107 research outputs found
(5R)-5-[(1R)-2,2-Dichloro-1-methylcyclopropyl]-2-methylcyclohex-2-en-1-one
The title compound, C11H14Cl2O, was synthesized by the reaction of a dichloromethane solution of (R)-carvone and potassium tert-butanolate in the presence of a catalytic amount of benzyltriethylammonium chloride in chloroform. The cyclohexene ring adopts a half-boat conformation. The cyclopropyl ring is unsymmetrical, the shortest C—C bond being distal to the alkyl-substituted C atom. The crystal packing is stabilized only by van der Waals interactions
ChemInform Abstract: Reactions of Organic Anions. Part 164. Formation of gem-Dichlorocyclopropanes from Perhalomethanes and Alkenes in a Phase-Transfer Catalytic (PTC) System.
ChemInform Abstract: REACTIONS OF ORGANIC ANIONS, LXXVI. A CONVENIENT PROCEDURE FOR THE GENERATION OF BROMOCHLOROCARBENE AND PREPARATION OF GEM-BROMOCHLOROCYCLOPROPANE DERIVATIVES
ChemInform Abstract: Phase-Transfer Catalysis: A Convenient Tool for the Functionalization of Benzocyclobutene-1-carbonitrile.
Solid - liquid phase transfer catalysis using solid sodium hydroxide in preparative ethers synthesis
ChemInform Abstract: REACTIONS OF ORGANIC ANIONS. LXXV. A SIMPLE METHOD FOR PREPARATION OF DIBROMOCHLOROMETHANE AND BROMODICHLOROMETHANE
ChemInform Abstract: Phase-Transfer-Catalyzed (PTC) Reactions of Electrophilic Alkenes with Carbon Tetrachloride and Alcohols.
- …
