243 research outputs found
Tetragonal to orthorhombic phase transition in SmFeAsO: a synchrotron powder diffraction investigation
The crystal structure of SmFeAsO has been investigated by means of Rietveld
refinement of high resolution synchrotron powder diffraction data collected at
300 K and 100 K. The compound crystallizes in the tetragonal P4/nmm space group
at 300 K and in the orthorhombic Cmma space group at 100 K; attempts to refine
the low temperature data in the monoclinic P112/n space group diverged. On the
basis of both resistive and magnetic analyses the tetragonal to orthorhombic
phase transition can be located at T about 140 K.Comment: Submitted to: Superconductor Science and Technology PACS: 61.05.cp,
61.66.Fn, 74.10.+v, 74.62.Dh, 74.70.D
Growth methods of c-axis oriented MgB2 thin films by pulsed laser deposition
High quality MgB2 thin films have been obtained by pulsed laser deposition
both on MgO and on Al2O3 substrates using different methods. In the standard
two-step procedure, an amorphous precursor layer is deposited at room
temperature starting both from stoichiometric target and from boron target:
after this first step, it is annealed in magnesium atmosphere in order to
crystallize the superconducting phase. The so obtained films show a strong
c-axis orientation, evidenced by XRD analysis, a critical temperature up to 38
K and very high critical fields along the basal planes, up to 22T at 15K. Also
an in situ one step technique for the realization of superconducting MgB2 thin
films has been developed. In this case, the presence of an argon buffer gas
during deposition is crucial and we observe a strong dependence of the quality
of the deposited film on the background gas pressure. The influence of the Ar
atmosphere has been confirmed by time and space-resolved spectroscopy
measurements on the emission spectrum of the plume. The Ar pressure modifies
strongly the plasma kinetics by promoting excitation and ionization of the
plume species, especially of the most volatile Mg atoms, increasing their
internal energy.Comment: Paper presented at Boromag Workshop, Genoa 17-19 June 2002, in press
on SUS
Experimental confirmation of the low B isotope coefficient in MgB2
Recent investigations have shown that the first proposed explanations of the
disagreement between experimental and theoretical value of isotope coefficient
in MgB2 need to be reconsidered. Considering that in samples with residual
resistivity of few mu-Ohm cm critical temperature variations produced by
disorder effects can be comparable with variations due to the isotopic effect,
we adopt a procedure in evaluating the B isotope coefficient which take account
of these effects, obtaining a value which is in agreement with previous results
and then confirming that there is something still unclear in the physics of
MgB2.Comment: 8 pages, 3 figures Title has been changed A statement has been added
in page 7 of the pdf file "Finally we would..." Reference 21 has been added
Figure 1 anf Figure 2 have been change
Tc=21K in epitaxial FeSe0.5Te0.5 thin films with biaxial compressive strain
High purity epitaxial FeSe0.5Te0.5 thin films with different thickness were
grown by Pulsed Laser Ablation on different substrates. By varying the film
thickness, Tc up to 21K were observed, significantly larger than the bulk
value. Structural analyses indicated that the a axis changes significantly with
the film thickness and is linearly related to the Tc. The latter result
indicates the important role of the compressive strain in enhancing Tc. Tc is
also related to both the Fe-(Se,Te) bond length and angle, suggesting the
possibility of further enhancement
The Crossover beteween Aslamazov-Larkin and Short Wavelength Fluctuations Regimes in HTS Conductivity Experiments
We present paraconductivity (AL) measurements in three different high
temperature superconductors: a melt textured sample, a
epitaxial thin film and a highly textured
tape. The crossovers between different temperature
regimes in excess conductivity have been analysed. The Lawrence-Doniach (LD)
crossover, which separates the 2D and 3D regimes, shifts from lower to higher
temperatures as the compound anisotropy decreases. Once the LD crossover is
overcome, the fluctuation conductivity of the three compounds shows the same
universal behaviour: for all the curves bend down
according to the law. This asymptotic behaviour was
theoretically predicted previously for the high temperature region where the
short wavelength fluctuations (SWF) become important.Comment: 4 pages, Revtex, 1 PostScript figure available upon request
([email protected]); submitted to Physical Review B rapid communication
Highly effective and isotropic pinning in epitaxial Fe(Se,Te) thin films grown on CaF2 substrates
We report on the isotropic pinning obtained in epitaxial Fe(Se,Te) thin films
grown on CaF2 (001) substrate. High critical current density values larger than
1 MA/cm2 in self field in liquid helium are reached together with a very weak
dependence on the magnetic field and a complete isotropy. Analysis through
Transmission Electron Microscopy evidences the presence of defects looking like
lattice disorder at a very small scale, between 5 and 20 nm, which are thought
to be responsible for such isotropic behavior in contrast to what observed on
SrTiO3, where defects parallel to the c-axis enhance pinning in that directio
Effect of grain refinement on enhancing critical current density and upper critical field in undoped MgB2 ex-situ tapes
Ex-situ Powder-In-Tube MgB2 tapes prepared with ball-milled, undoped powders
showed a strong enhancement of the irreversibility field H*, the upper critical
field Hc2 and the critical current density Jc(H) together with the suppression
of the anisotropy of all of these quantities. Jc reached 104 A/cm2 at 4.2 K and
10 T, with an irreversibility field of about 14 T at 4.2 K, and Hc2 of 9 T at
25 K, high values for not-doped MgB2. The enhanced Jc and H* values are
associated with significant grain refinement produced by milling of the MgB2
powder, which enhances grain boundary pinning, although at the same time also
reducing the connectivity from about 12% to 8%. Although enhanced pinning and
diminished connectivity are in opposition, the overall influence of ball
milling on Jc is positive because the increased density of grains with a size
comparable with the mean free path produces strong electron scattering that
substantially increases Hc2, especially Hc2 perpendicular to the Mg and B
planes.Comment: 26 pages, 9 figures, submitted to J. Appl. Phy
Anisotropic critical currents in FeSe0.5Te0.5 films and the influence of neutron irradiation
We report on measurements of the superconducting properties of FeSe05Te05
thin films grown on lanthanum aluminate. The films have high transition
temperatures (above 19 K) and sharp resistive transitions in fields up to 15 T.
The temperature dependence of the upper critical field and the irreversibility
lines are steep and anisotropic, as recently reported for single crystals. The
critical current densities, assessed by magnetization measurements in a vector
VSM, were found to be well above 10^9 Am-2 at low temperatures. In all samples,
the critical current as a function of field orientation has a maximum, when the
field is oriented parallel to the film surface. The maximum indicates the
presence of correlated pinning centers. A minimum occurs in three films, when
the field is applied perpendicular to the film plane. In the forth film,
instead, a local maximum caused by c-axis correlated pinning centers was found
at this orientation. The irradiation of two films with fast neutrons did not
change the properties drastically, where a maximum enhancement of the critical
current by a factor of two was found
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