Investigation of HNCO isomers formation in ice mantles by UV and thermal processing: an experimental approach

Current gas phase models do not account for the abundances of HNCO isomers detected in various environments, suggesting a formation in icy grain mantles. We attempted to study a formation channel of HNCO and its possible isomers by vacuum-UV photoprocessing of interstellar ice analogues containing H$_2$O, NH$_3$, CO, HCN, CH$_3$OH, CH$_4$, and N$_2$ followed by warm-up, under astrophysically relevant conditions. Only the H$_2$O:NH$_3$:CO and H$_2$O:HCN ice mixtures led to the production of HNCO species. The possible isomerization of HNCO to its higher energy tautomers following irradiation or due to ice warm-up has been scrutinized. The photochemistry and thermal chemistry of H$_2$O:NH$_3$:CO and H$_2$O:HCN ices was simulated using the Interstellar Astrochemistry Chamber (ISAC), a state-of-the-art ultra-high-vacuum setup. The ice was monitored in situ by Fourier transform mid-infrared spectroscopy in transmittance. A quadrupole mass spectrometer (QMS) detected the desorption of the molecules in the gas phase. UV-photoprocessing of H$_2$O:NH$_3$:CO/H$_2$O:HCN ices lead to the formation of OCN$^-$ as main product in the solid state and a minor amount of HNCO. The second isomer HOCN has been tentatively identified. Despite its low efficiency, the formation of HNCO and the HOCN isomers by UV-photoprocessing of realistic simulated ice mantles, might explain the observed abundances of these species in PDRs, hot cores, and dark clouds

Experimental phase functions of mm-sized cosmic dust grains

We present experimental phase functions of three types of millimeter-sized dust grains consisting of enstatite, quartz and volcanic material from Mount Etna, respectively. The three grains present similar sizes but different absorbing properties. The measurements are performed at 527 nm covering the scattering angle range from 3 to 170 degrees. The measured phase functions show two well defined regions i) soft forward peaks and ii) a continuous increase with the scattering angle at side- and back-scattering regions. This behavior at side- and back-scattering regions are in agreement with the observed phase functions for the Fomalhaut and HR 4796A dust rings. Further computations and measurements (including polarization) for millimeter sized-grains are needed to draw some conclusions about the fluffy or compact structure of the dust grains

Degenerate Fermi Gas of 87^{87}Sr

We report quantum degeneracy in a gas of ultra-cold fermionic $^{87}$Sr atoms. By evaporatively cooling a mixture of spin states in an optical dipole trap for 10.5\,s, we obtain samples well into the degenerate regime with $T/T_F=0.26^{+.05}_{-.06}$. The main signature of degeneracy is a change in the momentum distribution as measured by time-of-flight imaging, and we also observe a decrease in evaporation efficiency below $T/T_F \sim 0.5$.Comment: 4 pages, 3 figure

Bose-Einstein Condensation of 88^{88}Sr Through Sympathetic Cooling with 87^{87}Sr

We report Bose-Einstein condensation of $^{88}$Sr, which has a small, negative s-wave scattering length ($a_{88}=-2$\,$a_0$). We overcome the poor evaporative cooling characteristics of this isotope by sympathetic cooling with $^{87}$Sr atoms. $^{87}$Sr is effective in this role in spite of the fact that it is a fermion because of the large ground state degeneracy arising from a nuclear spin of $I=9/2$, which reduces the impact of Pauli blocking of collisions. We observe a limited number of atoms in the condensate ($N_{max}\approx 10^4$) that is consistent with the value of $a_{88}$ and the optical dipole trap parameters.Comment: 4 pages, 4 figure

A compactness theorem for scalar-flat metrics on manifolds with boundary

Let (M,g) be a compact Riemannian manifold with boundary. This paper is concerned with the set of scalar-flat metrics which are in the conformal class of g and have the boundary as a constant mean curvature hypersurface. We prove that this set is compact for dimensions greater than or equal to 7 under the generic condition that the trace-free 2nd fundamental form of the boundary is nonzero everywhere.Comment: 49 pages. Final version, to appear in Calc. Var. Partial Differential Equation

Doping of inorganic materials in microreactors – preparation of Zn doped Fe₃O₄ nanoparticles

Microreactor systems are now used more and more for the continuous production of metal nanoparticles and metal oxide nanoparticles owing to the controllability of the particle size, an important property in many applications. Here, for the first time, we used microreactors to prepare metal oxide nanoparticles with controlled and varying metal stoichiometry. We prepared and characterised Zn-substituted Fe₃O₄ nanoparticles with linear increase of Zn content (ZnxFe₃−xO₄ with 0 ≤ x ≤ 0.48), which causes linear increases in properties such as the saturation magnetization, relative to pure Fe₃O₄. The methodology is simple and low cost and has great potential to be adapted to the targeted doping of a vast array of other inorganic materials, allowing greater control on the chemical stoichiometry for nanoparticles prepared in microreactors

Flavor Delta(54) in SU(5) SUSY Model

We design a supersymmetric SU (5) GUT model using \Delta (54), a finite non-abelian subgroup of SU (3)f . Heavy right handed neutrinos are introduced which transform as three-dimensional repre-sentation of our chosen family group. The model successfully reproduces the mass hierarchical mass structures of the Standard Model, and the CKM mixing matrix. It then provides predictions for the light neutrino with a normal hierarchy and masses such that m{\nu},1 \approx 5\times10-3 eV, m{\nu}, 2 \approx 1\times 10-2 eV, and m{\nu},3 \approx 5 \times 10-2 eV. We also provide predictions for masses of the heavy neutrinos, and correc- tions to the tri-bimaximal matrix that fit within experimental limits, e.g. a reactor angle of -7.31o. A simple modification to our model is introduced at the end and is shown to also produce predictions that fall well within those limits.Comment: 22 page

Designed to fail : a biopolitics of British Citizenship.

Tracing a route through the recent 'ugly history' of British citizenship, this article advances two central claims. Firstly, British citizenship has been designed to fail specific groups and populations. Failure, it argues, is a design principle of British citizenship, in the most active and violent sense of the verb to design: to mark out, to indicate, to designate. Secondly, British citizenship is a biopolitics - a field of techniques and practices (legal, social, moral) through which populations are controlled and fashioned. This article begins with the 1981 Nationality Act and the violent conflicts between the police and black communities in Brixton that accompanied the passage of the Act through the British parliament. Employing Michel Foucault's concept of state racism, it argues that the 1981 Nationality Act marked a pivotal moment in the design of British citizenship and has operated as the template for a glut of subsequent nationality legislation that has shaped who can achieve citizenship. The central argument is that the existence of populations of failed citizens within Britain is not an accident of flawed design, but is foundational to British citizenship. For many 'national minorities' the lived realities of biopolitical citizenship stand in stark contradistinction to contemporary governmental accounts of citizenship that stress community cohesion, political participation, social responsibility, rights and pride in shared national belonging