Catalytic Dehydrogenation of Amine-Boranes using Geminal Phosphino-Boranes

The reaction of the intramolecular frustrated Lewis pair (FLP) tBu2PCH2BPh2 with the amine-boranes NH3·BH3 and Me2NH·BH3 leads to the formation of the corresponding FLP-H2 adducts as well as novel five-membered heterocycles that result from capturing the in situ formed amino-borane by a second equivalent of FLP. The sterically more demanding tBu2PCH2BMes2 does not form such a five-membered heterocycle when reacted with Me2NH·BH3 and its H2 adduct liberates dihydrogen at elevated temperatures, promoting the metal-free catalytic dehydrogenation of amine-boranes.Peer reviewe

Influence of the Support on Propene Oxidation over Gold Catalysts

The epoxidation of propene without forming a substantial amount of byproducts is one of the holy grails of catalysis. Supported Cu, Ag and Au catalysts are studied for this reaction and the activity of the supported metals is generally well understood. On the contrary, limited information is available on the influence of the support on the epoxide selectivity. The reaction of propene with equal amounts of hydrogen and oxygen was tested over gold nanoparticles deposited onto CeO2, TiO2, WO3, γ‐Al2O3, SiO2, TiO2‐SiO2 and titanosilicate‐1. Several metal oxide supports caused further conversion of the synthesized propene oxide. Strongly acidic supports, such as WO3 and titanosilicate‐1, catalyzed the isomerization of propene oxide towards propanal and acetone. Key factors for achieving high PO selectivity are having inert or neutralized surface sites, a low specific surface and/or a low density of surface ‐OH groups. This work provides insights and practical guidelines to which metal oxide support properties lead to which products in the reaction of propene in the presence of oxygen and hydrogen over supported gold catalysts

Influence of the Support on Propene Oxidation over Gold Catalysts

The epoxidation of propene without forming a substantial amount of byproducts is one of the holy grails of catalysis. Supported Cu, Ag and Au catalysts are studied for this reaction and the activity of the supported metals is generally well understood. On the contrary, limited information is available on the influence of the support on the epoxide selectivity. The reaction of propene with equal amounts of hydrogen and oxygen was tested over gold nanoparticles deposited onto CeO2, TiO2, WO3, γ-Al2O3, SiO2, TiO2-SiO2 and titanosilicate-1. Several metal oxide supports caused further conversion of the synthesized propene oxide. Strongly acidic supports, such as WO3 and titanosilicate-1, catalyzed the isomerization of propene oxide towards propanal and acetone. Key factors for achieving high PO selectivity are having inert or neutralized surface sites, a low specific surface and/or a low density of surface -OH groups. This work provides insights and practical guidelines to which metal oxide support properties lead to which products in the reaction of propene in the presence of oxygen and hydrogen over supported gold catalysts

Influence of the Support on Propene Oxidation over Gold Catalysts

The epoxidation of propene without forming a substantial amount of byproducts is one of the holy grails of catalysis. Supported Cu, Ag and Au catalysts are studied for this reaction and the activity of the supported metals is generally well understood. On the contrary, limited information is available on the influence of the support on the epoxide selectivity. The reaction of propene with equal amounts of hydrogen and oxygen was tested over gold nanoparticles deposited onto CeO2, TiO2, WO3, γ‐Al2O3, SiO2, TiO2‐SiO2 and titanosilicate‐1. Several metal oxide supports caused further conversion of the synthesized propene oxide. Strongly acidic supports, such as WO3 and titanosilicate‐1, catalyzed the isomerization of propene oxide towards propanal and acetone. Key factors for achieving high PO selectivity are having inert or neutralized surface sites, a low specific surface and/or a low density of surface ‐OH groups. This work provides insights and practical guidelines to which metal oxide support properties lead to which products in the reaction of propene in the presence of oxygen and hydrogen over supported gold catalysts