933 research outputs found
Bacterial Peroxidase on Electrochemically Reduced Graphene Oxide for Highly Sensitive H<sub>2</sub>O<sub>2</sub> Detection
Peroxidase enzymes enable the construction of electrochemical sensors for highly sensitive and selective quantitative detection of various molecules, pathogens and diseases. Herein, we describe the immobilization of a peroxidase from Bacillus s. (BsDyP) on electrochemically reduced graphene oxide (ERGO) deposited on indium tin oxide (ITO) and polyethylene terephthalate (PET) layers. XRD, SEM, AFM, FTâIR and Raman characterization of the sensor confirmed its structural integrity and a higher enzyme surface occupancy. The BsDyPâERGO/ITO/PET electrode performed better than other horseradish peroxidaseâbased electrodes, as evinced by an improved electrochemical response in the nanomolar range (linearity 0.05â280â
ÎŒM of H(2)O(2), LOD 32â
nM). The bioelectrode was mechanically robust, active in the 3.5â6â
pH range and exhibited no loss of activity upon storage for 8â
weeks at 4â°C
Multipath Modeling of Automotive Power Line Communication Channels
In this paper an in-vehicle power line channel mathematical multipath representation is proposed. The selected approach aims at describing the transmission of a signal on a possibly complex power network by means of a finite number of delayed echoes. Model parameters are computed via a welldefined step-by-step procedure from frequency-domain channel characteristics. The feasibility and strength of the method are demonstrated by means of a measurement campaign. Two-port scattering measurements have been carried out on a commercial automobile and the effect of the measurement setup has been considered in the analysis
Recommended from our members
Chemistry modification of high oxygen-carbon powder by plasma melting
State-of-the-art melting of tantalum and tantalum alloys has relied on electron beam (EB) or vacuum-arc remelting (VAR) for commercial ingot production. The limited number of melting techniques for these materials are the result of high melting temperatures and reactivity with conventional mold/crucible materials. In addition, the required vacuum levels used in the EB and VAR processes limit these techniques to relatively low interstitial content material due toe extensive outgassing during melting. Plasma arc melting (PAM) provides and alternative for melting tantalum and offers the advantage or processing under inert or other gases rather than vacuum, The plasma process is not sensitive to materials outgassing and allows for the direct recycling of material that would otherwise be reprocessed by chemical extraction. The current work examines melting of high interstitial content tantalum powder by the plasma arc process. Various cover gases of argon-hydrogen and helium-hydrogen were investigated to determine best melt quality. Melted ingots were characterized by chemical and metallographic methods to determine overall interstitial content, compound and morphology
Hydrogen Susceptibility of Nanostructured Bainitic Steels
Abstract
Nanostructured steels with an ultimate tensile strength of 1.6Â GPa were produced with austenite content varying from 0 to 35Â vol pct. The effect on the mechanical properties was assessed after saturating the steel with hydrogen. Elongation was reduced to 2 to 5Â pct and UTS to 65 to 70Â pct of prior value. Thermal desorption measurements confirmed the higher solubility of hydrogen in the steel with higher austenite content. The level of hydrogen saturation was found to correlate to the total area of grain boundaries rather than to the volume fraction of retained austenite.This is the final version of the article. It was first available from Springer via http://dx.doi.org/10.1007/s11661-015-3221-
Austenite in Transformation-Induced Plasticity Steel Subjected to Multiple Isothermal Heat Treatments
The thermodynamic limit to the progress of the bainite reaction in steels containing a cementite inhibitor often leaves large quantities of thermally or mechanically unstable austenite. Such austenite is not effective in delaying the onset of plastic instabilities during the course of deformation. In such circumstances, it is useful to conduct isothermal transformation at a high temperature where the rate of reaction is relatively rapid, followed by a lower temperature step that permits more bainite to be generated. This in turn increases the stability of the refined austenite, which then transforms gently over a large range of strain during a tensile test. A significant corollary is that the two-step heat treatments are unnecessary in low-carbon steels, where the bainite reaction is able to proceed to a greater extent before reaching the thermodynamic limit. Furthermore, the two-step process can be counterproductive in low carbon steel, because the austenite content is reduced to a level below which it does not enhance the mechanical properties. Other circumstances in which multiple heat treatments are necessary are also discussed.The authors are grateful to POSCO for support through Steel
Innovation Programme, and to the World Class University Programme of the National
Research Foundation of Korea, Ministry of Education, Science and Technology, project
number R32-2008-000-10147.This is the accepted manuscript version. The final published version is available from Springer at http://link.springer.com/article/10.1007%2Fs11661-014-2405-z
Moduli Stabilisation and de Sitter String Vacua from Magnetised D7 Branes
Anomalous U(1)'s are ubiquitous in 4D chiral string models. Their presence
crucially affects the process of moduli stabilisation and cannot be neglected
in realistic set-ups. Their net effect in the 4D effective action is to induce
a matter field dependence in the non-perturbative superpotential and a
Fayet-Iliopoulos D-term. We study flux compactifications of IIB string theory
in the presence of magnetised D7 branes. These give rise to anomalous U(1)'s
that modify the standard moduli stabilisation procedure. We consider simple
orientifold models to determine the matter field spectrum and the form of the
effective field theory. We apply our results to one-modulus KKLT and
multi-moduli large volume scenarios, in particular to the Calabi-Yau
P^4_{[1,1,1,6,9]}. After stabilising the matter fields, the effective action
for the Kahler moduli can acquire an extra positive term that can be used for
de Sitter lifting with non-vanishing F- and D-terms. This provides an explicit
realization of the D-term lifting proposal of hep-th/0309187.Comment: 35 pages, 1 figure. v2: Minor changes, references adde
D terms from D-branes, gauge invariance and moduli stabilization in flux compactifications
We elucidate the structure of D terms in N=1 orientifold compactifications
with fluxes. As a case study, we consider a simple orbifold of the type-IIA
theory with D6-branes at angles, O6-planes and general NSNS, RR and
Scherk-Schwarz geometrical fluxes. We examine in detail the emergence of D
terms, in their standard supergravity form, from an appropriate limit of the
D-brane action. We derive the consistency conditions on gauged symmetries and
general fluxes coming from brane-localized Bianchi identities, and their
relation with the Freed-Witten anomaly. We extend our results to other N=1
compactifications and to non-geometrical fluxes. Finally, we discuss the
possible role of U(1) D terms in the stabilization of the untwisted moduli from
the closed string sector.Comment: 1+31 pages, 1 figur
The leading particle effect from light quark fragmentation in charm hadroproduction
The asymmetry of and meson production in scattering
observed by the E791 experiment is a typical phenomenon known as the leading
particle effect in charm hadroproducton. We show that the phenomenon can be
explained by the effect of light quark fragmentation into charmed hadrons
(LQF). Meanwhile, the size of the LQF effect is estimated from data of the E791
experiment.
A comparison is made with the estimate of the LQF effect from prompt
like-sign dimuon rate in neutrino experiments. The influence of the LQF effect
on the measurement of nucleon strange distribution asymmetry from charged
current charm production processes is briefly discussed.Comment: 6 latex pages, 1 figure, to appear in EPJ
- âŠ