40 research outputs found
Direct Patterning of Organic Functional Polymers through Conventional Photolithography and Noninvasive Cross-Link Agents
A new technique for direct patterning of functional organic polymers using commercial photolithography setups with a minimal loss of the materials' performances is reported. This result is achieved through novel cross-link agents made by boron- and fluorine-containing heterocycles that can react between themselves upon UV- and white-light exposure
Ultrafast Delamination of Graphite into High-Quality Graphene Using Alternating Currents
To bridge the gap between laboratory‐scale studies and commercial applications, mass production of high quality graphene is essential. A scalable exfoliation strategy towards the production of graphene sheets is presented that has excellent yield (ca. 75 %, 1–3 layers), low defect density (a C/O ratio of 21.2), great solution‐processability, and outstanding electronic properties (a hole mobility of 430 cm2 V−1 s−1). By applying alternating currents, dual exfoliation at both graphite electrodes enables a high production rate exceeding 20 g h−1 in laboratory tests. As a cathode material for lithium storage, graphene‐wrapped LiFePO4 particles deliver a high capacity of 167 mAh g−1 at 1 C rate after 500 cycles
On-surface synthesis of graphene nanoribbons with zigzag edge topology
Graphene-based nanostructures exhibit a vast range of exciting electronic
properties that are absent in extended graphene. For example, quantum
confinement in carbon nanotubes and armchair graphene nanoribbons (AGNRs) leads
to the opening of substantial electronic band gaps that are directly linked to
their structural boundary conditions. Even more intriguing are nanostructures
with zigzag edges, which are expected to host spin-polarized electronic edge
states and can thus serve as key elements for graphene-based spintronics. The
most prominent example is zigzag graphene nanoribbons (ZGNRs) for which the
edge states are predicted to couple ferromagnetically along the edge and
antiferromagnetically between them. So far, a direct observation of the
spin-polarized edge states for specifically designed and controlled zigzag edge
topologies has not been achieved. This is mainly due to the limited precision
of current top-down approaches, which results in poorly defined edge
structures. Bottom-up fabrication approaches, on the other hand, were so far
only successfully applied to the growth of AGNRs and related structures. Here,
we describe the successful bottom-up synthesis of ZGNRs, which are fabricated
by the surface-assisted colligation and cyclodehydrogenation of specifically
designed precursor monomers including carbon groups that yield atomically
precise zigzag edges. Using scanning tunnelling spectroscopy we prove the
existence of edge-localized states with large energy splittings. We expect that
the availability of ZGNRs will finally allow the characterization of their
predicted spin-related properties such as spin confinement and filtering, and
ultimately add the spin degree of freedom to graphene-based circuitry.Comment: 15 pages, 4 figure