Evolution of palladium sulfide phases during thermal treatments and consequences for acetylene hydrogenation

We thank Diamond Light Source for beamline access B18 (SP15151-5) and are grateful to the expertise and help provided by Dr Emma Gibson (UK Catalysis Hub, Harwell) and Diego Gianolio (Beamline Scientist on B18) whilst data collecting. XPS data collection was performed at the EPSRC National Facility for XPS (‘HarwellXPS’), operated by Cardiff University and UCL, under contract No. PR16195. We would also like to thank Prof. Philip R. Davies for helpful discussions on XPS data analysis. This work was partly supported by the National Key Research and Development Program of China (2016YFB0301601), National Natural Science Foundation of China.Peer reviewedPostprin

Palladium phosphide nanoparticles as highly selective catalysts for the selective hydrogenation of acetylene

This work was supported by the National Key Research and Development Program of China (2016YFB0301601), National Natural Science Foundation of China.Peer reviewedPostprin

Adsorbate-Induced Structural Evolution of Pd Catalyst for Selective Hydrogenation of Acetylene

ACKNOWLEDGMENT: This work was financially supported by National Natural Science Foundation of China (21908002), project funded by China Postdoctoral Science Foundation (2019M660416, 2020T130045) and the Fundamental Research Funds for the Central Universities (buctrc201921, JD2004, XK1802-6). We would like to thank the UK catalysis Hub for help collecting the XAS.Peer reviewedPostprin

Highly Selective and Stable Isolated Non-Noble Metal Atom Catalysts for Selective Hydrogenation of Acetylene

ACKNOWLEDGMENTS This work was financially supported by National Natural Science Foundation of China (21908002) and the Fundamental Research Funds for the Central Universities (buctrc201921, JD2108).Peer reviewedPostprin

Understanding the Role of Coordinatively Unsaturated Al3+ Sites on Nanoshaped Al2O3 for Creating Uniform Ni–Cu Alloys for Selective Hydrogenation of Acetylene

Acknowledgments This work was financially supported by the National Key R&D Program of China (2021YFB3801600), the National Natural Science Foundation of China (22218017), and the Fundamental Research Funds for the Central Universities (buctrc201921, JD2223). We acknowledge the Beijing Synchrotron Radiation Facility (BSRF) for providing the experimental resources for XAS experiments.Peer reviewedPostprin

Metal-Organic Framework-Derived Ni-S/C Catalysts for Selective Alkyne Hydrogenation

Acknowledgments This work was financially supported by the National Natural Science Foundation of China (22278017), the Fundamental Research Funds for the Central Universities (buctrc202303, JD2325), and the Young Elite Scientists Sponsorship Program by BAST (No. BYESS2023087).Peer reviewedPostprin

Comparison of Pd and Pd4S based catalysts for partial hydrogenation of external and internal butynes

Acknowledgements This work was supported by the National Natural Science Foundation of China (21908002), project funded by China Postdoctoral Science Foundation (2019M660416) and the Fundamental Research Funds for the Central Universities (buctrc201921).Peer reviewedPostprin

Mitigating catalyst deactivation in selective hydrogenation by enhancing dispersion and utilizing reaction heat effect

ACKNOWLEDGMENT This work was financially supported by National Key R&D Program of China (2021YFB3801600), National Natural Science Foundation of China (21908002), and Fundamental Research Funds for the Central Universities (buctrc201921, JD2223).Peer reviewedPostprin

Bone Mineral Density Reference Standards for Chinese Children Aged 3-18: Cross-Sectional Results of the 2013-2015 China Child and Adolescent Cardiovascular Health (CCACH) Study

Objectives: No nationwide paediatric reference standards for bone mineral density (BMD) are available in China. We aimed to provide sex-specific BMD reference values for Chinese children and adolescents (3-18 years). Methods: Data (10 818 participants aged 3-18 years) were obtained from cross-sectional surveys of the China Child and Adolescent Cardiovascular Health in 2015, which included four municipality cities and three provinces. BMD was measured using Hologic Discovery Dual Energy X-ray Absorptiometry (DXA) scanner. The DXA measures were modelled against age, with height as an independent variable. The LMS statistical method using a curve fitting procedure was used to construct reference smooth cross-sectional centile curves for dependent versus independent variables. Results: Children residing in Northeast China had the highest total body less head (TBLH) BMD while children residing in Shandong Province had the lowest values. Among children, TBLH BMD was higher for boys as compared with girls; but, it increased with age and height in both sexes. Furthermore, TBLH BMD was higher among US children as compared with Chinese children. There was a large difference in BMD for height among children from these two countries. US children had a much higher BMD at each percentile (P) than Chinese children; the largest observed difference was at P50 and P3 and the smallest difference was at P97. Conclusions: This is the first study to present a sex-specific reference dataset for Chinese children aged 3-18 years. The data can help clinicians improve interpretation, assessment and monitoring of densitometry results