Non-Weyl asymptotics for quantum graphs with general coupling conditions

Inspired by a recent result of Davies and Pushnitski, we study resonance asymptotics of quantum graphs with general coupling conditions at the vertices. We derive a criterion for the asymptotics to be of a non-Weyl character. We show that for balanced vertices with permutation-invariant couplings the asymptotics is non-Weyl only in case of Kirchhoff or anti-Kirchhoff conditions, while for graphs without permutation numerous examples of non-Weyl behaviour can be constructed. Furthermore, we present an insight helping to understand what makes the Kirchhoff/anti-Kirchhoff coupling particular from the resonance point of view. Finally, we demonstrate a generalization to quantum graphs with nonequal edge weights.Comment: minor changes, to appear in Pierre Duclos memorial issue of J. Phys. A: Math. Theo

A single-mode quantum transport in serial-structure geometric scatterers

We study transport in quantum systems consisting of a finite array of N identical single-channel scatterers. A general expression of the S matrix in terms of the individual-element data obtained recently for potential scattering is rederived in this wider context. It shows in particular how the band spectrum of the infinite periodic system arises in the limit $N\to\infty$. We illustrate the result on two kinds of examples. The first are serial graphs obtained by chaining loops or T-junctions. A detailed discussion is presented for a finite-periodic "comb"; we show how the resonance poles can be computed within the Krein formula approach. Another example concerns geometric scatterers where the individual element consists of a surface with a pair of leads; we show that apart of the resonances coming from the decoupled-surface eigenvalues such scatterers exhibit the high-energy behavior typical for the delta' interaction for the physically interesting couplings.Comment: 36 pages, a LaTeX source file with 2 TeX drawings, 3 ps and 3 jpeg figures attache

Lieb-Thirring inequalities for geometrically induced bound states

We prove new inequalities of the Lieb-Thirring type on the eigenvalues of Schr\"odinger operators in wave guides with local perturbations. The estimates are optimal in the weak-coupling case. To illustrate their applications, we consider, in particular, a straight strip and a straight circular tube with either mixed boundary conditions or boundary deformations.Comment: LaTeX2e, 14 page

Exponential splitting of bound states in a waveguide with a pair of distant windows

We consider Laplacian in a straight planar strip with Dirichlet boundary which has two Neumann ``windows'' of the same length the centers of which are $2l$ apart, and study the asymptotic behaviour of the discrete spectrum as $l\to\infty$. It is shown that there are pairs of eigenvalues around each isolated eigenvalue of a single-window strip and their distances vanish exponentially in the limit $l\to\infty$. We derive an asymptotic expansion also in the case where a single window gives rise to a threshold resonance which the presence of the other window turns into a single isolated eigenvalue

Magnetic transport in a straight parabolic channel

We study a charged two-dimensional particle confined to a straight parabolic-potential channel and exposed to a homogeneous magnetic field under influence of a potential perturbation $W$. If $W$ is bounded and periodic along the channel, a perturbative argument yields the absolute continuity of the bottom of the spectrum. We show it can have any finite number of open gaps provided the confining potential is sufficiently strong. However, if $W$ depends on the periodic variable only, we prove by Thomas argument that the whole spectrum is absolutely continuous, irrespectively of the size of the perturbation. On the other hand, if $W$ is small and satisfies a weak localization condition in the the longitudinal direction, we prove by Mourre method that a part of the absolutely continuous spectrum persists

Time-Energy coherent states and adiabatic scattering

Coherent states in the time-energy plane provide a natural basis to study adiabatic scattering. We relate the (diagonal) matrix elements of the scattering matrix in this basis with the frozen on-shell scattering data. We describe an exactly solvable model, and show that the error in the frozen data cannot be estimated by the Wigner time delay alone. We introduce the notion of energy shift, a conjugate of Wigner time delay, and show that for incoming state $\rho(H_0)$ the energy shift determines the outgoing state.Comment: 11 pages, 1 figur

Duality and Anholonomy in Quantum Mechanics of 1D Contact Interactions

We study systems with parity invariant contact interactions in one dimension. The model analyzed is the simplest nontrivial one --- a quantum wire with a point defect --- and yet is shown to exhibit exotic phenomena, such as strong vs weak coupling duality and spiral anholonomy in the spectral flow. The structure underlying these phenomena is SU(2), which arises as accidental symmetry for a particular class of interactions.Comment: 4 pages ReVTeX with 4 epsf figures. KEK preprint 2000-3. Correction in Eq.(14

Initial state maximizing the nonexponentially decaying survival probability for unstable multilevel systems

The long-time behavior of the survival probability for unstable multilevel systems that follows the power-decay law is studied based on the N-level Friedrichs model, and is shown to depend on the initial population in unstable states. A special initial state maximizing the asymptote of the survival probability at long times is found and examined by considering the spontaneous emission process for the hydrogen atom interacting with the electromagnetic field.Comment: 5 pages, 1 table. Accepted for publication in Phys. Rev.

Atomically dispersed Pt-N-4 sites as efficient and selective electrocatalysts for the chlorine evolution reaction

Chlorine evolution reaction (CER) is a critical anode reaction in chlor-alkali electrolysis. Although precious metal-based mixed metal oxides (MMOs) have been widely used as CER catalysts, they suffer from the concomitant generation of oxygen during the CER. Herein, we demonstrate that atomically dispersed Pt-N-4 sites doped on a carbon nanotube (Pt-1/CNT) can catalyse the CER with excellent activity and selectivity. The Pt-1/CNT catalyst shows superior CER activity to a Pt nanoparticle-based catalyst and a commercial Ru/Ir-based MMO catalyst. Notably, Pt-1/CNT exhibits near 100% CER selectivity even in acidic media, with low Cl- concentrations (0.1M), as well as in neutral media, whereas the MMO catalyst shows substantially lower CER selectivity. In situ electrochemical X-ray absorption spectroscopy reveals the direct adsorption of Cl- on Pt-N-4 sites during the CER. Density functional theory calculations suggest the PtN4C12 site as the most plausible active site structure for the CER