255 research outputs found
Excited-state Forces within a First-principles Green's Function Formalism
We present a new first-principles formalism for calculating forces for
optically excited electronic states using the interacting Green's function
approach with the GW-Bethe Salpeter Equation method. This advance allows for
efficient computation of gradients of the excited-state Born-Oppenheimer
energy, allowing for the study of relaxation, molecular dynamics, and
photoluminescence of excited states. The approach is tested on photoexcited
carbon dioxide and ammonia molecules, and the calculations accurately describe
the excitation energies and photoinduced structural deformations.Comment: 2 figures and 2 table
A First-Principles Study of the Electronic Reconstructions of LaAlO3/SrTiO3 Heterointerfaces and Their Variants
We present a first-principles study of the electronic structures and
properties of ideal (atomically sharp) LaAlO3/SrTiO3 (001) heterointerfaces and
their variants such as a new class of quantum well systems. We demonstrate the
insulating-to-metallic transition as a function of the LaAlO3 film thickness in
these systems. After the phase transition, we find that conduction electrons
are bound to the n-type interface while holes diffuse away from the p-type
interface, and we explain this asymmetry in terms of a large hopping matrix
element that is unique to the n-type interface. We build a tight-binding model
based on these hopping matrix elements to illustrate how the conduction
electron gas is bound to the n-type interface. Based on the `polar catastrophe'
mechanism, we propose a new class of quantum wells at which we can manually
control the spatial extent of the conduction electron gas. In addition, we
develop a continuous model to unify the LaAlO3/SrTiO3 interfaces and quantum
wells and predict the thickness dependence of sheet carrier densities of these
systems. Finally, we study the external field effect on both LaAlO3/SrTiO3
interfaces and quantum well systems. Our systematic study of the electronic
reconstruction of LaAlO3/SrTiO3 interfaces may serve as a guide to engineering
transition metal oxide heterointerfaces.Comment: 50 pages, 18 figures and 4 table
Bipolar rechargeable lithium battery for high power applications
Viewgraphs of a discussion on bipolar rechargeable lithium battery for high power applications are presented. Topics covered include cell chemistry, electrolytes, reaction mechanisms, cycling behavior, cycle life, and cell assembly
Density Contrast-Peculiar Velocity Relation in the Newtonian Gauge
In general relativistic framework of the large scale structure formation
theory in the universe, we investigate the relation between density contrast
and peculiar velocity in the Newtonian gauge. According to the gauge-invariant
property of the energy-momentum tensor in the Newtonian gauge, we consider the
perturbation of velocity in the energy-momentum tensor behaves as the Newtonian
peculiar velocity. It is shown that in the relativistic framework, the relation
between peculiar velocity and density contrast has an extra correction term
with respect to the Newtonian Peebles formula which in small scales, can be
ignorable . The relativistic correction of peculiar velocity for the structures
with the extension of few hundred mega parsec is about few percent which is
smaller than the accuracy of the recent observations for measuring peculiar
velocity. The peculiar velocity in the general relativistic framework also
changes the contribution of Doppler effect on the anisotropy of CMB.Comment: 9 pages, 1 figure, accepted in Int. J. Mod. Phys
Growth and interfacial properties of epitaxial oxides on semiconductors: ab initio insights
Crystalline metal oxides display a large number of physical functionalities such as ferroelectricity, magnetism, superconductivity, and Mott transitions. High quality heterostructures involving metal oxides and workhorse semiconductors such as silicon have the potential to open new directions in electronic device design that harness these degrees of freedom for computation or information storage. This review describes how first-principles theoretical modeling has informed current understanding of the growth mechanisms and resulting interfacial structures of crystalline, coherent, and epitaxial metal oxide thin films on semiconductors. Two overarching themes in this general area are addressed. First, the initial steps of oxide growth involve careful preparation of the semiconductor surface to guard against amorphous oxide formation and to create an ordered template for epitaxy. The methods by which this is achieved are reviewed, and possibilities for improving present processes to enable the epitaxial growth of a wider set of oxides are discussed. Second, once a heterointerface is created, the precise interfacial chemical composition and atomic structure is difficult to determine unambiguously from experiment or theory alone. The current understanding of the structure and properties of complex oxide/semiconductor heterostructures is reviewed, and the main challenges to prediction—namely, (i) are these heterostructures in thermodynamic equilibrium or kinetically trapped, and (ii) how do the interfaces modify or couple to the degrees of freedom in the oxide?—are explored in detail for two metal oxide thin films on silicon. Finally, an outlook of where theoretical efforts in this field may be headed in the near future is provided.National Science Foundation (U.S.). Materials Research Science and Engineering Centers (Program) (Grant DMR-1119826)National Science Foundation (U.S.). (Yale University. Biomedical High Performance Computing Center. Grant CNS 08-21132
Chaotic Inflation with Time-Variable Space Dimensions
Assuming the space dimension is not constant but decreases during the
expansion of the Universe, we study chaotic inflation with the potential
. Our investigations are based on a model Universe with variable
space dimensions. We write down field equations in the slow-roll approximation,
and define slow-roll parameters by assuming the number of space dimensions
decreases continuously as the Universe expands. The dynamical character of the
space dimension shifts the initial and final value of the inflaton field to
larger values. We obtain an upper limit for the space dimension at the Planck
length. This result is in agreement with previous works for the effective time
variation of the Newtonian gravitational constant in a model Universe with
variable space dimensions.Comment: 19 pages, To be published in Int.J.Mod.Phys.D. Minor changes to match
accepted versio
Long range correlation in cosmic microwave background radiation
We investigate the statistical anisotropy and Gaussianity of temperature
fluctuations of Cosmic Microwave Background radiation (CMB) data from {\it
Wilkinson Microwave Anisotropy Probe} survey, using the multifractal detrended
fluctuation analysis, rescaled range and scaled windowed variance methods. The
multifractal detrended fluctuation analysis shows that CMB fluctuations has a
long range correlation function with a multifractal behavior. By comparing the
shuffled and surrogate series of CMB data, we conclude that the multifractality
nature of temperature fluctuation of CMB is mainly due to the long-range
correlations and the map is consistent with a Gaussian distribution.Comment: 10 pages, 7 figures, V2: Added comments, references and major
correction
\u3cem\u3eIn situ\u3c/em\u3e pressure study of Rb\u3csub\u3e4\u3c/sub\u3eC\u3csub\u3e60\u3c/sub\u3e insulator to metal transition by Compton scattering
Compton scattering has been shown to be a powerful tool for studying the ground state electronic density in real materials. Using synchrotron radiation, we have studied pressure effects on Rb4C60 by measuring the Compton profiles below and above the insulator to metal transition at 0.8 GPa. The experimental results are compared with the corresponding calculated results, obtained from new ab initio energy band structure calculations. These results allow us to quantitatively evaluate contributions to the Compton profiles resulting from the contraction of the unit cell as well as from the contraction of the C60 molecule itself. In this paper, we point out an unexpected contraction of the volume of the C60 molecule, leading to a major effect on the electronic density of the Rb4C60 compound
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