2 research outputs found
Statistical mechanics far from equilibrium: prediction and test for a sheared system
We report the complete statistical treatment of a system of particles
interacting via Newtonian forces in continuous boundary-driven flow, far from
equilibrium. By numerically time-stepping the force-balance equations of a
model fluid we measure occupancies and transition rates in simulation. The
high-shear-rate simulation data verify the invariant quantities predicted by
our statistical theory, thus demonstrating that a class of non-equilibrium
steady states of matter, namely sheared complex fluids, is amenable to
statistical treatment from first principles.Comment: 4 pages plus a 3-page pdf supplemen
Nonequilibrium statistical mechanics of shear flow: invariant quantities and current relations
In modeling nonequilibrium systems one usually starts with a definition of
the microscopic dynamics, e.g., in terms of transition rates, and then derives
the resulting macroscopic behavior. We address the inverse question for a class
of steady state systems, namely complex fluids under continuous shear flow: how
does an externally imposed shear current affect the microscopic dynamics of the
fluid? The answer can be formulated in the form of invariant quantities, exact
relations for the transition rates in the nonequilibrium steady state, as
discussed in a recent letter [A. Baule and R. M. L. Evans, Phys. Rev. Lett.
101, 240601 (2008)]. Here, we present a more pedagogical account of the
invariant quantities and the theory underlying them, known as the
nonequilibrium counterpart to detailed balance (NCDB). Furthermore, we
investigate the relationship between the transition rates and the shear current
in the steady state. We show that a fluctuation relation of the
Gallavotti-Cohen type holds for systems satisfying NCDB.Comment: 24 pages, 11 figure