Poly(hydroxy alkanoate)s in Medical Applications

This review summarizes the state-of-the-art knowledge of the usage of poly(hydroxy alkanoate)s in medical and sanitary applications. Depending on the monomers incorporated into the polymers and copolymers, this class of polymers exhibits a broad range of (thermo-)plastic properties, enabling their processing by, e.g., solution casting or melt extrusion. In this review, strategies for the polymer analogous modification of these materials and their surfaces are highlighted and correlated with the potential applications of the corresponding materials and blends. While the commercial availability of purified PHAs is addressed in brief, special focus is put on the (bio-)degradability of these polymers and ways to influence the degradation mechanism and/or the duration of degradation

Comment on: Modular Theory and Geometry

In this note we comment on part of a recent article by B. Schroer and H.-W. Wiesbrock. Therein they calculate some new modular structure for the U(1)-current-algebra (Weyl-algebra). We point out that their findings are true in a more general setting. The split-property allows an extension to doubly-localized algebras.Comment: 13 pages, corrected versio

Anomalous Scale Dimensions from Timelike Braiding

Using the previously gained insight about the particle/field relation in conformal quantum field theories which required interactions to be related to the existence of particle-like states associated with fields of anomalous scaling dimensions, we set out to construct a classification theory for the spectra of anomalous dimensions. Starting from the old observations on conformal superselection sectors related to the anomalous dimensions via the phases which appear in the spectral decomposition of the center of the conformal covering group $Z(\widetilde{SO(d,2)}),$ we explore the possibility of a timelike braiding structure consistent with the timelike ordering which refines and explains the central decomposition. We regard this as a preparatory step in a new construction attempt of interacting conformal quantum field theories in D=4 spacetime dimensions. Other ideas of constructions based on the $AdS_{5}$-$CQFT_{4}$ or the perturbative SYM approach in their relation to the present idea are briefly mentioned.Comment: completely revised, updated and shortened replacement, 24 pages tcilatex, 3 latexcad figure

New Concepts in Particle Physics from Solution of an Old Problem

Recent ideas on modular localization in local quantum physics are used to clarify the relation between on- and off-shell quantities in particle physics; in particular the relation between on-shell crossing symmetry and off-shell Einstein causality. Among the collateral results of this new nonperturbative approach are profound relations between crossing symmetry of particle physics and Hawking-Unruh like thermal aspects (KMS property, entropy attached to horizons) of quantum matter behind causal horizons, aspects which hitherto were exclusively related with Killing horizons in curved spacetime rather than with localization aspects in Minkowski space particle physics. The scope of this modular framework is amazingly wide and ranges from providing a conceptual basis for the d=1+1 bootstrap-formfactor program for factorizable d=1+1 models to a decomposition theory of QFT's in terms of a finite collection of unitarily equivalent chiral conformal theories placed a specified relative position within a common Hilbert space (in d=1+1 a holographic relation and in higher dimensions more like a scanning). The new framework gives a spacetime interpretation to the Zamolodchikov-Faddeev algebra and explains its thermal aspects.Comment: In this form it will appear in JPA Math Gen, 47 pages tcilate

Responsive glyco-poly(2-oxazoline)s: synthesis, cloud point tuning, and lectin binding

A new sugar-substituted 2-oxazoline monomer was prepared using the copper-catalyzed alkyne-azide cycloaddition (CuAAC) reaction. Its copolymerization with 2-ethyl-2-oxazoline as well as 2-(dec-9-enyl)-2-oxazoline, yielding well-defined copolymers with the possibility to tune the properties by thiol-ene "click" reactions, is described. Extensive solubility studies on the corresponding glycocopolymers demonstrated that the lower critical solution temperature behavior and pH-responsiveness of these copolymers can be adjusted in water and phosphate-buffered saline (PBS) depending on the choice of the thiol. By conjugation of 2,3,4,6-tetra-O-acetyl-1-thio-beta-D-glucopyranose and subsequent deprotection of the sugar moieties, the hydrophilicity of the copolymer could be increased significantly, allowing a cloud-point tuning in the physiological range. Furthermore, the binding capability of the glycosylated copoly(2-oxazoline) to concanavalin A was investigated

A New Approach to Spin and Statistics

We give an algebraic proof of the spin-statistics connection for the parabosonic and parafermionic quantum topological charges of a theory of local observables with a modular PCT-symmetry. The argument avoids the use of the spinor calculus and also works in 1+2 dimensions. It is expected to be a progress towards a general spin-statistics theorem including also (1+2)-dimensional theories with braid group statistics.Comment: LATEX, 15 pages, no figure

The Pivotal Role of Causality in Local Quantum Physics

In this article an attempt is made to present very recent conceptual and computational developments in QFT as new manifestations of old and well establihed physical principles. The vehicle for converting the quantum-algebraic aspects of local quantum physics into more classical geometric structures is the modular theory of Tomita. As the above named laureate to whom I have dedicated has shown together with his collaborator for the first time in sufficient generality, its use in physics goes through Einstein causality. This line of research recently gained momentum when it was realized that it is not only of structural and conceptual innovative power (see section 4), but also promises to be a new computational road into nonperturbative QFT (section 5) which, picturesquely speaking, enters the subject on the extreme opposite (noncommutative) side.Comment: This is a updated version which has been submitted to Journal of Physics A, tcilatex 62 pages. Adress: Institut fuer Theoretische Physik FU-Berlin, Arnimallee 14, 14195 Berlin presently CBPF, Rua Dr. Xavier Sigaud 150, 22290-180 Rio de Janeiro, Brazi

The paradigm of the area law and the structure of transversal and longitudinal lightfront degrees of freedom

It is shown that an algebraically defined holographic projection of a QFT onto the lightfront changes the local quantum properties in a very drastic way. The expected ubiquitous vacuum polarization characteristic of QFT is confined to the lightray (longitudinal) direction, whereas operators whose localization is transversely separated are completely free of vacuum correlations. This unexpected ''transverse return to QM'' combined with the rather universal nature of the strongly longitudinal correlated vacuum correlations (which turn out to be described by rather kinematical chiral theories) leads to a d-2 dimensional area structure of the d-1 dimensional lightfront theory. An additive transcription in terms of an appropriately defined entropy related to the vacuum restricted to the horizon is proposed and its model independent universality aspects which permit its interpretation as a quantum candidate for Bekenstein's area law are discussed. The transverse tensor product foliation structure of lightfront degrees of freedom is essential for the simplifying aspects of the algebraic lightcone holography. Key-words: Quantum field theory; Mathematical physics, Quantum gravityComment: 16 pages latex, identical to version published in JPA: Math. Gen. 35 (2002) 9165-918

Noninteraction of waves in two-dimensional conformal field theory

In higher dimensional quantum field theory, irreducible representations of the Poincare group are associated with particles. Their counterpart in two-dimensional massless models are "waves" introduced by Buchholz. In this paper we show that waves do not interact in two-dimensional Moebius covariant theories and in- and out-asymptotic fields coincide. We identify the set of the collision states of waves with the subspace generated by the chiral components of the Moebius covariant net from the vacuum. It is also shown that Bisognano-Wichmann property, dilation covariance and asymptotic completeness (with respect to waves) imply Moebius symmetry. Under natural assumptions, we observe that the maps which give asymptotic fields in Poincare covariant theory are conditional expectations between appropriate algebras. We show that a two-dimensional massless theory is asymptotically complete and noninteracting if and only if it is a chiral Moebius covariant theory.Comment: 28 pages, no figur