12 research outputs found
ESI-MS Study on First-Generation Ruthenium Olefin Metathesis Catalysts in Solution: Direct Detection of the Catalytically Active 14-Electron Ruthenium Intermediate
No full textSynthesis of bioactive spiro-2-[3′-(2′-phenyl)-3H-indolyl]-1-aryl-3-phenylaziridines and SAR studies on their antimicrobial behavior
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Novel [4 + 2] Cycloaddition between Thiobenzophenone and Aryl-Substituted Alkenes via Photoinduced Electron Transfer
No full textExperimental and Theoretical Studies on the Radical-Cation-Mediated Imino-Diels_Alder Reaction
Full text link[EN] The feasibility of an electron transfer imino-Diels Alder reaction betweenN-benzylideneaniline and arylalkenes in the presence of a pyrylium salt
as a photosensitizer has been demonstrated by a combination of product studies, laser flash photolysis (LFP), and DFT theoretical calculations.
A stepwise mechanism involving two intermediates and two transition states is proposed.Financial support from the MICINN (Grants CTQ2010-14882, CTQ2009-13699, CTQ2009-11027, and JCI-2010-06204) and from the UPV (Grant No. 20100994 and MCI Program) is gratefully acknowledged. Dedicated to Prof. Dr. Jaime Primo (Universidad Politecnica de Valencia) on the occasion of his 60th birthday.Pérez Ruiz, R.; Domingo, LR.; Jiménez Molero, MC.; Miranda Alonso, MÁ. (2011). Experimental and Theoretical Studies on the Radical-Cation-Mediated Imino-Diels_Alder Reaction. Organic Letters. 13(19):5116-5119. https://doi.org/10.1021/ol201984sS51165119131
ESI-MS Studies and Calculations on Second-Generation Grubbs and Hoveyda–Grubbs Ruthenium Olefin Metathesis Catalysts
No full textDFT Study on the Molecular Mechanism of the [4 + 2] Cycloaddition between Thiobenzophenone and Arylalkenes via
No full textBrønsted-Acid-Catalyzed Asymmetric Multicomponent Reactions for the Facile Synthesis of Highly Enantioenriched Structurally Diverse Nitrogenous Heterocycles
No full textZinc and Cadmium Coordination Polymers with Bis(tetrazole) Ligands Bearing Flexible Spacers: Synthesis, Crystal Structures, and Properties
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