Fluorescence quenching of versatile fluorescent probes based on strongly electron-donating distyrylbenzenes responsive to aromatic chlorinated and nitro compounds, boronic acid and Ca2+

ArticleSPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY. 69(1): 167-173journal articl

Characteristic impedance and its applications to rock and mining engineering

Abstract The characteristic impedance of a rock is defined as the product of the sonic velocity and the density of the rock. Based on previous studies, this article finds that: (1) For an intact rock, its characteristic impedance is a comprehensive physical property, since it is closely related with strengths, fracture toughness, Young’s modulus, and Poisson’s ratio. (2) For rock masses, their characteristic impedances either increase markedly or slightly with increasing depth. (3) The bursts of intact rocks in laboratory are dependent on their characteristic impedances to a great extent, and strong rock bursts happen mostly in the rocks with large characteristic impedance. (4) Rock burst occurrence in tunnel and mines has a close relation with the characteristic impedances of the rocks. (5) Laboratory experiments on different rock samples show that seismic velocity increases as applied stress rises, and field monitored results from coal mines indicate that in the areas where rock bursts happened, the seismic velocity was increasing markedly before or during the bursts. (7) Drillability of rock depends on the characteristic impedance of the rock and the rock with larger impedance has lower drillability or lower penetration rate. (8) The potential applications of characteristic impedance include evaluation and classification of rock masses, and prediction of rock burst proneness and drillability

Energy dissipation and particle size distribution of granite under different incident energies in SHPB compression tests

Abstract To investigate energy dissipation and particle size distribution of rock under dynamic loads, a series of dynamic compression tests of granite specimens were conducted using a conventional split-Hopkinson pressure bar (SHPB) device with a high-speed camera. The experimental results show that the dissipated energy increases linearly with an increasing incident energy, following two different inclined paths connected by a critical incident energy, and the linear energy dissipation law in the dynamic compression test has been confirmed. This critical incident energy was found to be 0.29–0.33 MJ/m³. As the incident energy was smaller than the critical incident energy, the rock specimens remained unruptured after the impact. When the incident energy was greater than the critical incident energy, the rock specimens were ruptured or fragmented after the impact. In addition, the experimental results indicate that the dissipated energy and energy consumption ratio of a rock specimen, either unruptured or fragmented, increase with an increasing strain rate. Furthermore, it was found that fragment sizes at each mesh decrease with an increasing incident energy; that is, fragmentation becomes finer as incident energy increases