Unraveling radial dependency effects in fiber thermal drawing

Fiber-based devices with advanced functionalities are emerging as promising solutions for various applications in flexible electronics and bioengineering. Multimaterial thermal drawing, in particular, has attracted strong interest for its ability to generate fibers with complex architectures. Thus far, however, the understanding of its fluid dynamics has only been applied to single material preforms for which higher order effects, such as the radial dependency of the axial velocity, could be neglected. With complex multimaterial preforms, such effects must be taken into account, as they can affect the architecture and the functional properties of the resulting fiber device. Here, we propose a versatile model of the thermal drawing of fibers, which takes into account a radially varying axial velocity. Unlike the commonly used cross section averaged approach, our model is capable of predicting radial variations of functional properties caused by the deformation during drawing. This is demonstrated for two effects observed, namely, by unraveling the deformation of initially straight, transversal lines in the preform and the dependence on the draw ratio and radial position of the in-fiber electrical conductivity of polymer nanocomposites, an important class of materials for emerging fiber devices. This work sets a thus far missing theoretical and practical understanding of multimaterial fiber processing to better engineer advanced fibers and textiles for sensing, health care, robotics, or bioengineering applications

Multimaterial multifunctional fiber devices

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Materials Science and Engineering, 2008.Includes bibliographical references (p. 125-129).Optical fibers and semiconductor devices differ significantly in their properties and their processing approaches. The latter require an assembly of metal, insulator and semiconductor materials into complex geometries with small feature sizes (sub 100 nm), while maintaining high quality interfaces. Sophisticated logic and detection functions are realized through the integration of many such devices onto a chip. Conventional optical fibers have been restricted to insulating materials, much simpler cylindrically symmetric structures and larger feature sizes (order of a micrometer). Consequently a single fiber operates as a single optical transport device. Indeed the notion of integration has been foreign to optical fibers. Their processing however is much simpler compared to semiconductor devices as it utilizes a macroscopic perform to microscopic fiber fabrication approach. This process can efficiently yield highly uniform long and flexible fibers amenable to the formation of large area assemblies and woven fabrics. In this thesis, it is established that in-principle sophisticated semiconductor devices can be produced using simple preform-to-fiber thermal drawing techniques: In the first chapter a new materials processing paradigm is introduced where for the first time metals, insulators and semiconductors are thermally co-drawn in intimate contact and prescribed geometries. The second chapter focuses on unifunctional fiber devices and in particular the unique features of ID distributed photodetecting fibers. The concept of fiber device integration is then established by demonstrating optic, electronic and optoelectronic functionalities within a single fiber. In a third chapter a model for understanding the influence of geometric and structural changes on the performance of fiber photodetectors is derived.(cont.) It is demonstrated in particular that similarly to the evolution of semiconductor devices, the reduction of the materials feature dimensions inside the fiber significantly impacts the fiber performance characteristics. This in turn enables an increase in device density integrated into a single fiber. Unprecedented angular and spectral resolutions are achieved using this approach as described in chapter four. Finally, the first field effect is observed in a thermally drawn semiconductor metal insulator fiber. This paves the way to further integration of ever more complex electronic functionalities inside fiber devices.by Fabien Sorin.Ph.D

Hybrid Optical Fibers – An Innovative Platform for In‐Fiber Photonic Devices

The field of hybrid optical fibers is one of the most active research areas in current fiber optics and has the vision of integrating sophisticated materials inside fibers, which are not traditionally used in fiber optics. Novel in-fiber devices with unique properties have been developed, opening up new directions for fiber optics in fields of critical interest in modern research, such as biophotonics, environmental science, optoelectronics, metamaterials, remote sensing, medicine, or quantum optics. Here the recent progress in the field of hybrid optical fibers is reviewed from an application perspective, focusing on fiber-integrated devices enabled by including novel materials inside polymer and glass fibers. The topics discussed range from nanowire-based plasmonics and hyperlenses, to integrated semiconductor devices such as optoelectronic detectors, and intense light generation unlocked by highly nonlinear hybrid waveguides

Multi-material micro-electromechanical fibers with bendable functional domains

The integration of increasingly complex functionalities within thermally drawn multi-material fibers is heralding a novel path towards advanced soft electronics and smart fabrics. Fibers capable of electronic, optoelectronic, piezoelectric or energy harvesting functions are created by assembling new materials in intimate contact within increasingly complex architectures. Thus far, however, the opportunities associated with the integration of cantilever-like structures with freely moving functional domains within multi-material fibers have not been explored. Used extensively in the micro-electromechanical system (MEMS) technology, electro-mechanical transductance from moving and bendable domains is used in a myriad of applications. In this article we demonstrate the thermal drawing of micro-electromechanical fibers (MEMF) that can detect and localize pressure with high accuracy along their entire length. This ability results from an original cantilever-like design where a freestanding electrically conductive polymer composite film bends under an applied pressure. As it comes into contact with another conducting domain, placed at a prescribed position in the fiber cross-section, an electrical signal is generated. We show that by a judicious choice of materials and electrical connectivity, this signal can be uniquely related to a position along the fiber axis. We establish a model that predicts the position of a local touch from the measurement of currents generated in the 1D MEMF device, and demonstrate an excellent agreement with the experimental data. This ability to detect and localize touch over large areas, curved surfaces and textiles holds significant opportunities in robotics and prosthetics, flexible electronic interfaces, and medical textiles

Controlled Sub-Micrometer Hierarchical Textures Engineered in Polymeric Fibers and Microchannels via Thermal Drawing

The controlled texturing of surfaces at the micro- and nanoscales is a powerful method for tailoring how materials interact with liquids, electromagnetic waves, or biological tissues. The increasing scientific and technological interest in advanced fibers and fabrics has triggered a strong motivation for leveraging the use of textures on fiber surfaces. Thus far however, fiber-processing techniques have exhibited an inherent limitation due to the smoothing out of surface textures by polymer reflow, restricting achievable feature sizes. In this article, a theoretical framework is established from which a strategy is developed to reduce the surface tension of the textured polymer, thus drastically slowing down thermal reflow. With this approach the fabrication of potentially kilometers-long polymer fibers with controlled hierarchical surface textures of unprecedented complexity and with feature sizes down to a few hundreds of nanometers is demonstrated, two orders of magnitude below current configurations. Using such fibers as molds, 3D microchannels are also fabricated with textured inner surfaces within soft polymers such as poly(dimethylsiloxane), at dimensions and a degree of simplicity impossible to reach with current techniques. This strategy for the texturing of high curvature surfaces opens novel opportunities in bioengineering, regenerative scaffolds, microfluidics, and smart textiles

Impact of COVID-19 on cardiovascular testing in the United States versus the rest of the world

Objectives: This study sought to quantify and compare the decline in volumes of cardiovascular procedures between the United States and non-US institutions during the early phase of the coronavirus disease-2019 (COVID-19) pandemic. Background: The COVID-19 pandemic has disrupted the care of many non-COVID-19 illnesses. Reductions in diagnostic cardiovascular testing around the world have led to concerns over the implications of reduced testing for cardiovascular disease (CVD) morbidity and mortality. Methods: Data were submitted to the INCAPS-COVID (International Atomic Energy Agency Non-Invasive Cardiology Protocols Study of COVID-19), a multinational registry comprising 909 institutions in 108 countries (including 155 facilities in 40 U.S. states), assessing the impact of the COVID-19 pandemic on volumes of diagnostic cardiovascular procedures. Data were obtained for April 2020 and compared with volumes of baseline procedures from March 2019. We compared laboratory characteristics, practices, and procedure volumes between U.S. and non-U.S. facilities and between U.S. geographic regions and identified factors associated with volume reduction in the United States. Results: Reductions in the volumes of procedures in the United States were similar to those in non-U.S. facilities (68% vs. 63%, respectively; p = 0.237), although U.S. facilities reported greater reductions in invasive coronary angiography (69% vs. 53%, respectively; p < 0.001). Significantly more U.S. facilities reported increased use of telehealth and patient screening measures than non-U.S. facilities, such as temperature checks, symptom screenings, and COVID-19 testing. Reductions in volumes of procedures differed between U.S. regions, with larger declines observed in the Northeast (76%) and Midwest (74%) than in the South (62%) and West (44%). Prevalence of COVID-19, staff redeployments, outpatient centers, and urban centers were associated with greater reductions in volume in U.S. facilities in a multivariable analysis. Conclusions: We observed marked reductions in U.S. cardiovascular testing in the early phase of the pandemic and significant variability between U.S. regions. The association between reductions of volumes and COVID-19 prevalence in the United States highlighted the need for proactive efforts to maintain access to cardiovascular testing in areas most affected by outbreaks of COVID-19 infection