Leaching of metals and metalloids from hydrothermal ore particulates and their effects on marine phytoplankton

http://www.godac.jamstec.go.jp/darwin/cruise/natsushima/nt11-15/ehttp://www.godac.jamstec.go.jp/darwin/cruise/natsushima/nt12-06/

Postseismic fluid discharge chemically recorded in altered pseudotachylyte discovered from an ancient megasplay fault: an example from the Nobeoka Thrust in the Shimanto accretionary complex, SW Japan

Abstract Megasplay fault branching from plate boundaries of subduction zones is thought to be important sources of earthquakes and tsunamis. In this study, we performed structural and geochemical analyses on a fossilized megasplay fault (the Nobeoka Thrust of the Shimanto accretionary complex) to understand fluid-rock interaction and how the splay fault plays a role in fluid flow in the seismogenic zone. As a result of structural observations, we report that the principal slip zone (PSZ) of the Nobeoka Thrust is composed of foliated cataclasite originating from a sandstone-shale mélange and includes a thin (~ 1.5 mm thick) pseudotachylyte layer. Major and trace element composition analysis and EPMA element mapping revealed that the pseudotachylyte is enriched in Li and Cs within the PSZ, as well as in the slip zone of a minor fault in the footwall. Li and Cs enrichment in pseudotachylyte is interpreted as a result of fluid-rock interaction in the postseismic stage, because such an anomaly only results from a large fluid/rock ratio (R > 512–24 at 250–350 °C) under the influence of Li- and Cs-enriched fluids. The amount of fluid that reacted with the pseudotachylyte is estimated to be 1.78 × 100 to 7.61 × 103 m3

Leaching of Metals and Metalloids from Hydrothermal Ore Particulates and Their Effects on Marine Phytoplankton

Seafloor massive sulfide deposits have attracted much interest as mineral resources. Therefore, the potential environmental impacts of full-scale mining should be considered. In this study, we focused on metal and metalloid contamination that could be triggered by accidental leakage and dispersion of hydrothermal ore particulates from mining vessels into surface seawater. We determined the leaching potential of metals and metalloids from four hydrothermal ores collected from the Okinawa Trough into aerobic seawater and then evaluated the toxic effects of ore leachates on a phytoplankton species, Skeletonema marinoi–dohrnii complex, which is present ubiquitously in the ocean. Large amounts of metals and metalloids were released from the ground hydrothermal ores into seawater within 5 min under aerobic conditions. The main components of leachates were Zn + Pb, As + Sb, and Zn + Cu, which were obtained from the Fe–Zn–Pb-rich and Zn–Pb-rich zero-age, Ba-rich, and Fe-rich ores, respectively. The leachates had different chemical compositions from those of the ore. The rapid release and difference in chemical compositions between the leachates and the ores indicated that substances were not directly dissolved from the sulfide-binding mineral phase but from labile phases mainly on the adsorption–desorption interface of the ores under these conditions. All ore leachates inhibited the growth of S. marinoi–dohrnii complex but with different magnitudes of toxic effects. These results indicate that the fine particulate matter of hydrothermal ores is a potential source of toxic contamination that may damage primary production in the ocean. Therefore, we insist on the necessity for the prior evaluation of toxic element leachability from mineral ores into seawater to minimize mining impacts on the surface environment