Very deep spectroscopy of the bright Saturn Nebula NGC 7009 -- I. Observations and plasma diagnostics

We present very deep CCD spectrum of the bright, medium-excitation planetary nebula NGC 7009, with a wavelength coverage from 3040 to 11000 A. Traditional emission line identification is carried out to identify all the emission features in the spectra, based on the available laboratory atomic transition data. Since the spectra are of medium resolution, we use multi-Gaussian line profile fitting to deblend faint blended lines, most of which are optical recombination lines (ORLs) emitted by singly ionized ions of abundant second-row elements such as C, N, O and Ne. Computer-aided emission-line identification, using the code EMILI developed by Sharpee et al., is then employed to further identify all the emission lines thus obtained. In total about 1200 emission features are identified, with the faintest ones down to fluxes 10^{-4} of H_beta. The flux errors for all emission lines, estimated from multi-Gaussian fitting, are presented. Plots of the whole optical spectrum, identified emission lines labeled, are presented along with the results of multi-Gaussian fits. Plasma diagnostics using optical forbidden line ratios are carried out. Also derived are electron temperatures and densities from the H I, He I and He II recombination spectrum.Comment: 66 pages, 16 figures, 7 tables, paper accepted by MNRAS in Marc

Spectroscopic Observations of Planetary Nebulae in the Northern Spur of M31

We present spectroscopy of three planetary nebulae (PNe) in the Northern Spur of the Andromeda Galaxy (M31) obtained with the Double Spectrograph on the 5.1 m Hale Telescope at the Palomar Observatory. The samples are selected from the observations of Merrett et al. Our purpose is to investigate formation of the substructures of M31 using PNe as a tracer of chemical abundances. The [O III] 4363 auroral line is detected in the spectra of two objects, enabling temperature determinations. Ionic abundances are derived from the observed collisionally excited lines, and elemental abundances of nitrogen, oxygen, and neon as well as sulphur and argon are estimated. Correlations between oxygen and the alpha-element abundance ratios are studied, using our sample and the M31 disk and bulge PNe from the literature. In one of the three PNe, we observed relatively higher oxygen abundance compared to the disk sample in M31 at similar galactocentric distances. The results of at least one of the three Northern Spur PNe might be in line with the proposed possible origin of the Northern Spur substructure of M31, i.e. the Northern Spur is connected to the Southern Stream and both substructures comprise the tidal debris of the satellite galaxies of M31.Comment: 5 tables, 17 figures; accepted for publication in Ap

Very Large Telescope deep echelle spectroscopy of Galactic planetary nebulae NGC6153, M1-42 and Hf2-2

published_or_final_versio

Tailoring microstructure and texture of annealed Al-Mn alloy through the variation of homogenization and prior cold deformation strain

The grain structures and crystallographic textures desired for various applications of aluminium alloys are usually modified by recrystallization during annealing. In this study, the interactions between recrystallization and precipitation were investigated using the same Al-Mn alloy but with different homogenization procedures (which gives different microchemistries in terms of solute level and second phase particle state) and prior cold deformation strains, both of which are easy to realize in industrial practice. The results show that recrystallization and precipitation kinetics are both promoted at large deformations but their mutual interactions also exis

The Properties of H{\alpha} Emission-Line Galaxies at z = 2.24

Using deep narrow-band $H_2S1$ and $K_{s}$-band imaging data obtained with CFHT/WIRCam, we identify a sample of 56 H$\alpha$ emission-line galaxies (ELGs) at $z=2.24$ with the 5$\sigma$ depths of $H_2S1=22.8$ and $K_{s}=24.8$ (AB) over 383 arcmin$^{2}$ area in the ECDFS. A detailed analysis is carried out with existing multi-wavelength data in this field. Three of the 56 H$\alpha$ ELGs are detected in Chandra 4 Ms X-ray observation and two of them are classified as AGNs. The rest-frame UV and optical morphologies revealed by HST/ACS and WFC3 deep images show that nearly half of the H$\alpha$ ELGs are either merging systems or with a close companion, indicating that the merging/interacting processes play a key role in regulating star formation at cosmic epoch z=2-3; About 14% are too faint to be resolved in the rest-frame UV morphology due to high dust extinction. We estimate dust extinction from SEDs. We find that dust extinction is generally correlated with H$\alpha$ luminosity and stellar mass (SM). Our results suggest that H$\alpha$ ELGs are representative of star-forming galaxies (SFGs). Applying extinction correction for individual objects, we examine the intrinsic H$\alpha$ luminosity function (LF) at $z=2.24$, obtaining a best-fit Schechter function characterized by a faint-end slope of $\alpha=-1.3$. This is shallower than the typical slope of $\alpha \sim -1.6$ in previous works based on constant extinction correction. We demonstrate that this difference is mainly due to the different extinction corrections. The proper extinction correction is thus key to recovering the intrinsic LF as the extinction globally increases with H$\alpha$ luminosity. Moreover, we find that our H$\alpha$ LF mirrors the SM function of SFGs at the same cosmic epoch. This finding indeed reflects the tight correlation between SFR and SM for the SFGs, i.e., the so-called main sequence.Comment: 15 pages, 12 figures, 2 tables, Received 2013 October 11; accepted 2014 February 13; published 2014 March 18 by Ap

Controlling soliton interactions in Bose-Einstein condensates by synchronizing the Feshbach resonance and harmonic trap

We present how to control interactions between solitons, either bright or dark, in Bose-Einstein condensates by synchronizing Feshbach resonance and harmonic trap. Our results show that as long as the scattering length is to be modulated in time via a changing magnetic field near the Feshbach resonance, and the harmonic trapping frequencies are also modulated in time, exact solutions of the one-dimensional nonlinear Schr\"{o}dinger equation can be found in a general closed form, and interactions between two solitons are modulated in detail in currently experimental conditions. We also propose experimental protocols to observe the phenomena such as fusion, fission, warp, oscillation, elastic collision in future experiments.Comment: 7 pages, 7 figure

Mechanism for the Nonadiabatic Photooxidation of Benzene to Phenol: Orientation-Dependent Proton-Coupled Electron Transfer

An efficient catalytic one-step conversion of benzene to phenol was achieved recently by selective photooxidation under mild conditions with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) as the photocatalyst. Herein, high-level electronic structure calculations in the gas phase and in acetonitrile solution are reported to explore the underlying mechanism. The initially populated 1ππ* state of DDQ can relax efficiently through a nearby dark 1nπ* doorway state to the 3ππ* state of DDQ, which is found to be the precursor state involved in the initial intermolecular electron transfer from benzene to DDQ. The subsequent triplet-state reaction between DDQ radical anions, benzene radical cations, and water is computed to be facile. The formed DDQH and benzene-OH radicals can undergo T1→S0 intersystem crossing and concomitant proton-coupled electron transfer (PCET) to generate the products DDQH2 and phenol. Two of the four considered nonadiabatic pathways involve an orientation-dependent triplet PCET process, followed by intersystem crossing to the ground state (S0). The other two first undergo a nonadiabatic T1→S0 transition to produce a zwitterionic S0 complex, followed by a barrierless proton transfer. The present theoretical study identifies novel types of nonadiabatic PCET processes and provides detailed mechanistic insight into DDQ-catalyzed photooxidation