1,125 research outputs found
Non-Weyl asymptotics for quantum graphs with general coupling conditions
Inspired by a recent result of Davies and Pushnitski, we study resonance
asymptotics of quantum graphs with general coupling conditions at the vertices.
We derive a criterion for the asymptotics to be of a non-Weyl character. We
show that for balanced vertices with permutation-invariant couplings the
asymptotics is non-Weyl only in case of Kirchhoff or anti-Kirchhoff conditions,
while for graphs without permutation numerous examples of non-Weyl behaviour
can be constructed. Furthermore, we present an insight helping to understand
what makes the Kirchhoff/anti-Kirchhoff coupling particular from the resonance
point of view. Finally, we demonstrate a generalization to quantum graphs with
nonequal edge weights.Comment: minor changes, to appear in Pierre Duclos memorial issue of J. Phys.
A: Math. Theo
A single-mode quantum transport in serial-structure geometric scatterers
We study transport in quantum systems consisting of a finite array of N
identical single-channel scatterers. A general expression of the S matrix in
terms of the individual-element data obtained recently for potential scattering
is rederived in this wider context. It shows in particular how the band
spectrum of the infinite periodic system arises in the limit . We
illustrate the result on two kinds of examples. The first are serial graphs
obtained by chaining loops or T-junctions. A detailed discussion is presented
for a finite-periodic "comb"; we show how the resonance poles can be computed
within the Krein formula approach. Another example concerns geometric
scatterers where the individual element consists of a surface with a pair of
leads; we show that apart of the resonances coming from the decoupled-surface
eigenvalues such scatterers exhibit the high-energy behavior typical for the
delta' interaction for the physically interesting couplings.Comment: 36 pages, a LaTeX source file with 2 TeX drawings, 3 ps and 3 jpeg
figures attache
Lieb-Thirring inequalities for geometrically induced bound states
We prove new inequalities of the Lieb-Thirring type on the eigenvalues of
Schr\"odinger operators in wave guides with local perturbations. The estimates
are optimal in the weak-coupling case. To illustrate their applications, we
consider, in particular, a straight strip and a straight circular tube with
either mixed boundary conditions or boundary deformations.Comment: LaTeX2e, 14 page
Exponential splitting of bound states in a waveguide with a pair of distant windows
We consider Laplacian in a straight planar strip with Dirichlet boundary
which has two Neumann ``windows'' of the same length the centers of which are
apart, and study the asymptotic behaviour of the discrete spectrum as
. It is shown that there are pairs of eigenvalues around each
isolated eigenvalue of a single-window strip and their distances vanish
exponentially in the limit . We derive an asymptotic expansion also
in the case where a single window gives rise to a threshold resonance which the
presence of the other window turns into a single isolated eigenvalue
Magnetic transport in a straight parabolic channel
We study a charged two-dimensional particle confined to a straight
parabolic-potential channel and exposed to a homogeneous magnetic field under
influence of a potential perturbation . If is bounded and periodic along
the channel, a perturbative argument yields the absolute continuity of the
bottom of the spectrum. We show it can have any finite number of open gaps
provided the confining potential is sufficiently strong. However, if
depends on the periodic variable only, we prove by Thomas argument that the
whole spectrum is absolutely continuous, irrespectively of the size of the
perturbation. On the other hand, if is small and satisfies a weak
localization condition in the the longitudinal direction, we prove by Mourre
method that a part of the absolutely continuous spectrum persists
Time-Energy coherent states and adiabatic scattering
Coherent states in the time-energy plane provide a natural basis to study
adiabatic scattering. We relate the (diagonal) matrix elements of the
scattering matrix in this basis with the frozen on-shell scattering data. We
describe an exactly solvable model, and show that the error in the frozen data
cannot be estimated by the Wigner time delay alone. We introduce the notion of
energy shift, a conjugate of Wigner time delay, and show that for incoming
state the energy shift determines the outgoing state.Comment: 11 pages, 1 figur
Duality and Anholonomy in Quantum Mechanics of 1D Contact Interactions
We study systems with parity invariant contact interactions in one dimension.
The model analyzed is the simplest nontrivial one --- a quantum wire with a
point defect --- and yet is shown to exhibit exotic phenomena, such as strong
vs weak coupling duality and spiral anholonomy in the spectral flow. The
structure underlying these phenomena is SU(2), which arises as accidental
symmetry for a particular class of interactions.Comment: 4 pages ReVTeX with 4 epsf figures. KEK preprint 2000-3. Correction
in Eq.(14
Initial state maximizing the nonexponentially decaying survival probability for unstable multilevel systems
The long-time behavior of the survival probability for unstable multilevel
systems that follows the power-decay law is studied based on the N-level
Friedrichs model, and is shown to depend on the initial population in unstable
states. A special initial state maximizing the asymptote of the survival
probability at long times is found and examined by considering the spontaneous
emission process for the hydrogen atom interacting with the electromagnetic
field.Comment: 5 pages, 1 table. Accepted for publication in Phys. Rev.
Atomically dispersed Pt-N-4 sites as efficient and selective electrocatalysts for the chlorine evolution reaction
Chlorine evolution reaction (CER) is a critical anode reaction in chlor-alkali electrolysis. Although precious metal-based mixed metal oxides (MMOs) have been widely used as CER catalysts, they suffer from the concomitant generation of oxygen during the CER. Herein, we demonstrate that atomically dispersed Pt-N-4 sites doped on a carbon nanotube (Pt-1/CNT) can catalyse the CER with excellent activity and selectivity. The Pt-1/CNT catalyst shows superior CER activity to a Pt nanoparticle-based catalyst and a commercial Ru/Ir-based MMO catalyst. Notably, Pt-1/CNT exhibits near 100% CER selectivity even in acidic media, with low Cl- concentrations (0.1M), as well as in neutral media, whereas the MMO catalyst shows substantially lower CER selectivity. In situ electrochemical X-ray absorption spectroscopy reveals the direct adsorption of Cl- on Pt-N-4 sites during the CER. Density functional theory calculations suggest the PtN4C12 site as the most plausible active site structure for the CER
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