Effects of Biological and Chemical Degradation on the Properties of Scots Pine Wood—Part I: Chemical Composition and Microstructure of the Cell Wall

Research on new conservation treatment for archaeological wood requires large amounts of wooden material. For this purpose, artificial wood degradation (biological—using brown-rot fungus Coniophora puteana, and chemical—using NaOH solution) under laboratory conditions was conducted to obtain an abundance of similar samples that mimic naturally degraded wood and can serve for comparative studies. However, knowledge about its properties is necessary to use this material for further study. In this study, the chemical composition and microstructure of degraded cell walls were investigated using FT-IR, XRD, helium pycnometry and nitrogen absorption methods. The results show that biological degradation caused the loss of hemicelluloses and celluloses, including the reduction in cellulose crystallinity, and led to lignin modification, while chemical degradation mainly depleted the amount of hemicelluloses and lignin, but also affected crystalline cellulose. These changes affected the cell wall microstructure, increasing both surface area and total pore volume. However, the chemical degradation produced a greater number of mesopores of smaller size compared to fungal decomposition. Both degradation processes weakened the cell wall’s mechanical strength, resulting in high shrinkage of degraded wood during air-drying. The results of the study suggest that degraded wood obtained under laboratory conditions can be a useful material for studies on new consolidants for archaeological wood

Effects of Biological and Chemical Degradation on the Properties of Scots Pine Wood—Part I: Chemical Composition and Microstructure of the Cell Wall

Research on new conservation treatment for archaeological wood requires large amounts of wooden material. For this purpose, artificial wood degradation (biological—using brown-rot fungus Coniophora puteana, and chemical—using NaOH solution) under laboratory conditions was conducted to obtain an abundance of similar samples that mimic naturally degraded wood and can serve for comparative studies. However, knowledge about its properties is necessary to use this material for further study. In this study, the chemical composition and microstructure of degraded cell walls were investigated using FT-IR, XRD, helium pycnometry and nitrogen absorption methods. The results show that biological degradation caused the loss of hemicelluloses and celluloses, including the reduction in cellulose crystallinity, and led to lignin modification, while chemical degradation mainly depleted the amount of hemicelluloses and lignin, but also affected crystalline cellulose. These changes affected the cell wall microstructure, increasing both surface area and total pore volume. However, the chemical degradation produced a greater number of mesopores of smaller size compared to fungal decomposition. Both degradation processes weakened the cell wall’s mechanical strength, resulting in high shrinkage of degraded wood during air-drying. The results of the study suggest that degraded wood obtained under laboratory conditions can be a useful material for studies on new consolidants for archaeological wood

UV irradiation influence on the structural and optical properties of CdO thin films

Polycrystalline Cd thin films were evaporated in a vacuum onto glass substrates at Cd source temperature of 770 K. The as-deposited Cd films were subjected to a gradual heating at the rate of 5 K/min, up to a temperature of 650 K and were then maintained at this temperature for 5 min. Then, the respective samples were cooled down to room temperature at the same rate. The obtained CdO thin films were UV irradiated for 2 h (150 W mercury lamp, 3.18–3.65 eV). By means of XRD, AFM and XPS techniques, the structural characteristics of the typical obtained CdO samples before and after UV treatment were investigated. The obtained results indicate that the UV treatment induces a recrystallization process: changes in sample morphology, surface roughness and crystallite size and orientation. XRD and XPS studies evidenced an improvement in crystalline structure and stoichiometry. UV irradiated sample shows photo-catalytic properties

Spontaneous parametric down-conversion in bottom-up grown lithium niobate microcubes

Nonclassical light sources are highly sought-after as they are an integral part of quantum communication and quantum computation devices. Typical sources use bulk nonlinear crystals that rely on stringent phase-matching conditions, limiting the operating wavelength and bandwidth. In this work, we demonstrate the generation of photon pairs from a freestanding lithium niobate microcube at the telecommunication wavelength of 1.56 µm through the spontaneous parametric down-conversion process. The maximum photon pair generation rate obtained from a single microcube with the size of 3.6 µm is 490 Hz, resulting in an efficiency of 20.6 GHz/Wm, which is three orders of magnitude larger than the efficiency of biphoton generation in bulk nonlinear crystals. The microcubes are synthesized through a solvothermal method, offering the possibility for scalable devices via bottom-up assembly on any substrates. Our work constitutes an important step forward in the realization of compact nonclassical light sources with a wide bandwidth for various quantum applications

Efficient Biphoton Generation in LiNbO3 Microcubes and GaAs Nanowires at Telecom Wavelength

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