Echo in a Single Molecule

Echo is a ubiquitous phenomenon found in many physical systems, ranging from spins in magnetic fields to particle beams in hadron accelerators. It is typically observed in inhomogeneously broadened ensembles of nonlinear objects, and is used to eliminate the effects of environmental-induced dephasing, enabling observation of proper, inherent object properties. Here, we report experimental observation of quantum wave packet echoes in a single isolated molecule. In contrast to conventional echoes, here the entire dephasing-rephasing cycle occurs within a single molecule without any inhomogeneous spread of molecular properties, or any interaction with the environment. In our experiments, we use a short laser pulse to impulsively excite a vibrational wave packet in an anharmonic molecular potential, and observe its oscillations and eventual dispersion with time. A second delayed pulsed excitation is applied, giving rise to an echo: a partial recovery of the initial coherent wavepacket. The vibrational dynamics of single molecules is visualized by time-delayed probe pulse dissociating them one at a time. Two mechanisms for the echo formation are discussed: ac Stark-induced molecular potential shaking and creation of depletion-induced "hole" in the nuclear spatial distribution. Interplay between the optically induced echoes and quantum revivals of the vibrational wave packets is observed and theoretically analyzed. The single molecule wave packet echoes may lead to the development of new tools for probing ultrafast intramolecular processes in various molecules.Comment: 9 pages, 7 figure

Preparation and properties of antistatic high-strength aramid III/MWCNTs-OH fibers

Composite fibers made from aramid III and hydroxylated multiwalled carbon nanotubes (MWCNTs-OH) combine the excellent mechanical and electrical properties of both components, resulting in strong antistatic performance. However, it is of paramount importance to ensure the homogeneous dispersion of multi-walled carbon nanotubes functionalized with hydroxyl groups (MWCNTs-OH) within the aramid III spinning solution and optimize the compatibility between the two constituents to augment the overall performance of the composite fibers. To this end, this investigation successfully accomplished the dispersion of MWCNTs-OH in the spinning solution and probed the dispersion mechanism using molecular dynamics simulations. Moreover, composite fibers, comprising 2.4 weight percent MWCNTs-OH, were initially fabricated using the wet spinning method. These fibers displayed a uniform texture and a tensile strength of 1.210 GPa, signifying a noteworthy enhancement of 113.25% in comparison to the strength prior to modification. With respect to thermal behavior, the fibers exhibited a mass reduction of 21.24% within the temperature range of 0°C–538°C. In the temperature interval from 538°C to 800°C, the mass loss diminished to 10.31%, representing a substantial 71.03% reduction when compared to the unmodified state. Remarkably, even when subjected to temperatures exceeding 800°C, the composite fibers retained a residual mass of 68.45%, indicating a notable 61.17% increase from their initial condition. In terms of electrical properties, the fibers exhibited a specific resistance (ρ) of 3.330 × 109 Ω cm, demonstrating effective antistatic behavior. In summary, the antistatic composite fibers studied in this paper can effectively mitigate the hazards of static electricity in various applications, including military protection and engineering equipment in both military and civilian fields

Investigation on Ground Collapse Due to Exfiltration of Shallowly Buried Water-Supply Pipeline

Pipeline exfiltration from damaged water-supply systems frequently causes soil erosion and ground subsidence, which jeopardizes the safety of pedestrians and vehicles and even causes casualties. Despite the severe consequences, it is difficult for engineers to give reliable assessments of pipeline exfiltration hazards. In this study, erosion processes were explored using model tests and coupled computational fluid dynamics–discrete element method (CFD-DEM) simulations. It was discovered that the erosion zone can be divided into two zones—the exfiltration zone and the seepage diffusion zone. When water pressure reached 2.412 × 10−2 MPa, local porosity approached 1.0, indicating there were no soil particles remaining. As pipeline pressure increased from 2.122 × 10−3 MPa to 2.412 × 10−2 MPa, ground failure transitioned from downward settlement to upward bulge, and the ground failure duration of the fractured prototype pipe was reduced by 22–28% (from 125 s to 98 s), with a standard deviation of less than 5. The established exponential decay model (v(t)=v0e(−αt),R2>0.89) enabled prediction of erosion duration. Based on the erosion height curve, the erosion duration and erosion area in similar engineering environments can be estimated, providing a reference for evaluating the risk of ground collapse due to pipe exfiltration

Multi-Scale Investigation on Bearing Capacity and Load-Transfer Mechanism of Screw Pile Group via Model Tests and DEM Simulation

Screw piles are widely used in infrastructure, such as railways, highways, and ports, etc., owing to their large pile resistance compared to unthreaded piles. While most screw pile research focuses on single pile behavior under rotational installation using torque-capacity correlations. Limited studies investigate group effects under alternative installation methods. In this study, the load-transfer mechanism of screw piles and soil displacement under vertical installation was explored using laboratory model tests combined with digital image correlation techniques. In addition, numerical simulations using the discrete element method were performed. Based on both lab tests and numerical simulation results, it is discovered that the ultimate bearing capacity of a single screw pile was approximately 50% higher than that of a cylindrical pile with the same outer diameter and length. For pile groups, the group effect coefficient of a triple-pile group composed of screw piles was 0.64, while that of cylindrical piles was 0.55. This phenomenon was caused by the unique thread-soil interaction of screw piles. The threads generated greater side resistance and reduced stress concentration at the pile tip compared with cylindrical piles. Moreover, the effects of pile type, pile number, embedment length, pile spacing, and thread pitch on pile resistance and soil displacement were also investigated. The findings in this study revealed the micro–macro correspondence of screw pile performance and can serve as references for pile construction in practice

Research on High Precision Angle Measurement and Compensation Technology Based on Circular Grating

Abstract In this paper, the angle measurement method of high-precision circular grating is studied. The principle analysis of circular grating angle measurement, the principle analysis of multi reading head, and the design of rotary servo control system are carried out. After analyzing the error model of circular grating angle measurement, the research based on harmonic compensation model is carried out respectively. Aiming at the problem of zero crossing oscillation of compensation algorithm, the piecewise compensation strategy is designed, which fully demonstrates the application value of circular grating angle measurement method in high-precision angle measurement system.</jats:p

Impact of Red Imported Fire Ant Nest-Building on Soil Properties and Bacterial Communities in Different Habitats

The red imported fire ant (Solenopsis invicta Buren) is a highly adaptable invasive species that can nest and reproduce in different habitat soils. We aimed to explore the adaptability of red imported fire ants in different habitats by analyzing changes in the physicochemical properties of nest soils and bacterial communities. Five habitat types (forest, tea plantation, rice field, lawn, and brassica field) were selected. The results showed that the pH of the nest soils increased significantly in all five habitats compared to the control soils of the same habitat. A significant increase in nitrogen content was detected in the nests. The Cr, Pb, Cu, and Ni levels were significantly reduced in the soils of the five habitats, due to nesting activities. Analysis of the composition and diversity of the soil microbial community showed that, although the richness and diversity of bacteria in the nest soils of red imported fire ants in the five habitats varied, the relative abundance of Actinobacteria significantly increased and it emerged as the dominant bacterial group. These results indicate that red imported fire ants modify the physicochemical properties of nest soils and bacterial communities to create a suitable habitat for survival and reproduction

Comparative Analyses of Reproductive Caste Types Reveal Vitellogenin Genes Involved in Queen Fertility in Solenopsis invicta

The red imported fire ant (Solenopsis invicta Buren) is a social pest species with a robust reproductive ability that causes extensive damage. Identification of the genes involved in queen fertility is critical in order to better understand the reproductive biology and screening for the potential molecular targets in S. invicta. Here, we used the mRNA deep sequencing (RNA-seq) approach to identify differentially expressed genes (DEGs) in the transcriptomes of three reproductive caste types of S. invicta, including queen (QA) and winged female (FA) and male (MA) ants. The genes that were specific to and highly expressed in the queens were then screened, and the Vg2 and Vg3 genes were chosen as targets to explore their functions in oogenesis and fertility. A minimum of 6.08 giga bases (Gb) of clean reads was obtained from all samples, with a mapping rate &gt; 89.78%. There were 7524, 7133, and 977 DEGs identified in the MA vs. QA, MA vs. FA, and FA vs. QA comparisons, respectively. qRT&ndash;PCR was used to validate 10 randomly selected DEGs, including vitellogenin 2 (Vg2) and 3 (Vg3), and their expression patterns were mostly consistent with the RNA-seq data. The S. invicta Vgs included conserved domains and motifs that are commonly found in most insect Vgs. SiVg2 and SiVg3 were highly expressed in queens and winged females and were most highly expressed in the thorax, followed by the fat body, head, and epidermis. Evaluation based on a loss-of-function-based knockdown analysis showed that the downregulation of either or both of these genes resulted in smaller ovaries, less oogenesis, and less egg production. The results of transcriptional sequencing provide a foundation for clarifying the regulators of queen fertility in S. invicta. The functions of SiVg2 and SiVg3 as regulators of oogenesis highlight their importance in queen fecundity and their potential as targets of reproductive disruption in S. invicta control

First Record of Aspergillus fijiensis as an Entomopathogenic Fungus against Asian Citrus Psyllid, Diaphorina citri Kuwayama (Hemiptera: Liviidae)

The Asian citrus psyllid Diaphorina citri Kuwayama (Hemiptera: Liviidae) is the most widespread and devastating pest species in citrus orchards and is the natural vector of the phloem-limited bacterium that causes Huanglongbing (HLB) disease. Thus, reducing the population of D. citri is an important means to prevent the spread of HLB disease. Due to the long-term use of chemical control, biological control has become the most promising strategy. In this study, a novel highly pathogenic fungal strain was isolated from naturally infected cadavers of adult D. citri. The species was identified as Aspergillus fijiensis using morphological identification and phylogenetic analysis and assigned the strain name GDIZM-1. Tests to detect aflatoxin B1 demonstrated that A. fijiensis GDIZM-1 is a non-aflatoxin B1 producer. The pathogenicity of the strain against D. citri was determined under laboratory and greenhouse conditions. The results of the laboratory study indicated that nymphs from the 1st to 5th instar and adults of D. citri were infected by A. fijiensis GDIZM-1. The mortality of nymphs and adults of D. citri caused by infection with A. fijiensis increased with the concentration of the conidial suspension and exposure time, and the median lethal concentration (LC50) and median lethal time (LT50) values gradually decreased. The mortality of D. citri for all instars was higher than 70%, with high pathogenicity at the 7th day post treatment with 1 &times; 108 conidia/mL. The results of the greenhouse pathogenicity tests showed that the survival of D. citri adults was 3.33% on the 14th day post-treatment with 1 &times; 108 conidia/mL, which was significantly lower than that after treatment with the Metarhizium anisopliae GDIZMMa-3 strain and sterile water. The results of the present study revealed that the isolate of A. fijiensis GDIZM-1 was effective against D. citri and it provides a basis for the development of a new microbial pesticide against D. citri after validation of these results in the field