6 research outputs found
Kinetics and mechanism of the reaction of chlorous acid with chlorate in aqueous sulfuric acid
No full textInfluence of Mercuric Nitrate on Species and Reactions Related to Chlorine Dioxide Formation
No full text
Synthesis of Dimethyl Derivatives of Imidazolinone Herbicides: Their Use in Efficient Gas Chromatographic Methods for the Determination of These Herbicides
No full textESR spin-trap study of the radicals present during the thermolysis of some novel alkyl peroxy esters.
No full textThe thermolysis of four alkylperoxy esters was undertaken at various temperatures between 300 and 353 K and the radicals generated were trapped employing DMPO, DEPMPO, PBN-d14 and TTBNB. The adducts of a range of second-generation carbon-centred radicals, formed via decarboxylation of the acyloxyl moiety, including those of the 2,4,4-trimethylpentyl and hept-3-yl radicals, were also observed. The co-generated tert-alkoxyl radicals, released during the thermolysis of tert-butylperoxy-3,3,5-trimethylhexanoate, tert-amylperoxy-2-ethylhexanoate and the bifunctional peroxide 2,5-dimethyl-2,5-bis(2-ethylhexanoylperoxy)hexane, were all successfully trapped, as were a range of second-generation carbon-centred radicals formed following -scission of these tert-alkoxyl radicals
