Transition between relieved and unrelieved modes when cutting rocks with conical picks

In the modern theory of rock cutting in production conditions, it is customary to distinguish two large classes of achievable cutting modes – relieved and unrelieved. The kinematics of rock-breaking machines in most cases determines the operation of the cutting tool in both modes in one cycle of the cutting tool. The currently available calculation methods have been developed for a stable, usually unrelieved cutting mode. In this article, the task is set to determine the conditions for the transition between cutting modes and the modernization of the calculation method for determining the forces on the cutting tool. The problem is solved by applying methods of algebraic analysis based on the search for the extremum of the force function on the cutter, depending on the ratio of the real cut spacing to the optimal spacing for the current chip thickness. As a result of solving the problem, an expression is obtained for determining the chip thickness, for which, at the specified parameters, the transition between the relieved and unrelieved cutting modes is provided. The obtained result made it possible to improve the method of calculating the forces on the cutting tool in the areas of the cutter movement with relieved cutting

Palladium-Catalyzed Amination of Dichloroquinolines with Adamantane-Containing Amines

Pd-catalyzed amination of isomeric 2,6-, 2,8-, 4,8- and 4,7-dichloroquinolines was studied using adamantane-containing amines in which substituents at the nitrogen atom differ in bulkiness. The selectivity of the amination of 2,6-dichloroquinoline was very low, substantially better results were obtained with 2,8-dichloroquinoline, and 4,8- and 4,7-dichloroquinolines provided the best yields of the amination products. Diamination of 4,8- and 4,7-dichloroquinolines was carried out with two amines which differ strongly in the bulkiness of the alkyl group. In the majority of cases BINAP ligand was successfully applied, however, it had to be replaced with DavePhos in certain reactions when using the most sterically hindered amine as well as for the diamination reactions