Clathrate type 2 hydrate formation in vacuo under astrophysical conditions

The properties of clathrate hydrates were used to explain the complex and poorly understood physical processes taking place within cometary nuclei and other icy solar system bodies. Most of all the experiments previously conducted used starting compositions which would yield clathrate types I hydrates. The main criterion for type I vs. type II clathrate hydrate formation is the size of the guest molecule. The stoichiometry of the two structure types is also quite different. In addition, the larger molecules which would form type II clathrate hydrates typically have lower vapor pressures. The result of these considerations is that at temperatures where we identified clathrate formation (120-130 K), it is more likely that type II clathrate hydrates will form. We also formed clathrate II hydrates of methanol by direct vapor deposition in the temperature range 125-135 K

Low-pressure clathrate-hydrate formation in amorphous astrophysical ice analogs

In modeling cometary ice, the properties of clathrate hydrates were used to explain anomalous gas release at large radial distances from the Sun, and the retention of particular gas inventories at elevated temperatures. Clathrates may also have been important early in solar system history. However, there has never been a reasonable mechanism proposed for clathrate formation under the low pressures typical of these environments. For the first time, it was shown that clathrate hydrates can be formed by warming and annealing amorphous mixed molecular ices at low pressures. The complex microstructures which occur as a result of clathrate formation from the solid state may provide an explanation for a variety of unexplained phenomena. The vacuum and imaging systems of an Hitachi H-500H Analytical Electron Microscope was modified to study mixed molecular ices at temperatures between 12 and 373 K. The resulting ices are characterized by low-electron dose Transmission Electron Microscopy (TEM) and Selected Area Electron Diffraction (SAED). The implications of these results for the mechanical and gas release properties of comets are discussed. Laboratory IR data from similar ices are presented which suggest the possibility of remotely observing and identifying clathrates in astrophysical objects

Interstellar grain chemistry and the composition of comets

During the past 15 years considerable progress in observational techniques has been achieved in the middle infrared, the spectral region most diagnostic of molecular vibrations. Spectra of many different astronomical infrared sources are now available. By comparing these astronomical spectra with the spectra of lab ices, one can determine the composition and abundance of the icy materials frozen on the cold dust grains present in the interior of molecular clouds. In the experiments described, the assumption is made that cometary ices are similar to interstellar ices. As an illustration of the processes which can take place as an ice is irradiated and subsequently warmed, the infrared spectra is presented of the mixture H2O:CH3OH:CO:NH3:C6H14 (100:50:10:10:10). Apart from the last species, the ratio of these compounds is representative of the simplest ices found in interstellar clouds

Transonic steady- and unsteady-pressure measurements on a high-aspect-ratio supercritical-wing model with oscillating control surfaces

A supercritical wing with an aspect ratio of 10.76 and with two trailing-edge oscillating control surfaces is described. The semispan wing is instrumented with 252 static orifices and 164 in situ dynamic-pressure gages for studying the effects of control-surface position and motion on steady- and unsteady-pressures at transonic speeds. Results from initial tests conducted in the Langley Transonic Dynamics Tunnel at two Reynolds numbers are presented in tabular form

Hilltown Able: a unit memoir of Battery A--744th Field Artillery Battalion to V-E day

The American Third Army is the cockiest of all the armies and the fastest-moving. Long on armor, it is led by Lieut. General George S. Patton Jr. and, like him, it is colorful, proud and bold. Its motto is speed and more speed. Its record is the best possible evidence that Marshall and Eisenhower were right when they refused to fire Patton after the face-slapping incident in Sicily.https://digicom.bpl.lib.me.us/ww_reg_his/1010/thumbnail.jp

Streaming clumps ejection model and the heterogeneous inner coma of Comet Wild 2

It is modeled that a significant component of the jets of some comets are released as aggregate clumps, which then fragment and shed particles after release, leading to a heterogeneous innermost coma

Characteristics of vertical and lateral tunnel turbulence measured in air in the Langley Transonic Dynamics Tunnel

Preliminary measurements of the vertical and lateral velocity components of tunnel turbulence were obtained in the Langley Transonic Dynamics Tunnel test section using a constant-temperature anemometer equipped with a hot-film X-probe. For these tests air was the test medium. Test conditions included tunnel velocities ranging from 100 to 500 fps at atmospheric pressure. Standard deviations of turbulence velocities were determined and power spectra were computed. Unconstrained optimization was employed to determine parameter values of a general spectral model of a form similar to that used to describe atmospheric turbulence. These parameters, and others (notably break frequency and integral scale length), were determined at each test condition and compared with those of Dryden and Von Karman atmospheric turbulence spectra. When the data were discovered to be aliased, the spectral model was modified to account for and 'eliminate' the aliasing

Transonic unsteady airloads on an energy efficient transport wing with oscillating control surfaces

An aspect ratio 10.8 supercritical wing with oscillating control surfaces is described. The wing is instrumental with 252 static orifices and 164 in situ dynamic pressure transducers for studying the effects of control surface deflection on steady and unsteady pressures at transonic speeds. Results from initial wind tunnel tests conducted in the Langley Transonic Dynamics Tunnel are discussed. Unsteady pressure results are presented for two trailing edge control surfaces oscillating separately at the design Mach number of 0.78. Some experimental results are compared with analytical results obtained by using linear lifting surface theory

A multicomponent model of the infrared emission from Comet Halley

A model based on a mixture of coated silicates and amorphous carbon grains produces a good spectral match to the available Halley data and is consistent with the compositional and morphological information derived from interplanetary dust particle studies and Halley flyby data. The dark appearance of comets may be due to carbonaceous coatings on the dominant (by mass) silicates. The lack of a 10 micrometer feature may be due to the presence of large silicate grains. The optical properties of pure materials apparently are not representative of cometary materials. The determination of the optical properties of additional silicates and carbonaceous materials would clearly be of use