Monte Carlo simulations of copolymers at homopolymer interfaces: Interfacial structure as a function of the copolymer density

By means of extensive Monte Carlo simulations of the bond fluctuation model, we study the effect of adding AB diblock copolymers on the properties of an interface between demixed homopolymer phases. The parameters are chosen such that the homopolymers are strongly segregated, and the whole range of copolymer concentrations in the two phase coexistence region is scanned. We compare the ``mushroom'' regime, in which copolymers are diluted and do not interact with each other, with the ``wet brush'' regime, where copolymers overlap and stretch, but are still swollen by the homopolymers. A ``dry brush'' regime is never entered for our choice of chain lengths. ``Intrinsic'' profiles are calculated using a block analysis method introduced by us in earlier work. We discuss density profiles, orientational profiles and contact number profiles. In general, the features of the profiles are similar at all copolymer concentrations, however, the profiles in the concentrated regime are much broader than in the dilute regime. The results compare well with self-consistent field calculations.Comment: to appear in J. Chem. Phy

A Technical Note on Quantum Dots for Multi-Color Fluorescence in situ Hybridization

Quantum dots (Qdots) are semiconductor nanocrystals, which are photo-stable, show bright fluorescence with narrow, symmetric emission spectra and are available in multiple resolvable colors. We established a FISH protocol for the simultaneous visualization of up to 6 different DNA probes differentially labeled with Qdots and with conventional organic fluorochromes. Using a Leica SP5 laser scanning confocal microscope for image capture, we tested various combinations of hapten-labeled probes detected with streptavidin-Qdot525, sheep anti-digoxigenin-Qdot605, rat anti-dinitrophenyl-Qdot655 and goat anti-mouse-Qdot655, respectively, together with FITC-dUTP-, Cy3-dUTP- and Texas Red-dUTP-labeled probes. We further demonstrate that Qdots are suitable for imaging of FISH probes using 4Pi microscopy, which promises to push the resolution limits of light microscopy to 100 nanometers or less when applying a deconvolution algorithm, but requires the use of highly photo-stable fluors. Copyright (C) 2009 S. Karger AG, Base

Interaction-induced Renormalization of Andreev Reflection

We analyze the charge transport between a one-dimensional weakly interacting electron gas and a superconductor within the scaling approach in the basis of scattering states. We derive the renormalization group equations, which fully account for the intrinsic energy dependence due to Andreev reflection. A strong renormalization of the corresponding reflection phase is predicted even for a perfectly transparent metal-superconductor interface. The interaction-induced suppression of the Andreev conductance is shown to be highly sensitive to the normal state resistance, providing a possible explanation of experiments with carbon-nanotube/superconductor junctions by Morpurgo et al. [Science 286, 263 (2001)].Comment: 4 pages, 2 figure

The central molecular gas structure in LINERs with low luminosity AGN: evidence for gradual disappearance of the torus

We present observations of the molecular gas in the nuclear environment of three prototypical low luminosity AGN (LLAGN), based on VLT/SINFONI AO-assisted integral-field spectroscopy of H2 1-0 S(1) emission at angular resolutions of ~0.17". On scales of 50-150 pc the spatial distribution and kinematics of the molecular gas are consistent with a rotating thin disk, where the ratio of rotation (V) to dispersion (sigma) exceeds unity. However, in the central 50 pc, the observations reveal a geometrically and optically thick structure of molecular gas (V/sigma10^{23} cm^{-2}) that is likely to be associated with the outer extent of any smaller scale obscuring structure. In contrast to Seyfert galaxies, the molecular gas in LLAGN has a V/sigma<1 over an area that is ~9 times smaller and column densities that are in average ~3 times smaller. We interpret these results as evidence for a gradual disappearance of the nuclear obscuring structure. While a disk wind may not be able to maintain a thick rotating structure at these luminosities, inflow of material into the nuclear region could provide sufficient energy to sustain it. In this context, LLAGN may represent the final phase of accretion in current theories of torus evolution. While the inflow rate is considerable during the Seyfert phase, it is slowly decreasing, and the collisional disk is gradually transitioning to become geometrically thin. Furthermore, the nuclear region of these LLAGN is dominated by intermediate-age/old stellar populations (with little or no on-going star formation), consistent with a late stage of evolution.Comment: 15 pages, including 4 figures and 1 table, Accepted for publication in ApJ Letter

The evolution of HI and CIV quasar absorption line systems at 1.9 < z < 3.2

We have investigated the distribution and evolution of ~3100 intergalactic HI absorbers with HI column densities log N(HI) = [12.75, 17.0] at 1.9 < z < 3.2, using 18 high resolution, high S/N quasar spectra obtained from the ESO VLT/UVES archive. We used two sets of Voigt profile fitting analysis, one including all the available high-order Lyman lines to obtain reliable HI column densities of saturated lines, and another using only the Ly-alpha lines. There is no significant difference between the results from the two fits. Combining our results with literature data, the mean number density at 0 < z < 4 is not well described by a single power law and strongly suggests that its evolution slows down at z < 1.5 at the high and low column density ranges. We also divided our entire HI absorbers at 1.9 < z < 3.2 into two samples, the unenriched forest and the CIV-enriched forest, depending on whether HI lines are associated with CIV at log N(CIV) > 12.2 within a given velocity range. The entire HI column density distribution function (CDDF) can be described as the combination of these two well-characterised populations which overlap at log N(HI) ~ 15. At log N(HI) < 15, the unenriched forest dominates, showing a similar power-law distribution to the entire forest. The CIV-enriched forest dominates at log N(HI) > 15, with its distribution function proportional to N(HI)^(-1.45). However, it starts to flatten out at lower N(HI), since the enriched forest fraction decreases with decreasing N(HI). The deviation from the power law at log N(HI) = [14, 17] shown in the CDDF for the entire HI sample is a result of combining two different HI populations with a different CDDF shape. The total HI mass density relative to the critical density is Omega(HI) ~ 1.6 x 10^(-6) h^(-1), where the enriched forest accounts for ~40% of Omega(HI).Comment: 26 pages, 20 figures, accepted for AA, in pres

LIINUS/SERPIL: a design study for interferometric imaging spectroscopy at the LBT

LIINUS/SERPIL is a design study to augment LBTs interferometric beam combiner camera LINC-NIRVANA with imaging spectroscopy. The FWHM of the interferometric main beam at 1.5 micron will be about 10 mas, offering unique imaging and spectroscopic capabilities well beyond the angular resolution of current 8-10m telescopes. At 10 mas angular scale, e.g., one resolution element at the distance of the Galactic Center corresponds to the average diameter of the Pluto orbit (79 AU), hence the size of the solar system. Taking advantage of the LBT interferometric beam with an equivalent maximum diameter of 23 m, LIINUS/SERPIL is an ideal precursor instrument for (imaging) spectrographs at extremely large full aperture telescopes. LIINUS/SERPIL will be built upon the LINC-NIRVANA hardware and LIINUS/SERPIL could potentially be developed on a rather short timescale. The study investigates several concepts for the optical as well as for the mechanical design. We present the scientific promises of such an instrument together with the current status of the design study.Comment: 12 pages, SPIE conference proceeding, Orlando, 200