2,9,16,19,22,25-Hexaoxatetra­cyclo­[24.4.0.24,7.010,15]dotriaconta-1(26),4,6,10(15),11,13,27,29,31-nona­ene

The title 22-crown-6 unit, C26H28O6, comprising of three benzo groups and triethyl­ene glycol, was prepared by the reaction of α,α′-dibromo-p-xylene with 1,8-bis­(2-hydroxy­phen­oxy)-3,6-dioxaoctane in the presence of Cs2CO3 with tetra­hydro­furan (THF) and recrystallized from dichloro­methane–hexane (1:20 v/v) at room temperature. In the mol­ecular structure, two O atoms of the central ethyl­ene glycol in the triethyl­ene glycol unit exhibit exo conformations due to intra­molecular C—H⋯O inter­actions. A number of C—H⋯O and C—H⋯π inter­molecular inter­actions contribute to the stabilization of the crystal packing

The North Pacific Oxygen Uptake Rates Over the Past Half-Century

The transport of dissolved oxygen (O2) from the surface ocean into the interior is a critical process sustaining aerobic life in mesopelagic ecosystems, but its rates and sensitivity to climate variations are poorly understood. Using a circulation model constrained to historical variability by assimilation of observations, we show that the North Pacific thermocline effectively takes up O2 primarily by expanding the area through which O2-rich mixed layer water is detrained into the thermocline. The outcrop area during the critical winter season varies in concert with the Pacific Decadal Oscillation (PDO). When the central North Pacific Ocean is in a cold phase, the winter outcrop window for the Central Mode Water class (CMW; a neutral density range of γ = 25.6 - 26.6) expands southward allowing more O2-rich surface water to enter the ocean’s interior. An increase in volume flux of water to the CMW density class is partly compensated by a reduced supply to the shallower densities of Subtropical Mode Water (γ = 24.0 - 25.5). The thermocline has become better oxygenated since the 1980s due partly to strong O2 uptake. Positive O2 anomalies appear first near the outcrop and subsequently downstream in the subtropical gyre. In contrast to the O2 variations within the ventilated thermocline, observed O2 in Intermediate Water (density range of γ = 26.7 – 27.2) shows a declining trend over the past half-century, a trend not explained by the open ocean water mass formation rate

Differential effect of corn oil-based low trans structured fat on the plasma and hepatic lipid profile in an atherogenic mouse model: comparison to hydrogenated trans fat

<p>Abstract</p> <p>Background</p> <p><it>Trans </it>fat are not desirable in many aspects on health maintenance. Low <it>trans </it>structured fats have been reported to be relatively more safe than <it>trans </it>fats.</p> <p>Methods</p> <p>We examined the effects of low <it>trans </it>structured fat from corn oil (LC), compared with high <it>trans </it>fat shortening, on cholesterol and fatty acid metabolism in apo E deficient mice which is an atherogenic animal model. The animals were fed a high <it>trans </it>fat (10% fat: commercial shortening (CS)) or a low <it>trans </it>fat (LC) diet for 12 weeks.</p> <p>Results</p> <p>LC decreased apo B and hepatic cholesterol and triglyceride concentration compared to the CS group but significantly increased plasma total cholesterol and triglyceride concentration and fecal lipids with a simultaneous increase in HDL-cholesterol level, apo A-I, and the ratio of HDL-cholesterol to total cholesterol (HTR). Reduction of hepatic lipid levels by inclusion of LC intake was observed alongside modulation of hepatic enzyme activities related to cholesterol esterification, fatty acid metabolism and fecal lipids level compared to the CS group. The differential effects of LC intake on the plasma and hepatic lipid profile seemed to be partly due to the fatty acid composition of LC which contains higher MUFA, PUFA and SFA content as well as lower content of <it>trans </it>fatty acids compared to CS.</p> <p>Conclusions</p> <p>We suggest that LC may exert a dual effect on plasma and hepatic lipid metabolism in an atherogenic animal model. Accordingly, LC, supplemented at 10% in diet, had an anti-atherogenic effect on these <it>apo E</it>^{<it>-/- </it>}mice, and increased fecal lipids, decreased hepatic steatosis, but elevated plasma lipids. Further studies are needed to verify the exact mode of action regarding the complex physiological changes and alteration in lipid metabolism caused by LC.</p

Downlink scheduling and resource management for best effort service

Abstract. Throughput performance and geographical service fairness of best effort service used for downlink of a 802.16e based TDD-OFDMA sectored cellular networks are evaluated in conjunction with different scheduling schemes and frequency reuse plans. The OFDM systems are based on two multiple access schemes, which are the OFDM-TDM and OFDMA, and considered scheduling schemes are round robin, max C/I, PF and G-fair schedulers with adaptive rate control. The 3-sectored 1 FA, 3-sectored 3 FA, and 6-sectored 3 FA plans are compared in terms of throughput, capacity, and geographical service fairness, which assist in determining the choice of a scheduling and frequency reuse plan

Oppositely rotating eigenmodes of spin-polarized current-driven vortex gyrotropic motions in elliptical nanodots

The authors found that there exist two different rotational eigenmodes of oppositely rotating sense in spin-polarized current-driven vortex gyrotropic motions in soft magnetic elliptical nanodots. Simple mathematical expressions were analytically calculated by adopting vortex-core (VC)-rotation-sense- dependent dynamic susceptibility tensors based on the linearized Thiele equation [Phys. Rev. Lett. 30, 230 (1973)]. The numerical calculations of those analytical expressions were confirmed by micromagnetic simulations, revealing that linear-regime steady-state VC motions driven by any polarized oscillating currents can be interpreted simply by the superposition of the clockwise and counterclockwise rotational eigenmodes. The shape of the orbital trajectories of the two eigenmodes is determined only by the lateral dimension of elliptical dots. Additionally, the orbital radii and phases of the two eigenmodes' VC motions were found to markedly vary with the frequency of applied currents, particularly across the vortex eigenfrequency and according to the vortex polarization, which results in overall VC motions driven by any polarized oscillating currents.open8

Data for Korean college students&apos; anxious and avoidant attachment, self-compassion, anxiety and depression

The data presented in this article are from 473 Korean college students׳ responses to an online survey consisting of measures of anxious and avoidant attachment (the Experiences in Close Relationships-Revised Scale: ECR-R), self-compassion (Neff׳s Self-Compassion Scale: SCS), depression (the Center for Epidemiological Studies-Depression Scale: CES-D) and anxiety (the State-Trait Anxiety Inventory-the Trait Anxiety Scale: STAT-T). Each variable was measured by a Korean version of the instrument. Participants were recruited from three universities in South Korea: 288 were men and 185 were women; 199 were undergraduate and 273 were graduate students. The online program used to collect the data prompted for but did not require responses to items; 26 surveys were not completed, and data from these surveys were not included in the dataset. Major findings based on the data presented here are reported in the article “Insecure attachment and emotional distress: Fear of self-compassion and self-compassion as mediators” (Joeng et al., 2017) [1]. The data, an SPSS file, are included as supplementary material.111Yscopu