Esterification of methacrylic acid with ethylene glycol over heteropolyacid supported on ZSM-5

Esterification of methacrylic acid with ethylene glycol was carried out over Heteropolyacids [HPA: H4SiW12O40 (STA) and H3PW12O40 (PTA)] supported on ZSM-5. For comparison, the same reaction was carried out over unsupported HPA, H 2SO4, BF3 and PTSA. Among the catalysts studied, HPA showed better activity compared to H2SO4, BF3 and PTSA. Catalytic activity was compared with HPA supported ZSM-5 catalysts. Typical results indicated that 30 wt% PTA supported on ZSM-5 showed nearly the same activity as that of bulk PTA. It was found that the reaction follows first order kinetics with respect to methacrylic acid. The reaction products were identified by 1H-NMR and FT-IR

Saturation and Wilson Line Distributions

We introduce a Wilson line distribution function bar{W}_tau(v) to study gluon saturation at small Feynman x_F, or large tau=ln(1/x_F). This new distribution can be obtained from the distribution W_tau(alpha) of the Color Glass Condensate model and the JIMWLK renormalization group equation. bar{W}_tau(v) is physically more relevant, and mathematically simpler to deal with because of unitarity of the Wilson line v. A JIMWLK equation is derived for bar{W}_tau(v); its properties are studied. These properties are used to complete Mueller's derivation of the JIMWLK equation, though for bar{W}_tau(v) and not W_tau(alpha). They are used to derive a generalized Balitsky-Kovchegov equation for higher multipole amplitudes. They are also used to compute the unintegrated gluon distribution at x_F=0, yielding a completely flat spectrum in transverse momentum squared k^2, with a known height. This is similar but not identical to the mean field result at small k^2.Comment: One reference and two short comments added. To appear in Physical Revies

Internal photoemission in molecular junctions: Parameters for interfacial barrier determinations

The photocurrent spectra for large-area molecular junctions are reported, where partially transparent copper top contacts permit illumination by UV-vis light. The effect of variation of the molecular structure and thickness are discussed. Internal photoemission (IPE), a process involving optical excitation of hot carriers in the contacts followed by transport across internal system barriers, is dominant when the molecular component does not absorb light. The IPE spectrum contains information regarding energy level alignment within a complete, working molecular junction, with the photocurrent sign indicating transport through either the occupied or unoccupied molecular orbitals. At photon energies where the molecular layer absorbs, a secondary phenomenon is operative in addition to IPE. In order to distinguish IPE from this secondary mechanism, we show the effect of the source intensity as well as the thickness of the molecular layer on the observed photocurrent. Our results clearly show that the IPE mechanism can be differentiated from the secondary mechanism by the effects of variation of experimental parameters. We conclude that IPE can provide valuable information regarding interfacial energetics in intact, working molecular junctions, including clear discrimination of charge transport mediated by electrons through unoccupied system orbitals from that mediated by hole transport through occupied system orbitals.Peer reviewed: YesNRC publication: Ye