0.2-0.3 eV, and the resonance broadens. These changes improve the agreement with experiment. For a Ag sample and an Ir tip, the quantum efficiency is $\approx$ 10$^{-4}$ emitted photons in the visible frequency range per tunneling electron. A study of the energy dissipation into the tip and sample shows that in total about 1 % of the electrons undergo inelastic processes while tunneling.Comment: 16 pages, 10 figures (1 ps, 9 tex, automatically included); To appear in Phys. Rev. B (15 October 1998