Association of trace metals with various sedimentary phases in dam reservoirs

In the present study sediment and water samples collected from Kowsar Dam reservoir in Kohkiluye and Boyerahmad Province, southwest of Iran, are subjected to bulk digestion and chemical partitioning. The concentrations of nickel, lead, zinc, copper, cobalt, cadmium, manganese and iron in water and bed sediment were determined by atomic absorption spectrometry. The concentrations of metals bounded to five sedimentary phases were estimated. On this basis, the proportions of natural and anthropogenic elements were calculated.The anthropogenic portion of elements are as follows: zinc (96%)> cobalt (88%)> iron (78%)> magnesium (78%)> nickel (78%)> copper (66%)> lead (63 )> cadmium (59%). The results show sediment contamination by nickel, cadmium and lead, according to the world aquatic sediments and mean earth crust values. Manganese and copper have strong association with organic matter and are of high portion of sulfide bounded ions. Finally, The degree of sediment contamination was evaluated using enrichment factor, geo-accumulation index (Igeo) and pollution index (IPoll). The sediments were identified to be of high cadmium and lead pollution index. The pattern of pollution intensity according to enrichment factor is as follows; manganese (1.25) < copper (1.63) < zinc (1.93) < cobalt (2.35) < nickel (3.83) < lead (12.63) < cadmium (78.32). Cluster analysis was performed in order to assess heavy metal interactions between water and sediment. Accordingly, nickel, cadmium and copper are earth originated. Zinc, copper and manganese are dominated by pH. All the elemental concentrations in water and sediment are correlated except for sedimental copper

Eocene Gold Ore Formation at Muteh, Sanandaj-Sirjan Tectonic Zone, Western Iran: A Result of Late-Stage Extension and Exhumation of Metamorphic Basement Rocks within the Zagros Orogen

A multidisciplinary study including field geology, microstructure analysis, 40Ar/39Ar dating, and fluid inclusion microthermometry and Raman spectrometry has been carried out on the Muteh gold deposit located in a greenschist to amphibolite facies metamorphic rock complex of the Sanandaj-Sirjan tectonic zone, Zagros orogen, Iran. The Muteh gold deposit has been previously interpreted as genetically related to Precambrian granitic intrusions, as an exhalative hot-spring deposit related to Paleozoic rhyolitic-acidic tuffs, and to local metamorphic processes. Host rocks of the gold deposit are predominantly schist and gneiss, and subsidiary amphibolite and quartzite, and are intruded by leucogranites. In the vicinity of the gold deposit, the metamorphic and granitic rocks display a subhorizontal mylonitic foliation, containing a northeast-oriented stretching lineation. Field investigations in one of the producing open pits show that the gold orebodies are controlled by northwest-oriented normal faults and joints, dipping to the northeast and the southwest, and crosscutting the ductile fabric of the host rocks. Both the ductile fabric of the host rocks and the gold ore-controlling brittle structures are interpreted to have formed within a single, continuous extensional event, which started with ductile deformation and gradually changed into brittle deformation. Hydrothermal alteration associated with ore formation consists of quartz, muscovite, pyrite, dolomite-ankerite, and albite, which crosscuts the ductile fabric and overprints the metamorphic minerals of the host rocks. Pyrite is the dominant opaque mineral and is the major phase associated with gold. Chalcopyrite, marcasite, bismuth, galena, sphalerite, and pyrrhotite are subsidiary to rare phases. 40Ar/39Ar incremental-heating and in situ laser-ablation age data reveal a coherent sequence of cooling and hydrothermal events in the metamorphic complex hosting the Muteh gold deposit. Muscovite samples from the alteration zone and from one quartz vein from the orebodies yield 40Ar/39Ar ages between 55.7 and 38.5 Ma and show that gold mineralization is the youngest among the different dated events. This Eocene age is consistent with the young structural setting of the gold orebodies revealing an emplacement along northwestoriented normal faults, which can be correlated with Tertiary extensional tectonic events reported by previous field investigations. The data also indicate that gold ore formation is coeval with magmatism in the adjacent Tertiary Urumieh-Dokhtar magmatic belt and with intrusive activity within the Sanandaj-Sirjan zone, with a 40Ar/39Ar age of 54 Ma near Muteh according to our study. The remaining 40Ar/39Ar data reveal a Cretaceous to early Tertiary metamorphic, magmatic, and deformation history of the complex hosting the Muteh gold deposit. The fluid inclusion study showed that distinct fluids were present during the regional geologic evolution predating ore formation and later Eocene gold ore formation. Early regional fluids consist of an H2O-CO2-NaCl fluid with subsidiary N2 and CH4 that underwent local unmixing. The salinities of the liquid-rich inclusions resulting from unmixing range between 2.2 and 17.5 wt percent NaCl equiv, and those of the CO2-rich, vaporrich inclusions range between 2.8 and 7.2 wt percent NaCl equiv. The high salinity of the regional liquid-rich fluids is attributed to metamorphism of evaporite-bearing sedimentary rocks, magmatic intrusions, retrograde hydration reactions, metamorphism of impure marbles, and migmatization. The fluid inclusions spatially associated with the gold veins postdating regional metamorphism and ductile deformation of the host rocks contain a low-salinity aqueous fluid with a dilute, low-density CO2 component, and maximum salinities between 2.6 and 5.8 wt percent NaCl equiv. Gold deposition at Muteh occurred during or after late stages of Eocene brittle extension as a result of exhumation of the host metamorphic complex, possibly during magmatic activity in the Sanandaj-Sirjam zone. It is most likely linked to the introduction of a distinct low-salinity, low CO2 content aqueous fluid during crustal extension. These fluids are younger than, and therefore unrelated to, the highly saline and CO2-rich, regional metamorphic-magmatic fluids. Our results refute previous models advocating Precambrian to Paleozoic ages of the Muteh gold deposit

Magntic susceptibility as a proxy to heavy metal content in the sediments of Anzali wetland, Iran

<p>Abstract</p> <p>Heavy metal concentrations and magnetic susceptibility of sediment samples were analyzed as indicators of urban and industrial contamination in Anzali wetland in Gilan, Iran. The aim was to investigate the suitability of magnetic properties measurements for indicating heavy metal pollution. The concentration of six heavy metals (Ni, Cr, Cd, Zn, Fe, and Pb) was determined in different depths of four sediment core samples within four different regions of the wetland (Abkenar, Hendekhaleh, Shijan and Siakeshim). Average concentration of heavy metals in the sediment cores was higher than the severe effect level (SEL) for Ni, Cr and Fe (77.26, 113.63 ppm and 5.2%, respectively) and lower than SEL for Cd, Zn and Pb (0.84, 137.7, 29.77 ppm, respectively). It was found that the trend of metal concentrations with the depth is different in each core and is related to the pollution discharges into the rivers entering the wetland. Core magnetic susceptibility measurements also showed different magnetic properties in each core. Cluster analysis was applied using Pearson correlation coefficient between heavy metal concentrations and magnetic properties across each core. Significant relationship was found to exist between magnetic susceptibility and the concentration of Ni in Abkenar and the concentration of Fe in other regions. Whereas Abkenar is almost the isolated and uncontaminated region of the wetland, it revealed a difference in magnetic properties between contaminated and uncontaminated sediments. It was concluded that magnetic properties of samples from contaminated zone were mostly related to Fe content. The result of this study demonstrated that magnetic susceptibility measurements could be applied as a proxy method for heavy metal pollution determination in marine environments in Iran especially as a rapid and cost-effective introductory site assessments.</p