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Heteroleptic Dysprosium(III) Single-Molecule Magnets with Amidinate and Cyclopentadienyl Ligands
Here we use a pseudoallyl ligand, N,N′-chelating amidinate (Am), together with pentamethylcyclopentadienyl
(Cp*) to give two dysprosium(III) single-molecule magnets (SMMs):
[{(AmiPr)DyCp*(μ-Cl)}2] and [AmdippDyCp*(Cl)(μ-Cl)Li(THF)3] with distinct energy barriers
(Ueff) of 97 and 472 K, respectively.
The latter Ueff value is similar to the
homoleptic Cp*-based Dy-SMM